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Ionics

, Volume 24, Issue 4, pp 1039–1048 | Cite as

Si/polyaniline-based porous carbon composites with an enhanced electrochemical performance as anode materials for Li-ion batteries

  • Shuo Zhao
  • Cong Yao
  • Leiming Sun
  • Xiaochao Xian
Original Paper
  • 237 Downloads

Abstract

Silicon/polyaniline-based porous carbon (Si/PANI-AC) composites have been prepared by a three-step method: coating polyaniline on Si particles using in situ polymerization, carbonizing, and further activating by steam. The morphology and structure of Si/PANI-AC composites have been characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and Raman spectra, respectively. The content and pore structure of the carbon coating layer in Si/PANI-AC have been measured by thermogravimetric analysis and N2 adsorption-desorption isotherm, respectively. The results indicate some micropores about 1~2 nm in the carbon layer appear during activation and that crystal structure and morphology of Si particles can be retained during preparation. Si/PANI-AC composites exhibit high discharge capacity about 1000 mAh g−1 at 1.5 A g−1; moreover, when the current density returns to 0.2 A g−1, the discharge capacity is still 1692 mAh g−1 and remains 1453 mAh g−1 after 70 cycles. The results indicate that the porous carbon coating layer in composites plays an important role in the improvement of the electrochemical performance of pure Si.

Keywords

Silicon/polyaniline-based porous carbon Composites Steam activation Electrochemical performance Li-ion batteries 

Notes

Acknowledgements

The authors are grateful to the Fundamental Research Funds for the Central Universities (no. CQDXWL-2014-Z008) and the Chongqing Foundation and Advanced Research Projects (no. cstc2016jcyjA0462) for financial assistance.

Supplementary material

11581_2017_2258_MOESM1_ESM.doc (822 kb)
ESM 1 (DOC 821 kb)

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Copyright information

© Springer-Verlag GmbH Germany 2017

Authors and Affiliations

  1. 1.School of Chemistry and Chemical EngineeringChongqing UniversityChongqingPeople’s Republic of China

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