Abstract
Nanocrystalline FeMnO3 was synthesized by sol-gel method using succinic acid as a chelating agent. The structural and morphological characterizations of the synthesized material were carried out by using XRD, FT-IR, and SEM with EDX. The hysteresis loop at room temperature shows the antiferromagnetic behavior of the material. The variation in the frequency and temperature dependent dielectric constant illustrated the Maxwell-Wagner relaxation in the sample. Nyquist plot illustrated the grains resistance at higher frequency whereas at lower frequency it is dominated by the grain boundary resistance. The electrical modulus also confirms the relaxation process. The activation energy calculation of impedance and modulus shows the existence of oxygen vacancy. XPS analysis confirmed the existence of oxygen vacancy and different oxidation states of Fe3+/Fe2+ and Mn3+/Mn4+ in the material. Conductivity studies of the material were analyzed and fitted by using Jonscher Power law.
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References
Herranz T, Rojas S, Ojeda M, Perez Alonso FJ, Terreros P et al (2006) Synthesis, structural features, and reactivity of Fe-Mn mixed oxides prepared by microemulsion. Chem Mater 18:2364–2375
Li M, Xu W, Wang W, Liu Y, Cui B, Guo X (2014) Facile synthesis of specific FeMnO3 hollow sphere/graphene composites and their superior electrochemical energy storage performances for supercapacitor. J Power Sources 248:465–473
Lungu A, Malaescu I, Marin CN, Vlazan P, Sfirloaga P (2015) The electrical properties of manganese ferrite powders prepared by two different methods. Phys B Condens Matter 462:80–85
Rayaproln S, Kaushik SD (2015) Magnetic and magnetocaloric properties of FeMnO3. Ceram Int 41:9567–9571
Rezlescu a N, Rezlescu E, Popa PD, Doroftei C, Ignat M (2014) Characterization and catalytic properties of some perovskites. Compos Part B 60:515–522
Liu N, Yao KL, Gao GY, Liu JB (2013) First-principles study of the (001) surface of half-metallic cubic BaCrO3. J Magn Magn Mater 344:60–67
Hamdad N (2011) The ground states properties and the spin effect on the cubic and hexagonal perovskite manganese oxide BaMnO3: GGA+U calculation. Phys B Condens Matter 406(6):1194–1203
Seyfi B, Baghalha M, Kazeman H (2009) Modified LaCoO3 nano-perovskite catalysts for the environmental application of automotive CO oxidation. Chem Eng J 148(143):306–311
Chen W, Zhu W, Ke C, Yang Z, Wang L et al (2010) Impedance spectroscopy and conductivity mechanism of CoFe2O4–Pb(Zr0.53Ti0.47)O3 composite thick films. J Alloys Compd 508:141–146
Kumari N, Kumar V, Singh SK (2015) Structural, dielectric and magnetic investigations on Al3+ substituted Zn-ferrospinels. RSC Adv 5(47):37925–37934
Rahmounia H, Smarib M, Cherifa B, Dhahrib E, Khirounia K (2015) Conduction mechanism, impedance spectroscopic investigation and dielectric behavior of La0.5Ca0.5−xAgxMnO3 manganites with compositions below the concentration limit of silver solubility in perovskites (0≤ x≤ 0.2). Dalton Trans 44(22):10457–10466
Kool A, Thakur P, Bagchi B, Hoque NA, Banerjee S, Das S (2015) Sol–gel synthesis of transition-metal ion conjugated alumina-rich mullite nanocomposites with potential mechanical, dielectric and photoluminescence properties. RSC Adv 5(126):104299–104313
Lick ID, Soria DB (2009) Synthesis of MnFeO3 from the oxidative thermal decomposition of Mn[Fe(CN)5NO]·2H2O. J Argent Chem Soc 97(1):102–108
Mahnaz G, Malekzadeh A (2014) Structural features of (Ce, La or Sr)(Mn or Co)O3 nano-perovskites as a catalyst for carbon monoxide oxidation. Acta Metall Sin 27(4):635–641
