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Ionics

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CuFe2O4 magnetic nanoparticles to improve the ionic transfer properties of electrodialysis heterogeneous cation exchange membrane

  • S. M. HosseiniEmail author
  • M. Aliabadi Farahani
  • H. Khalili
  • B. Van der Bruggen
  • M. Nemati
  • Z. Rajabi
  • A. Ahmadi
Original Paper
  • 39 Downloads

Abstract

Mixed matrix polyvinyl chloride-copper ferrite nanoparticles cation exchange membranes were prepared by casting solution technique. The effect of CuFe2O4 nanoparticles concentration on electrochemical properties of prepared membranes was investigated. The CuFe2O4 nanoparticles were synthesized by chemical precipitation technique. The formation of copper ferrite nanoparticles was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and X-ray diffraction (XRD). Scanning microscopy images showed uniform distribution of particles in the membrane matrix. Membrane surface hydrophilicity and charge density, membranes potential, transport number (> 97%) and permselectivity (> 96%) were enhanced by using CuFe2O4 nanoparticles in the membrane body. Also, ion exchange capacity and cation flux were increased initially by utilizing CuFe2O4 nanoparticles up to 1 wt% in the casting solution and then followed by a decreasing trend by adding more concentration up to 8 wt%. The PVC-CuFe2O4 membranes displayed lower electrical resistance (< 4 Ω.Cm2) compared to unmodified ones.

Keywords

CuFe2O4 nanoparticles Heterogeneous membrane Electrochemical property Electrodialysis 

Notes

Funding information

This research is financially supported by Arak University.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • S. M. Hosseini
    • 1
    Email author
  • M. Aliabadi Farahani
    • 1
  • H. Khalili
    • 2
  • B. Van der Bruggen
    • 3
    • 4
  • M. Nemati
    • 1
  • Z. Rajabi
    • 1
  • A. Ahmadi
    • 2
  1. 1.Department of Chemical Engineering, Faculty of EngineeringArak UniversityArakIran
  2. 2.Department of Physics, Faculty of SciencesArak UniversityArakIran
  3. 3.Process Engineering for Sustainable Systems Section, Department of Chemical EngineeringUniversity of LeuvenLeuvenBelgium
  4. 4.Faculty of Engineering and the Built EnvironmentTshwane University of TechnologyPretoriaSouth Africa

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