Abstract
Single-chamber solid oxide fuel cell made of conventional materials with two gas tubes located at the different sides of the cell was fabricated and tested in a diluted methane-oxygen mixture to evaluate the influence of various operating parameters on cell performance. The traditional gas supply method was also studied for comparison. Experimental results showed that the cell performance was greatly enhanced by using the dual gas supply method. At a furnace temperature of 700 °C, the maximum power density was 459.2 mW cm−2 for a CH4/O2 ratio of 1.5, which was 67% higher than that of the traditional gas supply method. Additionally, the dual gas supply method could provide the required reactant gas for each electrode by changing the gas composition of both the gas tubes separately. The highest power density of 493.9 mW cm−2 was obtained at the anode and cathode CH4/O2 ratios of 1.5 and 1, respectively. A cell with dual gas supply method will generate a more attractive power output than that of the traditional method in a single-chamber condition.
Similar content being viewed by others
References
Sun CW, Stimming U (2007) Recent anode advances in solid oxide fuel cells. J Power Sources 171:247–260
Chen KF, Tian YT, Lü Z, Ai N, Huang XQ, Su WH (2009) Behavior of 3 Mol% yttria-stabilized tetragonal zirconia polycrystal film prepared by slurry spin coating. J Power Sources 186:128–132
Sun CW, Xie Z, Xia CR, Li H, Chen LQ (2006) Investigations of mesoporous CeO2-Ru as a reforming catalyst layer for solid oxide fuel cells. Electrochem Commun 8:833–838
Yang W, Zhu CL, Ma ZH, Sun CW, Chen LQ, Chen YJ (2014) MoO3 nanorods/Fe2(MoO4)3 nanoparticles composite anode for solid oxide fuel cells. Int J Hydrog Energy 39:14411–14415
Yang Q, Chai FT, Ma C, Sun CW, Shi SQ, Chen LQ (2016) Enhanced coking tolerance of MgO-promoted Ni cermet anode for hydrocarbon fueled solid oxide fuel cells. J Mater Chem A 4:18031–18036
Yang Q, Chen J, Sun CW, Chen LQ (2016) Direct operation of methane fueled solid oxide fuel cells with Ni cermet anode via Sn modification. Int J Hydrog Energy 41:11391–11398
Kuhn M, Napporn TW (2010) Single-chamber solid oxide fuel cell technology - from its origins to Today’s state of the art. Energies 3:57–134
Wei B, Lu Z, Huang XQ, Liu ML, Chen KF, Su WH (2007) Enhanced performance of a single-chamber solid oxide fuel cell with an SDC-impregnated cathode. J Power Sources 167:58–63
Buergler BE, Siegrist ME, Gauckler LJ (2005) Single chamber solid oxide fuel cells with integrated current-collectors. Solid State Ionics 176:1717–1722
Yano M, Tomita A, Sano M, Hibino T (2007) Recent advances in single-chamber solid oxide fuel cells: a review. Solid State Ionics 177:3351–3359
Riess I (2008) On the single chamber solid oxide fuel cells. J Power Sources 175:325–337
Yano M, Nagao M, Okamoto K, Tomita A, Uchiyama Y, Uchiyama N, Hibino T (2008) A single-chamber SOFC stack operating in engine exhaust. Electrochem Solid-State Lett 11:B29–B33
Shao ZP, Mederos J, Chueh WC, Haile SM (2006) High power-density single-chamber fuel cells operated on methane. J Power Sources 162:589–596
Hibino T, Hashimoto A, Inoue T, Tokuno JI, Yoshida SI, Sano M (2000) Single-chamber solid oxide fuel cells at intermediate temperatures with various hydrocarbon-air mixtures. J Electrochem Soc 147:2888–2892
Tomita A, Hirabayashi D, Hibino T, Nagao M, Sano M (2005) Single-chamber SOFCs with a Ce0.9Gd0.1O1.95 electrolyte film for low-temperature operation. Electrochem Solid-State Lett 8-1:A63–A65
