, Volume 24, Issue 11, pp 3431–3437 | Cite as

Flower-like MoS2 supported on three-dimensional graphene aerogels as high-performance anode materials for sodium-ion batteries

  • Yu Wang
  • Yuhong Jin
  • Shubo Li
  • Jiying Han
  • Zhendong Ju
  • Mengqiu Jia
Original Paper


Flower-like MoS2 supported on three-dimensional graphene aerogel (MoS2/GA) composite has been prepared by a facile hydrothermal method followed by subsequent heat-treatment process. Each of MoS2 microflowers is surrounded by the three-dimensional graphene nanosheets. The MoS2/GA composite is applied as an anode material of sodium-ion batteries (SIBs) and it exhibits high initial discharge/charge capacities of 562.7 and 460 mAh g−1 at a current density of 0.1 A g−1 and good cycling performance (348.6 mAh g−1 after 30 cycles at 0.1 A g−1). The good Na+ storage properties of the MoS2/GA composite could be attributed to the unique structure which flower-like MoS2 are homogeneously and tightly decorated on the surface of three-dimensional graphene aerogel. Our results demonstrate that as-prepared MoS2/GA composite has a great potential prospect as anodes for SIBs.


MoS2 Graphene aerogel Anode materials Sodium-ion batteries 


  1. 1.
    Xiao Y, Lee SH, Sun YK (2016) The application of metal sulfides in sodium ion batteries. Adv Energy Mater:1601329CrossRefGoogle Scholar
  2. 2.
    Zhang X, Lai ZC, Tan CL, Zhang H (2016) Solution-processed two-dimensional MoS2 nanosheets: preparation, hybridization, and applications. Angew Chem Int Ed 55:8816–8838CrossRefGoogle Scholar
  3. 3.
    Hu Z, Wang LX, Zhang K, Wang JB, Cheng FY, Tao ZL, Chen J (2014) MoS2 nanoflowers with expanded interlayers as high-performance anodes for sodium-ion batteries. Angew Chem 126:13008–13012CrossRefGoogle Scholar
  4. 4.
    Ma GY, Huang KS, Zhuang QC, Ju ZC (2016) Superior cycle stability of nitrogen-doped graphene nanosheets for Na-ion batteries. Mater Lett 174:221–225CrossRefGoogle Scholar
  5. 5.
    Zhou KQ, Zhen YC, Hong ZS, Guo JH, Huang ZG (2017) Enhanced sodium ion batteries performance by the phase transition from hierarchical Fe2O3 to Fe3O4 hollow nanostructures. Mater Lett 190:52–55CrossRefGoogle Scholar
  6. 6.
    Wang J, Luo C, Gao T, Langrock A, Mignerey A, Wang C (2015) An advanced MoS2/carbon anode for high-performance sodium-ion batteries. Small 11:473–481CrossRefPubMedGoogle Scholar
  7. 7.
    Stephenson T, Li Z, Olsenab B, Mitlin D (2014) Lithium ion battery applications of molybdenum disulfide (MoS2) nanocomposites. Energy Environ Sci 7:209–231CrossRefGoogle Scholar
  8. 8.
    Sun N, H Liu BX (2015) Facile synthesis of high performance hard carbon anode materials for sodium ion batteries. J Mater Chem A 3:20560–20566CrossRefGoogle Scholar
  9. 9.
    Xu B, Wang HR, Zhu QZ, Sun N, Anasori B, Hu LF, Wang F, Guan YB, Gogotsi Y (2018) Reduced graphene oxide as a multi-functional conductive binder for supercapacitor electrodes. Energy Storage Mater 12:128–136CrossRefGoogle Scholar
  10. 10.
    Liu H, Jia MQ, Cao B, Chen RJ, Lv XY, Tang RJ, Wu F, Xu B (2016) Nitrogen-doped carbon/graphene hybrid anode material for sodium-ion batteries with excellent rate capability. J Power Sources 319:195–201CrossRefGoogle Scholar
  11. 11.
    Liu H, Jia MQ, Zhu QZ, Cao B, Chen RJ, Wang Y, Wu F, Xu B (2016) 3D-0D graphene-Fe3O4 quantum dot hybrids as high-performance anode materials for sodium-ion batteries. ACS Appl Mater Interfaces 8:26878–26885CrossRefGoogle Scholar
  12. 12.
    Liu H, Jia MQ, Yue SF, Cao B, Zhu QZ, Sun N, Xu B (2017) Creative utilization of natural nanocomposites: nitrogen-rich mesoporous carbon for high performance sodium ion battery. J Mater Chem A 5:9572–9579CrossRefGoogle Scholar
  13. 13.
    Wang TY, Chen SQ, Pang HP, Xue HG, Yu Y (2017) MoS2-based nanocomposites for electrochemical energy storage. Adv Sci:1600289CrossRefPubMedGoogle Scholar
  14. 14.
