Abstract
The composite supercapacitor materials can promote overall performance compared with individual materials owing to the synergistic effect. Here, we present a facile and effective method to synthesize NiMoO4/CoMoO4 nanorods by hydrothermal reaction and subsequent calcination. The as-synthesized products have both high capacitance and good stability, and successfully combine the properties of NiMoO4 and CoMoO4. NiMoO4/CoMoO4 nanorods displayed high specific capacitance of 1164 F/g at 2 A/g, and around 75% of capacitance was retained after 3000 cycles at 10 A/g. Especially, the composite materials showed excellent rate capability and around 83% of the capacitance was retained from 2 to 20 A/g. Furthermore, an asymmetric capacitor can deliver an energy density of 23.1 Wh/kg at a power density of 375 W/kg, and an energy density of 17.5 Wh/kg at a high power density of 3750 W/kg. These results indicate NiMoO4/CoMoO4 nanorods have prominent properties, which can be considered as promising material for supercapacitor.
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References
Yang J, Yu C, Fan X, Liang S, Li S, Huang H, Ling Z, Hao C, Qiu J (2016) Electroactive edge site-enriched nickel–cobalt sulfide into graphene frameworks for high-performance asymmetric supercapacitors. Energy Environ Sci 9:1299–1307
Xia X, Hao Q, Lei W, Wang W, Wang H, Wang X (2012) Reduced-graphene oxide/molybdenum oxide/polyaniline ternary composite for high energy density supercapacitors: synthesis and properties. J Mater Chem 22:8314–8320
Dubal DP, Ayyad O, Ruiz V, Gómez-Romero P (2015) Hybrid energy storage: the merging of battery and supercapacitor chemistries. Chem Soc Rev 44:1777–1790
Zhang S, Pan N (2015) Supercapacitors performance evaluation. Adv Energy Mater 5:1401401
Gao M, Wang WK, Rong Q, Jiang J, Zhang YJ, Yu HQ (2018) Porous ZnO-coated Co3O4 nanorod as a high-energy-density supercapacitor material. ACS Appl Mater Interfaces 10:23163–23173
Chen S, Xing W, Duan J, Hu X, Qiao SZ (2013) Nanostructured morphology control for efficient supercapacitor electrodes. J Mater Chem A 1:2941–2954
Chen W, Xia C, Alshareef HN (2014) One-step electrodeposited nickel cobalt sulfide nanosheet arrays for high-performance asymmetric supercapacitors. ACS Nano 8:9531–9541
Zhang LL, Zhao XS (2009) Carbon-based materials as supercapacitor electrodes. Chem Soc Rev 38:2520–2531
Liu J, Jiang J, Cheng C, Li H, Zhang J, Gong H, Fan HJ (2011) Co3O4 Nanowire@MnO2 ultrathin nanosheet core/shell arrays: a new class of high-performance pseudocapacitive materials. Adv Mater 23:2076–2081
Wang Y, Lei Y, Li J, Gu L, Yuan H, Xiao D (2014) Synthesis of 3D-nanonet hollow structured Co3O4 for high capacity supercapacitor. ACS Appl Mater Interfaces 6:6739–6747
Wang J, Zhang X, Wei Q, Lv H, Tian Y, Tong Z, Liu X, Hao J, Qu H, Zhao J, Li Y, Mai L (2016) 3D self-supported nanopine forest-like Co 3 O 4 @CoMoO 4 core–shell architectures for high-energy solid state supercapacitors. Nano Energy 19:222–233
Chen H, Hu L, Yan Y, Che R, Chen M, Wu L (2013) One-step fabrication of ultrathin porous nickel hydroxide-manganese dioxide hybrid nanosheets for supercapacitor electrodes with excellent capacitive performance. Adv Energy Mater 3:1636–1646
Wang J, Liu S, Zhang X, Liu X, Liu X, Li N, Zhao J, Li Y (2016) A high energy asymmetric supercapacitor based on flower-like CoMoO 4/MnO 2 heterostructures and activated carbon. Electrochim Acta 213:663–671
