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Kinetic study on LiFePO4-positive electrode material of lithium-ion battery

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Abstract

LiFePO4-positive electrode material was successfully synthesized by a solid-state method, and the effect of storage temperatures on kinetics of lithium-ion insertion for LiFePO4-positive electrode material was investigated by electrochemical impedance spectroscopy. The charge-transfer resistance of LiFePO4 electrode decreases with increasing the storage temperatures. This suggests that it has a high electrochemical activity at high temperature. The diffusion coefficient of lithium ion is greatly increased with increasing the storage temperatures, indicating that the kinetics of Li+ and electron transfer into the electrodes were much fast at high storage temperature.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (no. 50902001), the Key project of Scientific Research Foundation sponsored by Education Department of Anhui Province, China (no. KJ2010A045), and the Foundation for Young Talents in College of Anhui Province, China (no. 2010SQRL033ZD).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Anhui University of Technology, 59 Hudong Road, Maanshan, Anhui, 243002, People’s Republic of China

    Yan-Rong Zhu, Rong-Sun Zhu, Li-Juan Jiang, Hong-Bin Qiao & Ting-Feng Yi

  2. Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education, Heilongjiang University, Harbin, 150080, People’s Republic of China

    Ying Xie

  3. Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, People’s Republic of China

    Jie Shu

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  1. Yan-Rong Zhu
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  2. Ying Xie
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  3. Rong-Sun Zhu
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  4. Jie Shu
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Correspondence to Jie Shu or Ting-Feng Yi.

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Zhu, YR., Xie, Y., Zhu, RS. et al. Kinetic study on LiFePO4-positive electrode material of lithium-ion battery. Ionics 17, 437–441 (2011). https://doi.org/10.1007/s11581-011-0523-9

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  • DOI: https://doi.org/10.1007/s11581-011-0523-9

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