Yuvaraj S, Nithya VD, Fathima KS, Sanjeeviraja C, Selvan GK, Arumugam S, Selvan RK (2013) Investigations on the temperature dependent electrical and magnetic properties of NiTiO3 by molten salt synthesis. Mater Res Bull 48(3):1110–1116
Akhtar MJ, Younas M (2012) Structural and transport properties of nanocrystalline MnFe2O4 synthesized by co-precipitation method. Solid State Sci 14(10):1536–1542
Belboukhari A, Choukri E, Gagou Y, Elmoznine R, Abdelmoula N, Neqali A, el Marssi M, Khemakhem H, Mezzane D (2014) Investigation on relaxation and conduction mechanism in Pb075K05Nb2O6 new ferroelectric ceramic. Superlattice Microst 71:7–22
Sahoo S, Dash U, Parashar SKS, Ali SM (2013) Frequency and temperature dependent electrical characteristics of CaTiO3 nano-ceramic prepared by high-energy ball milling. J Adv Ceram 2(3):291–300
Rahman MT, Ramana CV (2014) Impedance spectroscopic characterization of gadolinium substituted cobalt ferrite Impedance spectroscopic characterization of gadolinium substituted cobalt ferrite ceramics. J Appl Phys 164108:116
Kajewski D, Ujma Z (2010) Electrical properties of SrBi2(Nb0.5Ta0.5)2O9 ceramics. J Phys Chem Solids 71(1):24–29
Diez A, Schmidt R, Sagua AE, Frechero MA, Matesanz E et al (2010) Structure and physical properties of nickel manganite NiMn2O4 obtained from nickel permanganate precursor. J Eur Ceram Soc 30(12):2617–2624
Lobo LS and Kumar AR (2016) Investigation of structural and electrical properties of ZnMn2O4 synthesized by sol–gel method. J Mater Sci Mater Electron 27(7):7398–7406
Lobo LS, Kalainathan S, Kumar AR (2015) Investigation of electrical studies of spinel FeCo2O4 synthesized by sol–gel method. Superlattice Microst 88:116–126
Mandal PR, Nath TK (2015) Oxygen-vacancy and charge hopping related dielectric relaxation and conduction process in orthorhombic Gd doped YFe0.6Mn0.4O3 multiferroics. J Alloys Compd 628:379–389
Tang Q, Jiang L, Liu J, Wang S, Sun G (2014) Effect of surface manganese valence of manganese oxides on the activity of the oxygen reduction reaction in alkaline media. ACS Catal 4(2):457–463
Ding J, Zhong Q, Zhang S (2014) Simultaneous removal of NOX and SO2 with H2O2 over Fe based catalysts at low temperature. RSC Adv 4(11):5394–5398
Pham MH, Dinh CT, Vuong GT, Ta ND, Do TO (2014) Visible light induced hydrogen generation using a hollow photocatalyst with two cocatalysts separated on two surface sides. Phys Chem Chem Phys 16(13):5937–5941
Raghasudha M, Ravinder D, Veerasomaiah P (2013) FTIR studies and dielectric properties of Cr substituted cobalt Nano ferrites synthesized by citrate-gel method. Nanosci Nanotechnol 3(5):105–114
Pelaiz-Barranco A, Guerra JDS, Lopez-Noda R, Araujo EB (2008) Ionized oxygen vacancy-related electrical conductivity in (Pb1−xLax)(Zr0.90Ti0.10)1−x/4O3 ceramics. J Phys D Appl Phys 41(21):215503
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Authors are grateful to VIT University for providing major financial support and excellent research facilities. The authors also thank Prof. S. Kalainathan, VIT University for providing the facilities to carry out dielectric studies.
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Lobo, L.S., Rubankumar, A. Investigation on structural and electrical properties of FeMnO3 synthesized by sol-gel method. Ionics 25, 1341–1350 (2019). https://doi.org/10.1007/s11581-018-2776-z
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DOI: https://doi.org/10.1007/s11581-018-2776-z