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Preparation and application of malachite green molecularly imprinted/gold nanoparticle composite film–modified glassy carbon electrode

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Abstract

A kind of new malachite green (MG) polypyrrole (PPy) molecularly imprinted (MIP)/gold nanoparticle composite (AuNPs) film–modified glassy carbon electrode (MG-MIPPPy/AuNPs/GCE) was prepared by potentiostatic deposition of gold nanoparticle on glassy carbon electrode at − 0.2 V (vs. SCE) for 100 s, pyrrole (Py) as monomer, and MG as template molecule (molar ratio = 1:1) by cyclic voltammetry (CV) electropolymerization. And various modified electrodes were characterized by SEM and EIS and CV methods. Potassium ferricyanide was used as a probe; the concentration of MG was indirectly detected by the linear relationship between the current change value (ΔIDPV) and the logarithm value of concentration of MG. Under the optimal conditions, there was a linear relationship between the ΔIDPV and the negative logarithm of concentration in the range of 2.73 × 10−9 M ~ 2.74 × 10−6 M (R = 0.9961). The detection limit is 3.57 × 10−11 M (S/N = 3). The sample recovery was 98.82 to 103.38%. These analysis results of real samples were satisfactory.

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Author notes

  1. Wen Chen and Er Wang contributed equally to this work.

Authors and Affiliations

  1. College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu, 610059, Sichuan, People’s Republic of China

    Yaqing Xu, Wen Chen & Yan Li

  2. Mineral Resources Chemistry Key Laboratory of Sichuan Higher Education Institution, Chengdu, 610059, Sichuan, People’s Republic of China

    Yaqing Xu, Wen Chen & Yan Li

  3. Sichuan Provincial Chuanjian Institute of Investigation and Design, Chengdu, 610015, Sichuan, People’s Republic of China

    Zhiyue Gao

  4. Analysis Laboratory 280 Research Institute of Nuclear Industry, Guanghan, 618300, Sichuan, People’s Republic of China

    Er Wang

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  1. Yaqing Xu
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  2. Zhiyue Gao
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  3. Wen Chen
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  4. Er Wang
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  5. Yan Li
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Correspondence to Wen Chen or Er Wang.

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Xu, Y., Gao, Z., Chen, W. et al. Preparation and application of malachite green molecularly imprinted/gold nanoparticle composite film–modified glassy carbon electrode. Ionics 25, 1177–1185 (2019). https://doi.org/10.1007/s11581-018-2778-x

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  • DOI: https://doi.org/10.1007/s11581-018-2778-x

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