Abstract
Exploration of high-rate lithium-ion batteries (LIBs) still remains a great challenge because of the ineffective charge transfer in electrode materials. In this work, the one-dimensional (1D)-2D coupled composites consisted of CoMoO4 nanorods and graphene sheets are developed as high-rate LIBs anode materials. The composites are well characterized with powder X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), thermogravimetric analysis (TGA), and Raman spectrum. Endowed with the structural advantages, the present sample exhibits remarkably enhanced electrochemical properties, such as the best high-rate performance for CoMoO4-based electrode materials so far (646 mAh g−1 at 5 A g−1 after 200 cycles), excellent rate capability, and stable cyclability.
References
Tarascon JM, Armand M (2001) Nature 414:359
Nishide H, Oyaizu K (2008) Science 319:737
Wang Y, Yi J, Xia Y (2012) Adv Energy Mater 2:830
Bruce PG, Scrosati B, Tarascon JM (2008) Anger Chem Int Ed 47:2930
Chen JS, Archer LA, Lou XW (2011) J Mater Chem 21:9912
Zhang X, Chen H, Xie Y, Guo J (2014) J Mater Chem A 2:3912
Sun YK, Chen Z, Noh HJ, Lee DJ, Jung HG, Ren Y, Wang S, Yoon CS, Myung ST, Amine K (2012) Nat Mater 11:942
Vu A, Qian Y, Stein A (2012) Adv Energy Mater 2:1056
Reddy MV, Subba Rao GV, Chowdari BVR (2013) Chem Rev 113:5364
Guo ZY, Zhou DD, Dong XL, Qiu ZJ, Wang Y, Xia Y (2013) Adv Mater 25:5668
Guo J, Jiang B, Zhang X, Liu H (2014) J Power Sources 262:15
Zhang L, Wu HB, Liu B, Lou XW (2014) Energy Environ Sci 7:1013
Yuan C, Wu HB, Xie Y, Lou XW (2014) Angew Chem Int Ed 53:1488
Rai AK, Gim J, Thi TV, Ahn D, Cho SJ, Kim J (2014) J Phys Chem C 118:11234
Bresser D, Paillard E, Kloepsch R, Krueger S, Fiedler M, Schmitz R, Baither D, Winter M, Passerini S (2013) Adv Energy Mater 3:513
Cherian CT, Reddy MV, Haur SC, Chowdari BVR (2013) ACS Appl Mater Interfaces 5:918
Yu H, Guan C, Rui X, Ouyang B, Yadian B, Huang Y, Zhang H, Hoster HR, Fan HJ, Yan Q (2014) Nanoscale 6:10556
Ko YN, Kang YC, Park SB (2014) RSC Adv 4:17873
Yao J, Gong Y, Yang S, Xiao P, Zhang Y, Keyshar K, Ye G, Ozden S, Vajtai R, Ajayan PM (2014) ACS Appl Mater Interfaces 6:20414
Guo J, Sun Y, Zhang X, Tang L, Liu H (2014) J Alloy Compd 604:286
Chang K, Chen WX (2011) ACS Nano 5:4720
Jiang X, Yang X, Zhu Y, Shen J, Fan K, Li C (2013) J Power Sources 237:178
Sun Y, Zhou T, Pan Q, Zhang X, Guo J (2015) RSC Adv 5:60237
Mohamed SG, Chen CJ, Chen CK, Hu SF, Liu RS (2014) ACS Appl Mater Interfaces 6:22701
Wang Y, Zhang HJ, Wei J, Wong CC, Lin J, Borgna A (2011) Energy Environ Sci 4:1845
Guo J, Chen L, Zhang X, Jiang B, Ma L (2014) Electrochim Acta 129:410
Wang J, Yang N, Tang H, Dong Z, Jin Q, Yang M, Kisailus D, Zhao H, Tang Z, Wang D (2013) Angew Chem Int Ed 52:6417
Xu GL, Li JT, Huang L, Lin W, Sun SG (2013) Nano Energy 2:394
Guo J, Jiang B, Zhang X, Tang L, Wen Y (2015) J Mater Chem A 3:2251
Acknowledgments
We gratefully acknowledge the financial support of the Shandong Provincial Natural Science Foundation, China (ZR2014EMM004, ZR2014JL015).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Guo, J., Zhu, H., Zhou, S. et al. Fast and large lithium storages from CoMoO4 nanorods-graphene composite. Ionics 21, 2993–2999 (2015). https://doi.org/10.1007/s11581-015-1532-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11581-015-1532-x