Yano M, Kawai T, Okamoto K, Nagao M, Sano M, Tomita A, Hibino T (2007) Single-chamber SOFCs using dimethyl ether and ethanol. J Electrochem Soc 154:B865–B870
Napporn TW, Jacques-Bédard X, Morin F, Meunier M (2004) Operating conditions of a single-chamber SOFC. J Electrochem Soc 151:A2088–A2094
Shao ZP, Kwak C, Haile SM (2004) Anode-supported thin-film fuel cells operated in a single chamber configuration 2T-I-12. Solid State Ionics 175:39–46
Suzuki T, Jasinski P, Petrovsky V, Anderson HU, Dogan F (2004) Anode supported single chamber solid oxide fuel cell in CH4-air mixture. J Electrochem Soc 151:A1473–A1476
Suzuki T, Jasinski P, Petrovsky V, Anderson HU, Dogan F (2005) Performance of a porous electrolyte in single-chamber SOFCs. J Electrochem Soc 152:A527–A531
Napporn TW, Morin F, Meunier M (2004) Evaluation of the actual working temperature of a single-chamber SOFC. Electrochem Solid-State Lett 7:A60–A62
Shao ZP, Haile SM, Ahn J, Ronney PD, Zhan ZL, Barnett SA (2005) A thermally self-sustained micro solid-oxide fuel-cell stack with high power density. Nature 435:795–798
Hibino T, Hashimoto A, Inoue T, Tokuno JI, Yoshida SI, Sano M (2001) A solid oxide fuel cell using an exothermic reaction as the heat source. J Electrochem Soc 148:A544–A549
Hibino T, Hashimoto A, Yano M, Suzuki M, Yoshida S, Sanob M (2002) High performance anodes for SOFCs operating in methane-air mixture at reduced temperatures. J Electrochem Soc 149:A133–A136
Zhang CM, Sun LL, Ran R, Shao ZP (2009) Activation of a single-chamber solid oxide fuel cell by a simple catalyst-assisted in-situ process. Electrochem Commun 11:1563–1566
Bay L, Horita T, Sakai N, Ishikawa M, Yamaji K, Yokokawa H (1998) Hydrogen solubility in Pr-doped and un-doped YSZ for a one chamber fuel cell. Solid State Ionics 113-115:363–367
Stefan IC, Jacobson CP, Visco SJ, De Jonghe LC (2004) Single chamber fuel cells: flow geometry, rate, and composition considerations. Electrochem Solid-State Lett 7:A198–A200
Morel B, Roberge R, Savoie S, Napporn TW, Meunier M (2009) Temperature and performance variations along single chamber solid oxide fuel cells. J Power Sources 186:89–95
Jacques-Bédard X, Napporn TW, Roberge R, Meunier M (2007) Coplanar electrodes Design for a Single-Chamber SOFC assessment of the operating parameters. J Electrochem Soc 154:B305–B309
Tian YT, Lü Z, Liu ML, Zhu XB, Wei B, Zhang YH, Huang XQ, Su WH (2013) Effect of gas supply method on the performance of the single-chamber SOFC micro-stack and the single cells. J Solid State Electrochem 17:269–275
Wei B, Lü Z, Huang XQ, Liu ML, Jia DC, Su WH (2009) A novel design of single-chamber SOFC micro-stack operated in methane-oxygen mixture. Electrochem Commun 11:347–350
Liu ML, Lü Z, Wei B, Huang XQ, Chen KF, Su WH (2009) A novel cell-Array Design for Single Chamber SOFC microstack. Fuel Cells 9(5):717–721
Liu ML, Qi X, Lv Z, Meng QY (2013) Effect of flow geometry on anode-supported single chamber SOFCs arrayed as V-shape. Int J Hydrog Energy 38:1976–1982
Hao Y, Goodwin DG (2008) Efficiency and fuel utilization of methane-powered single-chamber solid oxide fuel cells. J Power Sources 183:157–163
Funding
This study was supported by the National Natural Science Foundation of China (Nos. 51602213, 11604236, and 61575139) and the Youth Foundation of the Taiyuan University of Technology (No. 2015QN071).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Tian, Y., Lü, Z., Wang, Z. et al. Enhanced performance of a single-chamber solid oxide fuel cell with dual gas supply method. Ionics 25, 1281–1289 (2019). https://doi.org/10.1007/s11581-019-02893-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11581-019-02893-x