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Ionics

, Volume 24, Issue 4, pp 1221–1226 | Cite as

Enhanced efficiency in dye-sensitized solar cell based on zinc oxide-modified poly(ethylene oxide) gel electrolyte

  • X. H. Chan
  • M. H. Khanmirzaei
  • Fatin Saiha Omar
  • K. Ramesh
  • S. Ramesh
  • S. Ramesh
Original Paper

Abstract

Gel polymer electrolytes (GPEs) are more preferable than liquid electrolyte for dye-sensitized solar cells (DSSCs) due to several advantages. However, GPEs have poor ionic conductivity which renders the low efficiency of DSSCs. GPE systems based on poly(ethylene oxide) (PEO) as host polymer, sodium iodide (NaI) salt, and various amount of zinc oxide (ZnO) (1, 3, 5, and 7 wt%) were prepared and optimized. The highest ionic conductivity obtained for these systems was 7.05 × 10−3 S cm−1 for the GPE at 5 wt% of ZnO. The formation of structural features and complexes of the materials have been confirmed by Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). Under the illumination of AM 1.5 (100 mW cm−2), the fabricated DSSCs (with an arrangement of FTO glass/TiO2/N719dye/electrolyte/Pt/FTO glass) achieved the maximum power conversion efficiency of 6.94%, with a maximum short-circuit current density (J SC) of 18.75 mA cm−2, open-circuit voltage (V OC) of 0.666 mV, and fill factor (FF) of 55.6%.

Keywords

Gel polymer electrolyte Dye-sensitized solar cell Nanofiller ZnO PEO 

Notes

Acknowledgements

This work is financially supported by Fundamental Research Grant Scheme (FP012-2015A), from the Ministry of Education, Malaysia.

