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Mn-doped Bi26Mo10O69-d: synthesis and characterization

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Abstract

In this work, we research two series of Mn-substituted bismuth molybdates: Bi26-2xMn2xMo10O69-d and Bi26Mo10-2yMn2yO69-d. The synthesis of powder samples is performed by the conventional solid state technology. Samples are characterized by X-ray diffraction, scanning electron microscopy, and chemical analysis methods, and it is shown that single phase Bi26-2xMn2xMo10O69-d and Bi26Mo10-2yMn2yO69-d complex oxides form up to x = 0.8 and y = 0. We use densitometry, grain size measurements and scanning electron microscopy to study the morphology of ceramic pellets and powders. This issue reveals formation of dense ceramic samples with low porosity (≤3%). High-temperature X-ray diffraction is used to define small deviation of unit cell parameters from their linear dependence on temperature. Measurement of electrical conductivity is made using a.c. impedance spectroscopy method. We observe the decrease of electrical conductivity in Bi26-2xMn2xMo10O69-d series depending on dopant concentration.

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Acknowledgements

This work was financially supported by the Russian Foundation for Basic Research (project No 16-33-60026) and Ministry of Education and Science (grant of President of Russia № МК-7979.2016.3). XRPD data were obtained using the equipment of the Centre for Shared Use ‘Ural-M’

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Authors and Affiliations

  1. Chemistry Department, Ural Federal University, 51 Lenin Ave, 620000, Ekaterinburg, Russia

    Z. A. Mikhaylovskaya, E. S. Buyanova & M.V. Morozova

  2. Institute for Metallurgy, Ural Branch of the Russian Academy of Sciences, 101 Amundsen str, 620016, Ekaterinburg, Russia

    S. A. Petrova

  3. Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomayskaya str, 620990, Ekaterinburg, Russia

    I. V. Nikolaenko

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  1. Z. A. Mikhaylovskaya
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  2. E. S. Buyanova
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  3. M.V. Morozova
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  4. S. A. Petrova
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  5. I. V. Nikolaenko
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Correspondence to Z. A. Mikhaylovskaya.

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Mikhaylovskaya, Z.A., Buyanova, E.S., Morozova, M. et al. Mn-doped Bi26Mo10O69-d: synthesis and characterization. Ionics 23, 1107–1114 (2017). https://doi.org/10.1007/s11581-016-1917-5

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