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Hierarchical Co3O4@C hollow microspheres with high capacity as an anode material for lithium-ion batteries

Ionics volume 24, pages 3757–3769 (2018)Cite this article

Abstract

Three-dimensional hierarchical Co3O4@C hollow microspheres (Co3O4@C HSs) are successfully fabricated by a facile and scalable method. The Co3O4@C HSs are composed of numerous Co3O4 nanoparticles uniformly coated by a thin layer of carbon. Due to its stable 3D hierarchical hollow structure and uniform carbon coating, the Co3O4@C HSs exhibit excellent electrochemical performance as an anode material for lithium-ion batteries (LIBs). The Co3O4@C HSs electrode delivers a high reversible specific capacity, excellent cycling stability (1672 mAh g−1 after 100 cycles at 0.2 A g−1 and 842.7 mAh g−1 after 600 cycles at 1 A g−1), and prominent rate performance (580.9 mAh g−1 at 5 A g−1). The excellent electrochemical performance makes this 3D hierarchical Co3O4@C HS a potential candidate for the anode materials of the next-generation LIBs. In addition, this simple synthetic strategy should also be applicable for synthesizing other 3D hierarchical metal oxide/C composites for energy storage and conversion.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (grant no. 21303270), Hunan Provincial Natural Science Foundation of China (grant no. 2018JJ2485), Hunan Provincial Science and Technology Plan Project (grant nos. 2017TP1001 and 2016TP1007), Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of P. R. China (grant no. 2013[1792]), and Innovation-Driven Project of Central South University (grant no. 2016CXS031).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan, 410083, People’s Republic of China

    Ziqin Xu, Kuangmin Zhao, Qingmeng Gan, Suqin Liu & Zhen He

  2. Innovation Base of Energy and Chemical Materials for Graduate Students Training, Central South University, Changsha, Hunan, 410083, People’s Republic of China

    Ziqin Xu, Kuangmin Zhao & Qingmeng Gan

  3. Hunan Provincial Key Laboratory of Chemical Power Sources, Central South University, Changsha, Hunan, 410083, People’s Republic of China

    Suqin Liu & Zhen He

  4. Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University, Changsha, Hunan, 410083, People’s Republic of China

    Suqin Liu & Zhen He

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  1. Ziqin Xu
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Xu, Z., Zhao, K., Gan, Q. et al. Hierarchical Co3O4@C hollow microspheres with high capacity as an anode material for lithium-ion batteries. Ionics 24, 3757–3769 (2018). https://doi.org/10.1007/s11581-018-2554-y

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