Abstract
In this paper, a highly-active cobalt oxide (CoO) nanospheres catalyst has been synthesized by DC arc discharge plasma method and used as air electrode for lithium oxygen battery. Through scanning electron microscopy (SEM) observation, the particle size of the cobalt oxide (CoO) catalyst can be controlled between 40~60 nm and dispersed uniformly into the active material. And then the cobalt oxide (CoO) nanospheres mixed with La2O3 and Pt/C makes up the ternary catalyst of the air electrode for lithium oxygen battery. The electrochemical test results show that the oxygen reduction reaction peaks are more obvious, and the increase of charge transfer rate has no significant influence on the diffusion mass transfer rate. The specific capacity and energy density of air electrode with Co-La-Pt ternary catalyst can respectively reach 3250.2 mAh g−1 and 8574.2 Wh kg−1 at 0.025 mA cm−2. After 62 cycles, 38.3% of the initial capacity can still be maintained.
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Zhang X, Zhong X, Xu W, Li X, Liu W, Lin Y (2018) Preparation and electrochemical properties of Li4Ti5O12/Ti4O7 composite for lithium-ion batteries. Ionics 24:379–384
Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM (2012) Li-O2 and Li-S batteries with high energy storage. Nat Mater 11:19–29
Jung HG, Hassoun J, Park JB, Sun YK, Scrosati B (2012) An improved high-performance lithium–air battery. Nat Chem 4:579–585
Hu Y, Wang ZL (2015) Recent progress in piezoelectric nanogenerators as a sustainable power source in self-powered systems and active sensors. Nano Energy 14:3–14
Liu Y, Cheng M, Guo X, Wu Z, Chen Y, Xiang W, Li J, Zhong B (2017) Synthesis and electrochemical performance of micro-mesoporous carbon-sulfur composite cathode for Li-S batteries. Ionics 23:2951–2960
Tan A, Reddy MV, Adams S (2017) Synthesis and application of nanostructured MCo2O4 (M=Co,Ni) for hybrid Li-air batteries. Ionics 23:2589–2602
Strubel P, Thieme S, Biemelt T, Helmer A, Oschatz M, Brückner J, Althues H, Kaskel S (2015) Hard templating for synthesis of hierarchical porous carbons with tailored porosity and high performance in lithium-sulfur battery. Adv Funct Mater 25:287–297
Palomares V, Serras P, Villaluenga I, Hueso KB, Carretero-González J, Rojo T (2012) Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ Sci 5:5884–5901
Jadhav HS, Kalubarme RS, Jadhav AH, Seo JG (2016) Iron-nickel spinel oxide as an electrocatalyst for non-aqueous rechargeable lithium-oxygen batteries. J Alloys Compd 666:476–481
Lu Y, S f T, Qiu FL, Jiang J, Feng NN, Zhang XP, He P, Zhou HS (2016) Exploration of LiO2 by the method of electrochemical quartz crystal microbalance in TEGDME based Li-O2 battery. J Power Sources 329:525–529
Crowther O, Keeny D, Moureau DM, Meyer B, Salomon M, Hendrickson M (2012) Electrolyte optimization for the primary lithium metal air battery using an oxygen selective membrane. J Power Sources 202(1):347–351
Laino T, Curioni A (2013) Chemical reactivity of aprotic electrolytes on a solid Li2O2 surface: screening solvents for Li-air batteries. New J Phys 15(12):534–541
Yu L, Shen Y, Huang Y (2014) Fe-N-C catalyst modified graphene sponge as a cathode material for lithium-oxygen battery. J Alloys Compd 595:185–191
Zhang M, Takahashi K, Uechi I, Takeda Y, Yamamoto O, Im D, Lee DJ, Chi B, Pu J, Imanishi N (2013) Water-stable lithium anode with Li1.4Al0.4Ge1.6(PO4)3–TiO2 sheet prepared by tape casting method for lithium-air batteries. J Power Sources 235:117–121
