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An AlOOH-coated polyimide electrospun fibrous membrane as a high-safety lithium-ion battery separator

  • Guobin Zhong
  • Yong Wang
  • Chao Wang
  • Zhonghui Wang
  • Song Guo
  • Lijuan Wang
  • Xin Liang
  • Hongfa XiangEmail author
Original Paper
  • 167 Downloads

Abstract

To improve the safety of lithium-ion batteries (LIBs), an AlOOH-coated polyimide (API) fibrous membrane as an inorganic composite separator is developed via an electrospinning technique and a subsequent blade-coating process. Benefiting from the good thermostability of polyimide and the flame-retarding property of AlOOH, the API separator shows excellent thermal stability and flame retardance. Compared with commercial polyolefin separator, the API separator exhibits superior electrolyte wettability and electrochemical stability. The Li||LiCoO2 cell using the API separator exhibits the enhanced cycling performance and rate capability. Thus, the as-prepared API separator is promising as a new kind of inorganic composite separator for advanced LIBs with high safety.

Keywords

Composite separator Polyimide Boehmite Safety Lithium-ion batteries 

Notes

Acknowledgments

This study was supported by the Science and Technology Projects of China Southern Power Grid (Grant No. GDKJQQ20152008).

Supplementary material

11581_2018_2716_MOESM1_ESM.pdf (1.9 mb)
ESM 1 (PDF 1910 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Guobin Zhong
    • 1
  • Yong Wang
    • 2
  • Chao Wang
    • 1
  • Zhonghui Wang
    • 2
  • Song Guo
    • 3
  • Lijuan Wang
    • 2
  • Xin Liang
    • 2
  • Hongfa Xiang
    • 2
    Email author
  1. 1.Electric Power Research Institute of Guangdong Power Grid Co., Ltd.GuangzhouChina
  2. 2.School of Materials Science and Engineering, Anhui Provincial Key Laboratory of Advanced Functional Materials and DevicesHefei University of TechnologyHefeiChina
  3. 3.School of Chemical EngineeringNanjing University of Science & TechnologyNanjingChina

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