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Fabrication of bifunctional multiwalled carbon nanotubes@palygorskite nanofiber nanocomposite for electrochemical determination of niclosamide

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Abstract

Herein, we reported a novel niclosamide (NA) electrochemical sensor based on the multifunctional nanocomposite of palygorskite (Pal) nanofibers and bifunctional multiwalled carbon nanotubes (BMCN) with graphitization and carboxylation. For the BMCN@Pal nanocomposite, BMCN with one-dimensional nanotube structure possessed excellent electrical conductivity and good dispersion performance due to the graphitization and carboxylation; Pal with fibrous structure possessed good electrocatalytic activity due to the high absorption capability, large specific surface area, and prominent stability. Moreover, BMCN with interconnected carbon conductive network promoted the uniform distribution of Pal nanofibers and compensated for the poor electrical conductivity of Pal nanofibers. Thanks to the functional combination of BMCN and Pal, the BMCN@Pal/GCE sensor exhibited good NA electrochemical detection performance with low limit of detection of 7.88 nM in linear NA concentration of 0.01–10 μM. The BMCN@Pal/GCE sensor exhibited good repeatability and reproducibility. In addition, a good practical feasibility can be achieved at the BMCN@Pal/GCE sensor for the detection of NA in tap water and pond water samples (recovery rate: 96.2–100.3%, relative standard deviation: 2.53–4.97).

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Funding

This work was supported by the University Students’ Innovation and Pioneering Project (No. 202210467017) and the Postdoctoral Research Project of Henan Province (No. 202102098).

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Authors and Affiliations

  1. Henan Institute of Science and Technology, Xinxiang, 453003, China

    Xiuying Wan, Mengyuan Zhao, Gan Zhu & Hongyuan Zhao

  2. Sumy National Agrarian University, Sumy, 40021, Ukraine

    Fang Li

Authors
  1. Xiuying Wan
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  4. Gan Zhu
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Contributions

X.W. and M.Z. conceived and designed the experiment. X.W., M.Z., and F.L. analyzed the data and wrote the manuscript. X.W., M.Z., F.L., and G.Z. conducted experiments or provided materials and put forward valuable suggestions. HZ supervised the work, and all authors read and approved the final manuscript.

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Correspondence to Fang Li or Hongyuan Zhao.

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Wan, X., Zhao, M., Li, F. et al. Fabrication of bifunctional multiwalled carbon nanotubes@palygorskite nanofiber nanocomposite for electrochemical determination of niclosamide. Ionics 29, 3373–3384 (2023). https://doi.org/10.1007/s11581-023-04964-6

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