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Calculation of the thermodynamic interaction parameter ρ C, NiC , in the austenite of the Fe-C-Ni system

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Abstract

In the study, the interaction model has been considered, which assumes that the radius of interaction between carbon and nickel atoms in austenite corresponds to the nearest neighborhood of an octahedral interstice by lattice sites, and the interaction radius between two carbon atoms corresponds to two nearest coordination shells formed by octahedral interstices in the lattice. The three-particle potential of approach of C-Ni-C atoms is taken equal to zero. The pair potential of interaction between carbon atoms in austenite is taken to be equal to that obtained from the data of Mössbauer spectroscopy. In this model, the magnitude of the secondorder thermodynamic cross-interaction parameter ρ C, NiC in the austenite at a temperature of 1273 K has been calculated. The results of the calculation (ρ C, NiC = 11.4) satisfactorily agree with the experimental value (ρ C, NiC = 11.1).

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References

  1. A. V. Ruban, S. Shallcross, S. I. Simak, and H. L. Skriver, “Atomic and Magnetic Configurational Energetics by the Generalized Perturbation Method,” Phys. Rev. B: 70, 125115 (2004).

    Article  Google Scholar 

  2. B. Schönfeld, M. J. Portmann, S. Y Yu, and G. Kostorz, “The Type of Order in Cu-10 at. % Au-Evidence from the Diffuse Scattering of X-rays,” Acta Mater. 47 (5), 1413–1416 (1999).

    Article  Google Scholar 

  3. L. A. Bol'shov, “Interatomic Interaction in Solid Solutions of Gold in Copper” Fiz. Met. Metalloved. 102 (4), 373–377 (2006) [Phys. Met. Metallogr. 102 (4), 347–351 (2006)].

  4. K. Oda, H. Fujimura, and H. Ino, “Local Interactions in Carbon-Carbon and Carbon-M (M: Al, Mn, Ni) Atomic Pairs in FCC-Iron},” J. Phys.: Condens. Matter 6 (3), 679–692 (1994).

    Google Scholar 

  5. L. A. Bol'shov and V. N. Suslov, “Calculation of the Relative Intensities of the Components of the Mössbauer Spectra of Iron in the Austenite of the Iron-Carbon System,” Fiz. Met. Metalloved. 94 (1), 10–16 (2002) [Phys. Met. Metallogr. 94 (1), 6–11(2002)].

    Google Scholar 

  6. L. A. Bol'shov and V. N. Suslov, “Calculation of the Relative Intensities of the Components of the Mössbauer Spectra of Iron in the Austenite of the Iron-Nitrogen System,” Fiz. Met. Metalloved. 96 (6), 3–6 (2003) [Phys. Met. Metallogr. 96 (6), 547–550 (2003)].

    Google Scholar 

  7. L. A. Bol'shov and V. N. Suslov, “Statistical Calculations of the Thermodynamic Parameters of Solutions of Carbon in "Gamma-Iron,” Zhurnal Fizicheskoi Khimii 78 (3), 424–427 (2004) [Russian Journal of Physical Chemistry 78 (3), 344–347 (2004)].

    Google Scholar 

  8. L. A. Bol'shov, V. A. Grigoryan, and A. Ya. Stomakhin, “Statistical Thermodynamiks of Dilute Solution of Carbon and Nitrogen in Alloyed Austenite,” Fiz. Met. Metalloved. 34 (6), 1139–1144 (1972).

    Google Scholar 

  9. C. H. P Lupis, Chemical Thermodynamics of Materials (North-Holland, New York, 1983; Metallurgiya, Moscow, 1989) [in Russian].

    Google Scholar 

  10. C. Wagner, Thermodynamics of Alloys (Addison-Wesley, Reading, Mass., 1952, Metallurgizdat, Moscow, 1957).

    Google Scholar 

  11. L. A. Bol'shov, “On Short Order in Many-Component Alloys,” Fiz. Met. Metalloved. 51(6), 1167–1174 (1981).

    Google Scholar 

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Original Russian Text © L.A. Bol’shov, V.I. Bogdanov, V.A. Gorbunov, 2008, published in Fizika Metallov i Metallovedenie, 2008, Vol. 105, No. 2, pp. 123–126.

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Bol’shov, L.A., Bogdanov, V.I. & Gorbunov, V.A. Calculation of the thermodynamic interaction parameter ρ C, NiC , in the austenite of the Fe-C-Ni system. Phys. Metals Metallogr. 105, 113–115 (2008). https://doi.org/10.1007/s11508-008-2002-8

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  • DOI: https://doi.org/10.1007/s11508-008-2002-8

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