References

  1. 1.
    Kamat PV (2007) Meeting the clean energy demand: nanostructure architectures for solar energy conversion. J Phys Chem C 111:2834–2860CrossRefGoogle Scholar
  2. 2.
    Goetzberger A, Luther J, Willeke G (2002) Solar cells: past, present, future. Sol Energy Mater Sol Cells 74:1–11CrossRefGoogle Scholar
  3. 3.
    Kim J, Duraisamy N, Lee T-M et al (2014) Hybrid electrohydrodynamic atomization of nanostructured silver top contact for inverted organic solar cells. Sol Energy Mater Sol Cells 130:156–162CrossRefGoogle Scholar
  4. 4.
    Dissanayakea MAKL, Thotawatthagea CA, Senadeera GKR et al (2012) Efficiency enhancement by mixed cation effect in dye-sensitized solar cells with PAN based gel polymer electrolyte. J Photochem Photobiol A Chem 246:29–35CrossRefGoogle Scholar
  5. 5.
    Wang Y (2009) Recent research progress on polymer electrolytes for dye-sensitized solar cells. Sol Energy Mater Sol Cells 93:1167–1175CrossRefGoogle Scholar
  6. 6.
    Kim JH, Kang M-S, Kim YJ et al (2004) Dye-sensitized nanocrystalline solar cells based on composite polymer electrolytes containing fumed silica nanoparticles. Chem Commun 14:1662–1663CrossRefGoogle Scholar
  7. 7.
    Prabakaran K, Mohanty S, Nayak SK (2015) PEO/PVdF–HFP electrolytes for natural dye sensitized solar cell applications: effect of modified nano-TiO2 on electrochemical and photovoltaic performance. J Mater Sci Mater Electron 26:3887–3897CrossRefGoogle Scholar
  8. 8.
    Farhana NK, Khanmirzaei MH, Omar FS et al (2017) Ionic conductivity improvement in poly (propylene) carbonate-based gel polymer electrolytes using 1-butyl-3-methylimidazolium iodide (BmimI) ionic liquid for dye-sensitized solar cell application. Ionics (Kiel) 23:1601–1605CrossRefGoogle Scholar
  9. 9.
    Tang C, Hackenberg K, Fu Q et al (2012) High ion conducting polymer nanocomposite electrolytes using hybrid nanofillers. Nano Lett 12:1152–1156CrossRefGoogle Scholar
  10. 10.
    Omar FS, Ming HN, Hafiz SM, Ngee LH (2014) Microwave synthesis of zinc oxide/reduced graphene oxide hybrid for adsorption-photocatalysis application. Int J Photoenergy 176835:1–8Google Scholar
  11. 11.
    Ramasamy P, Lim D-H, Kim J, Kim J (2014) A general approach for synthesis of functional metal oxide nanotubes and their application in dye-sensitized solar cells. RSC Adv 4:2858–2864CrossRefGoogle Scholar
  12. 12.
    Wang ZL (2004) Zinc oxide nanostructures: growth, properties and applications. J Phys Condens Matter 16:R829–R858CrossRefGoogle Scholar
  13. 13.
    Sellam HSA (2012) Enhanced zinc ion transport in gel polymer electrolyte: effect of nano-sized ZnO dispersion. J Solid State Electrochem 16:3105–3114CrossRefGoogle Scholar
  14. 14.
    Omar FS, Numan A, Duraisamy N et al (2016) Ultrahigh capacitance of amorphous nickel phosphate for asymmetric supercapacitor applications. RSC Adv 6:76298–76306CrossRefGoogle Scholar
  15. 15.
    Chong MY, Numan A, Liew C-W et al (2016) Comparison of the performance of copper oxide and yttrium oxide nanoparticle based hydroxylethyl cellulose electrolytes for supercapacitors. J Appl Polym Sci 134:44636Google Scholar
  16. 16.
    Sundararajan V, Selvaraj G, Ng HM et al (2017) Exploring the effect of novel N-butyl-6-methylquinolinium bis(trifluoromethylsulfonyl)imide ionic liquid addition to poly(methyl methacrylate-co-methacrylic) acid electrolyte system as employed in gel-state dye sensitized solar cells. Electrochim Acta 240:361–370CrossRefGoogle Scholar
  17. 17.
    Chang W-C, Sian-Yang S, Wan-Chin Y et al (2016) Preparation of nano-composite gel electrolytes with metal oxide additives for dye-sensitized solar cells. Electrochem Acta 212:333–342CrossRefGoogle Scholar
  18. 18.
    Duraisamy N, Ju-HyungYun KJ (2015) Effect of surficial length on transparent conductor-coated Si pillar arrays. Mater Express 5:261–267CrossRefGoogle Scholar
  19. 19.
    Ramesh S, Yuen TF, Shen CJ (2008) Conductivity and FTIR studies on PEO–LiX [X: CF3SO3−, SO4 2−] polymer electrolytes. Spectrochim Acta Part A Mol Biomol Spectrosc 69:670–675CrossRefGoogle Scholar
  20. 20.
    Rajammal K, Sivakumar D, Duraisamy N, et al (2017) Influences of sintering temperatures and crystallite sizes on electrochemical properties of LiNiPO4 as cathode materials via sol–gel route for lithium ion batteries. J Sol-Gel Sci Technol 83:12–18Google Scholar
  21. 21.
    Fatin SO, Lim HN, Tan WT, Huang NM (2012) Comparison of photocatalytic activity and cyclic voltammetry of zinc oxide and titanium dioxide nanoparticles toward degradation of methylene blue. Int J Electrochem Sci 7:9074–9084Google Scholar
  22. 22.
    Zebardastan N, Khanmirzaei MH, Ramesh S, Ramesh K (2016) Novel poly(vinylidene fluoride-co-hexafluoro propylene)/polyethylene oxide based gel polymer electrolyte containing fumed silica (SiO2) nanofiller for high performance dye-sensitized solar cell. Electrochim Acta 220:1–8CrossRefGoogle Scholar
  23. 23.
    Prabakaran K, Mohanty S, Nayak SK (2015) Improved electrochemical and photovoltaic performance of dye sensitized solar cells based on PEO/PVDF–HFP/silane modified TiO2 electrolytes and MWCNT/Nafion ® counter electrode. RSC Adv 5:40491–40504CrossRefGoogle Scholar
  24. 24.
    Shi Y, Wang Y, Zhang M, Dong X (2011) Influences of cation charge density on the photovoltaic performance of dye-sensitized solar cells: lithium, sodium potassium, and dimethylimidazolium. Phys Chem Chem Phys 13:14590–14597CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany 2017

Authors and Affiliations

  • X. H. Chan
    • 1
  • M. H. Khanmirzaei
    • 1
  • Fatin Saiha Omar
    • 1
  • K. Ramesh
    • 1
  • S. Ramesh
    • 1
  • S. Ramesh
    • 2
  1. 1.Centre for Ionics University of Malaya, Department of Physics, Faculty of ScienceUniversity of MalayaKuala LumpurMalaysia
  2. 2.Centre of Advanced Manufacturing and Material Processing, Department of Mechanical Engineering, Faculty of EngineeringUniversity of MalayaKuala LumpurMalaysia

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