Safanama D, Adams S (2017) High efficiency aqueous and hybrid lithium-air batteries enabled by Li1.5Al0.5Ge1.5(PO4)3 ceramic anode-protecting membranes. J Power Sources 340:294–301
Black R, Lee JH, Adams B, Mims CA, Nazar LF (2012) The role of catalysts and peroxide oxidation in lithium-oxygen batteries. Angew Chem Int Ed 52:392–396
Sun N, Liu H, Yu Z, Zheng Z, Shao C (2016) The electrochemical performance of La0.6Sr0.4Co1-xNixO3 perovskite catalysts for Li-O2 batteries. Ionics 22:869–876
Sevim M, Francia C, Amici J, Vankova S, Sener T, Metin Ö (2016) Bimetallic MPt (M: Co,Cu,Ni) alloy nanoparticle assembled on reduced graphene oxide as high performance cathode catalysts for rechargeable lithium-oxygen batteries. J Alloys Compd 683:231–240
Liu J, Zhao Y, Li X, Wang C, Zeng Y, Yue G, Chen Q (2018) CuCr2O4@rGo Nanocomposites as high-performance cathode catalyst for rechargeable lithium-oxygen batteries. Nano-Micro Lett 10:22
Wei ZH, Zhao TS, Zhu XB, Tan P (2016) MnO2-x nanosheets on stainless steel felt as a carbon-and binder-free cathode for non-aqueous lithium-oxygen batteries. J Power Sources 306:724–732
Shao Y, Park S, Xiao J, Zhang JG, Wang Y, Liu J (2012) Electrocatalysts for nonaqueous lithium–air batteries: status, challenges, and perspective. ACS Catal 2:844–857
Mirzaeian M, Hall PJ (2009) Preparation of controlled porosity carbon aerogels for energy in rechargeable lithium oxygen batteries. Electrochim Acta 54:7444–7451
Tong S, Zheng M, Lu Y, Lin Z, Li J, Zhang X, Shi Y, Zhou H (2015) Mesoporous NiO with a single-crystalline structure utilized as a noble metal-free catalyst for non-aqueous Li–O2 batteries. J Mater Chem A 3:16177–16182
Zhang GQ, Zheng JP, Liang R, Zhang C, Wang B, Hendrichson MA, Plichta EJ (2011) α-MnO2/carbon nanotube/carbon nanofiber composite catalytic air electrodes for rechargeable lithium-air batteries. J Electrochem Soc 158:A822–A827
Do JS, Weng CH (2005) Preparation and characterization of CoO used as anodic material of lithium battery. J Power Sources 146:482–486
Khajehbashi SMB, Li J, Wang M, Wang M, Xu L, Zhao K, Wei Q, Shi C, Tang C, Huang L, Wang Z, Mai L (2017) A crystalline/amorphous cobalt (II ,III) oxide hybrid electrocatalyst tor lithium-air batteries. Energy Technol 5:568–579
Wang B, Abdulla WA, Wang D, Zhao XS (2015) A three-dimensional porous LiFePO4 cathode material modified with a nitrogen-doped graphene aerogel for high-power lithium ion batteries. Energy Environ Sci 8:869–875
Wang B, Xie Y, Liu T, Luo H, Wang B, Wang C, Wang L, Wang D, Dou S, Zhou Y (2017) LiFePO4 quantum-dots composite synthesized by a general microreactor strategy for ultra-high-rate lithium ion batteries. Nano Energy 42:363–372
Wang B, Liu T, Liu A, Liu G, Wang L, Gao T, Wang D, Zhao XS (2016) A hierarchical porous C@LiFePO4/carbon nanotubes microsphere composite for high-rate lithium-ion batteries: combined experimental and theoretical study. Adv Energy Mater 6:1600426
Funding
This work was supported by the National Natural Science Foundation of China (No. 21373002), the Natural Science Foundation of Liaoning Province of China (No.20170540021), the Project of Education Department of Liaoning Province of China (No.LF2017004, LQ2017014), and the Liaoning BaiQianWan Talents Program (No. 201797).
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Lang, X., Zhang, Y., Cai, K. et al. High performance CoO nanospheres catalyst synthesized by DC arc discharge plasma method as air electrode for lithium-oxygen battery. Ionics 25, 35–40 (2019). https://doi.org/10.1007/s11581-018-2588-1
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DOI: https://doi.org/10.1007/s11581-018-2588-1