    Choi SH, Ko YN, Lee JK, Kang YC (2015) 3D MoS2-graphene microspheres consisting of multiple nanospheres with superior sodium ion storage properties. Adv Funct Mater 25:1780–1788CrossRefGoogle Scholar
  15. 15.
    Xiang JY, Dong DD, Wen FS, Zhao J, Zhang XY, Wang LM, Liu ZY (2016) Microwave synthesized self-standing electrode of MoS2 nanosheets assembled on graphene foam for high-performance Li-Ion and Na-Ion batteries. J Alloys Comp 660:11–16CrossRefGoogle Scholar
  16. 16.
    Wang YX, Chou SL, Wexler D, Liu HK, Dou SX (2014) High-performance sodium-ion batteries and sodium-ion pseudocapacitors based on MoS2/graphene composites. Chem Eur J 20:9607–9612CrossRefGoogle Scholar
  17. 17.
    Xie X, Ao Z, Su D, Zhang J, Wang G (2015) MoS2/graphene composite anodes with enhanced performance for sodium-ion batteries: the role of the two-dimensional heterointerface. Adv Funct Mater 25:1393–1403CrossRefGoogle Scholar
  18. 18.
    Hummers WS, Offeman RE (1958) The preparation of graphite oxide. J Am Chem Soc 80:1339CrossRefGoogle Scholar
  19. 19.
    Sun TH, Li ZP, Liu XH, Ma LM, Wang JQ, Yang SG (2016) Facile construction of 3D graphene/MoS2 composites as advanced electrode materials for supercapacitors. J Power Sources 331:180–188CrossRefGoogle Scholar
  20. 20.
    Liu H, Jia M, Sun N, Cao B, Chen R, Zhu Q, Wu F, Qiao N, Xu B (2015) Nitrogen-rich mesoporous carbon as anode material for high-performance sodium-ion batteries. ACS Appl Mater Interfaces 7:27124–27130CrossRefGoogle Scholar
  21. 21.
    Qin W, Chen TQ, Pan LK, Niu LY, Hu BW, Li DS, Li JL, Sun Z (2015) MoS2-reduced graphene oxide composites via microwave assisted synthesis for sodium ion battery anode with improved capacity and cycling performance. Electrochim Acta 153:55–61CrossRefGoogle Scholar
  22. 22.
    Pan FS, Wang JQ, Yang ZZ, Gu L, Yu Y (2015) MoS2-graphene nanosheet-CNT hybrids with excellent electrochemical performances for lithium-ion batteries. RSC Adv 5:77518–77526CrossRefGoogle Scholar
  23. 23.
    He JR, Lia PJ, Lv WQ, Wen KC, Chen YF, Zhang WL, Lia YR, Qin W, He WD (2016) Three-dimensional hierarchically structured aerogels constructed with layered MoS2/graphene nanosheets as free-standing anodes for high-performance lithium ion batteries. Electrochim Acta 215:12–18CrossRefGoogle Scholar
  24. 24.
    Long H, Trochimczyk AH, Pham T, Tang ZR, Shi TL, Zettl A, Carraro C, Worsley MA, Maboudian R (2016) High surface area MoS2/graphene hybrid aerogel for ultrasensitive NO2 detection. Adv Funct Mater 26:5158–5165CrossRefGoogle Scholar
  25. 25.
    Zhou GM, Wang DW, Yin LC, Li N, Li F, Cheng HM (2012) Oxygen bridges between NiO nanosheets and graphene for improvement of lithium storage. ACS Nano 6:3214–3223CrossRefPubMedGoogle Scholar
  26. 26.
    Zhao B, Wang ZX, Gao Y, Chen L, Lu MN, Jiao Z, Jiang Y, Ding YZ, Cheng LL (2016) Hydrothermal synthesis of layer-controlled MoS2/graphene composite aerogels for lithium-ion battery anode materials. Appl Surf Sci 390:209–215CrossRefGoogle Scholar
  27. 27.
    Qin W, Chen TQ, Pan LK, Niu LY, Hu BW, Li DS, Li JL, Sun Z (2015) MoS2-reduced graphene oxide composites via microwave assisted synthesis for sodium ion battery anode with improved capacity and cycling performance. Electrochim Acta 153:55–61CrossRefGoogle Scholar
  28. 28.
    Sahu TS, Mitra S (2015) Exfoliated MoS2 sheets and reduced graphene oxide an excellent and fast anode for sodium-ion battery. Sci Rep 5:12571CrossRefPubMedGoogle Scholar
  29. 29.
    Xiong FY, Cai ZY, Qu LB, Zhang PF, Yuan ZF, Asare OK, Xu WW, Lin C, Mai LQ (2015) Three-dimensional crumpled reduced graphene oxide/MoS2 nanoflowers: a stable anode for lithium-ion batteries. ACS Appl Mater Interfaces 7:12625–12630CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Beijing Key Laboratory of Electrochemical Process and Technology for MaterialsBeijing University of Chemical TechnologyBeijingChina
  2. 2.Beijing Guyue New Materials Research InstituteBeijing University of TechnologyBeijingChina

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