Xu R, Lin J, Wu J, Huang M, Fan L, Xu Z, Song Z (2019) A high-performance pseudocapacitive electrode material for supercapacitors based on the unique NiMoO4/NiO nanoflowers. Appl Surf Sci 463:721–731
Feng Y, Liu L, Liang J, Yao W, Tian B, Jiang C, Wu W (2019) Ni(OH)2/NiMoO4 nanoplates for large-scale fully-printed flexible solid-state supercapacitors. J Power Sources 433:126676
Cai D, Liu B, Wang D, Wang L, Liu Y, Li H, Wang Y, Li Q, Wang T (2014) Construction of unique NiCo2O4 nanowire@CoMoO4 nanoplate core/shell arrays on Ni foam for high areal capacitance supercapacitors. J Mater Chem A 2:4954–4960
Zhao Y, Hu L, Zhao S, Wu L (2016) Preparation of MnCo2O4@Ni(OH)2 core-shell flowers for asymmetric supercapacitor materials with ultrahigh specific capacitance. Adv Funct Mater 26:4085–4093
Neeraj NS, Mordina B, Srivastava AK, Mukhopadhyay K, Prasad NE (2019) Impact of process conditions on the electrochemical performances of NiMoO4 nanorods and activated carbon based asymmetric supercapacitor. Appl Surf Sci 473:807–819
Chen Y, Liu B, Liu Q, Wang J, Liu J, Zhang H, Hu S, Jing X (2015) Flexible all-solid-state asymmetric supercapacitor assembled using coaxial NiMoO 4 nanowire arrays with chemically integrated conductive coating†. Electrochim Acta 178:429–438
Mai L-Q, Yang F, Zhao Y-L, Xu X, Xu L, Luo Y-Z (2011) Hierarchical MnMoO4/CoMoO4 heterostructured nanowires with enhanced supercapacitor performance. Nat Commun 2:381
Balamurugan J, Li C, Peera SG, Kim NH, Lee JH (2017) High-energy asymmetric supercapacitors based on free-standing hierarchical Co-Mo-S nanosheets with enhanced cycling stability. Nanoscale 9:13747–13759
Liu Y, Li Z, Yao L, Chen S, Zhang P, Deng L (2019) Confined growth of NiCo2S4 nanosheets on carbon flakes derived from eggplant with enhanced performance for asymmetric supercapacitors. Chem Eng J 366:550–559
Yao L, Yang J, Zhang P, Deng L (2018) In situ surface decoration of Fe3C/Fe3O4/C nanosheets: towards bi-functional activated carbons with supercapacitance and efficient dye adsorption. Bioresour Technol 256:208–215
Zhou M, Lu F, Shen X, Xia W, He H, Zeng X (2015) One-pot construction of three dimensional CoMoO4/Co3O4 hybrid nanostructures and their application in supercapacitors. J Mater Chem A 3:21201–21210
Cai D, Wang D, Liu B, Wang Y, Liu Y, Wang L, Li H, Huang H, Li Q, Wang T (2013) Comparison of the electrochemical performance of NiMoO4 nanorods and hierarchical nanospheres for supercapacitor applications. ACS Appl Mater Interfaces 5:12905–12910
Peng S, Li L, Wu HB, Madhavi S, Lou XWD (2015) Controlled growth of NiMoO4 nanosheet and nanorod arrays on various conductive substrates as advanced electrodes for asymmetric supercapacitors. Adv Energy Mater 5:1401172
Cao Y, An L, Liao L, Liu X, Ji T, Zou R, Yang J, Qin Z, Hu J (2016) Hierarchical core/shell structures of ZnO nanorod@CoMoO4 nanoplates used as a high-performance electrode for supercapacitors. RSC Adv 6:3020–3024
Yu X, Lu B, Xu Z (2014) Super long-life supercapacitors based on the construction of nanohoneycomb-like strongly coupled CoMoO(4)-3D graphene hybrid electrodes. Adv Mater 26:1044–1051
Wan H, Jiang J, Ji X, Miao L, Zhang L, Xu K, Chen H, Ruan Y (2013) Rapid microwave-assisted synthesis NiMoO4·H2O nanoclusters for supercapacitors. Mater Lett 108:164–167
Liu M-C, Kong L-B, Lu C, Li X-M, Luo Y-C, Kang L (2012) Waste paper based activated carbon monolith as electrode materials for high performance electric double-layer capacitors. RSC Adv 2:1890–1896
