Abstract
In the study, the interaction model has been considered, which assumes that the radius of interaction between carbon and nickel atoms in austenite corresponds to the nearest neighborhood of an octahedral interstice by lattice sites, and the interaction radius between two carbon atoms corresponds to two nearest coordination shells formed by octahedral interstices in the lattice. The three-particle potential of approach of C-Ni-C atoms is taken equal to zero. The pair potential of interaction between carbon atoms in austenite is taken to be equal to that obtained from the data of Mössbauer spectroscopy. In this model, the magnitude of the secondorder thermodynamic cross-interaction parameter ρ C, NiC in the austenite at a temperature of 1273 K has been calculated. The results of the calculation (ρ C, NiC = 11.4) satisfactorily agree with the experimental value (ρ C, NiC = 11.1).
Similar content being viewed by others
References
A. V. Ruban, S. Shallcross, S. I. Simak, and H. L. Skriver, “Atomic and Magnetic Configurational Energetics by the Generalized Perturbation Method,” Phys. Rev. B: 70, 125115 (2004).
B. Schönfeld, M. J. Portmann, S. Y Yu, and G. Kostorz, “The Type of Order in Cu-10 at. % Au-Evidence from the Diffuse Scattering of X-rays,” Acta Mater. 47 (5), 1413–1416 (1999).
L. A. Bol'shov, “Interatomic Interaction in Solid Solutions of Gold in Copper” Fiz. Met. Metalloved. 102 (4), 373–377 (2006) [Phys. Met. Metallogr. 102 (4), 347–351 (2006)].
K. Oda, H. Fujimura, and H. Ino, “Local Interactions in Carbon-Carbon and Carbon-M (M: Al, Mn, Ni) Atomic Pairs in FCC-Iron},” J. Phys.: Condens. Matter 6 (3), 679–692 (1994).
L. A. Bol'shov and V. N. Suslov, “Calculation of the Relative Intensities of the Components of the Mössbauer Spectra of Iron in the Austenite of the Iron-Carbon System,” Fiz. Met. Metalloved. 94 (1), 10–16 (2002) [Phys. Met. Metallogr. 94 (1), 6–11(2002)].
L. A. Bol'shov and V. N. Suslov, “Calculation of the Relative Intensities of the Components of the Mössbauer Spectra of Iron in the Austenite of the Iron-Nitrogen System,” Fiz. Met. Metalloved. 96 (6), 3–6 (2003) [Phys. Met. Metallogr. 96 (6), 547–550 (2003)].
L. A. Bol'shov and V. N. Suslov, “Statistical Calculations of the Thermodynamic Parameters of Solutions of Carbon in "Gamma-Iron,” Zhurnal Fizicheskoi Khimii 78 (3), 424–427 (2004) [Russian Journal of Physical Chemistry 78 (3), 344–347 (2004)].
L. A. Bol'shov, V. A. Grigoryan, and A. Ya. Stomakhin, “Statistical Thermodynamiks of Dilute Solution of Carbon and Nitrogen in Alloyed Austenite,” Fiz. Met. Metalloved. 34 (6), 1139–1144 (1972).
C. H. P Lupis, Chemical Thermodynamics of Materials (North-Holland, New York, 1983; Metallurgiya, Moscow, 1989) [in Russian].
C. Wagner, Thermodynamics of Alloys (Addison-Wesley, Reading, Mass., 1952, Metallurgizdat, Moscow, 1957).
L. A. Bol'shov, “On Short Order in Many-Component Alloys,” Fiz. Met. Metalloved. 51(6), 1167–1174 (1981).
Author information
Authors and Affiliations
Additional information
Original Russian Text © L.A. Bol’shov, V.I. Bogdanov, V.A. Gorbunov, 2008, published in Fizika Metallov i Metallovedenie, 2008, Vol. 105, No. 2, pp. 123–126.
Rights and permissions
About this article
Cite this article
Bol’shov, L.A., Bogdanov, V.I. & Gorbunov, V.A. Calculation of the thermodynamic interaction parameter ρ C, NiC , in the austenite of the Fe-C-Ni system. Phys. Metals Metallogr. 105, 113–115 (2008). https://doi.org/10.1007/s11508-008-2002-8
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11508-008-2002-8