Yin Z, Zhang S, Chen Y, Gao P, Zhu C, Yang P, Qi L (2015) Hierarchical nanosheet-based NiMoO4 nanotubes: synthesis and high supercapacitor performance. J Mater Chem A 3:739–745
Senthilkumar B, Meyrick D, Lee Y-S, Selvan RK (2013) Synthesis and improved electrochemical performances of nano β-NiMoO4–CoMoO4·xH2O composites for asymmetric supercapacitors. RSC Adv 3:16542–16548
Yin Z, Chen Y, Zhao Y, Li C, Zhu C, Zhang X (2015) Hierarchical nanosheet-based CoMoO4–NiMoO4 nanotubes for applications in asymmetric supercapacitors and the oxygen evolution reaction. J Mater Chem A 3:22750–22758
Zhang Z, Zhang H, Zhang X, Yu D, Ji Y, Sun Q, Wang Y, Liu X (2016) Facile synthesis of hierarchical CoMoO4@NiMoO4 core–shell nanosheet arrays on nickel foam as an advanced electrode for asymmetric supercapacitors. J Mater Chem A 4:18578–18584
Lin J, Yao L, Li Z, Zhang P, Zhong W, Yuan Q, Deng L (2019) Hybrid hollow spheres of carbon@CoxNi1−xMoO4 as advanced electrodes for high-performance asymmetric supercapacitors. Nanoscale 11:3281–3291
Chang C, Yang X, Xiang S, Lin X, Que H, Li M (2017) Nitrogen and sulfur co-doped glucose-based porous carbon materials with excellent electrochemical performance for supercapacitors. J Electrochem Soc 164:A1601–A1607
Liu M-C, Kong L-B, Lu C, Ma X-J, Li X-M, Luo Y-C, Kang L (2013) Design and synthesis of CoMoO4–NiMoO4·xH2O bundles with improved electrochemical properties for supercapacitors. J Mater Chem A 1:1380–1387
Ghosh D, Giri S, Das CK (2013) Synthesis, characterization and electrochemical performance of graphene decorated with 1D NiMoO4 . nH2O nanorods. Nanoscale 5:10428–10437
Nti F, Anang DA, Han JI (2018) Facilely synthesized NiMoO4/CoMoO4 nanorods as electrode material for high performance supercapacitor. J Alloys Compd 742:342–350
Li Z, Zhao D, Xu C, Ning J, Zhong Y, Zhang Z, Wang Y, Hu Y (2018) Reduced CoNi 2 S 4 nanosheets with enhanced conductivity for high-performance supercapacitors. Electrochim Acta 278:33–41
Chen C, Wang S, Luo X, Gao W, Huang G, Zeng Y, Zhu Z (2019) Reduced ZnCo2O4@NiMoO4·H2O heterostructure electrodes with modulating oxygen vacancies for enhanced aqueous asymmetric supercapacitors. J Power Sources 409:112–122
Zhang X, Wei L, Guo X (2018) Ultrathin mesoporous NiMoO4-modified MoO3 core/shell nanostructures: enhanced capacitive storage and cycling performance for supercapacitors. Chem Eng J 353:615–625
Chavan HS, Hou B, Ahmed ATA, Kim J, Jo Y, Cho S, Park Y, Pawar SM, Inamdar AI, Cha SN, Kim H, Im H (2018) Ultrathin Ni-Mo oxide nanoflakes for high-performance supercapacitor electrodes. J Alloys Compd 767:782–788
Rong Q, Long LL, Zhang X, Huang YX, Yu HQ (2015) Layered cobalt nickel silicate hollow spheres as a highly-stable supercapacitor material. Appl Energy 153:63–69
Chen C, Yan D, Luo X, Gao W, Huang G, Han Z, Zeng Y, Zhu Z (2018) Construction of core–shell NiMoO4@Ni-Co-S nanorods as advanced electrodes for high-performance asymmetric supercapacitors. ACS Appl Mater Interfaces 10:4662–4671
Dai CS, Chien PY, Lin JY, Chou SW, Wu WK, Li PH, Wu KY, Lin TW (2013) Hierarchically structured Ni(3)S(2)/carbon nanotube composites as high performance cathode materials for asymmetric supercapacitors. ACS Appl Mater Interfaces 5:12168–12174
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Zhang, P., Zhang, X. & Li, G. Fabrication of rod-like NiMoO4/CoMoO4 for application in asymmetric supercapacitors. Ionics 26, 393–401 (2020). https://doi.org/10.1007/s11581-019-03221-z
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DOI: https://doi.org/10.1007/s11581-019-03221-z