Abstract
Most of the outstanding applications of silver nanoparticles (Ag NPs) have arisen from their tunable localized surface plasmon resonance (LSPR). In this report, we have systematically studied the photothermal transformation of morphology of triangular-shaped Ag NPs (TSNP) under irradiation of a nanosecond (ns)-pulsed laser of 1064-nm wavelength with the pulse duration of 10 ns at different laser fluence and irradiation time. Interestingly, at a typical value of fluence of 104–174 J/cm2 both the triangular and plate-like Ag NPs are transformed into spherical Ag NPs of size ~ 5 nm in just 20–40 min of irradiation that is found to be very much faster when it is compared with the results of well-known chemically etching–based reshaping process in the presence of KBr. We have also demonstrated the possible use of the plasmonic absorption properties of the triangular, plate-like and transformed spherical Ag NPs for the development of a broad-band visible-NIR light absorber by just mixing these Ag NPs of three different morphologies. We have got almost 20% average (overall below 35%) transmission in the wavelength range from 400 to 800 nm in the liquid phase and 57% (overall below 65%) when NPs are put into PVA matrix in 16 vol%. The applicability of the prepared broadband absorber is being verified by monitoring the current response of a light-dependent resistor and degradation process of rhodamine 6G dye in sunlight.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11468-019-01016-6/MediaObjects/11468_2019_1016_Sch1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11468-019-01016-6/MediaObjects/11468_2019_1016_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11468-019-01016-6/MediaObjects/11468_2019_1016_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11468-019-01016-6/MediaObjects/11468_2019_1016_Sch2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11468-019-01016-6/MediaObjects/11468_2019_1016_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11468-019-01016-6/MediaObjects/11468_2019_1016_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11468-019-01016-6/MediaObjects/11468_2019_1016_Sch3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs11468-019-01016-6/MediaObjects/11468_2019_1016_Fig5_HTML.png)
Similar content being viewed by others
References
Potara M, Boca S, Licarete E, Damert A, Alupei MC, Chiriac MT, Popescu O, Schmidtd U, Astilean S (2013) Chitosan-coated triangular silver nanoparticles as a novel class of biocompatible, highly sensitive plasmonic platforms for intracellular SERS sensing and imaging. Nanoscale 5:6013–6022. https://doi.org/10.1039/c3nr00005b
Jiang Z, Wen G, Luo Y, Zhang X, Liu Q, Liang A (2014) A new silver nanorod SPR probe for detection of trace benzoyl peroxide. Sci Rep 4:5323–5330. https://doi.org/10.1038/srep05323
Wijaya YN, Kim J, Hur SH, Park SH, Kim MH et al (2018) Nanocrystal-based sensing platform for the quantification of water in water-ethanol mixtures. Sensors Actuators B 263:59–68. https://doi.org/10.1016/j.snb.2018.02.111
McFarland AD, Duyne RPV (2003) Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity. Nano Lett 3:1057–1062. https://doi.org/10.1021/nl034372s
Biswas S, Kole AK, Sarkar R, Kumbhakar P (2014) Synthesis of anisotropic nanostructures of silver for its possible applications in glucose and temperature sensing. Mater Res Express 1:045043–045058. https://doi.org/10.1088/2053-1591/1/4/045043
Ghannam T (2017) Dipole-nano-laser based plasmonic nano-sensor for sensing photons and bio-chemical analytes. Plasmonics 12:125–130. https://doi.org/10.1007/s11468-016-0237-y
Monteiro JP, de Oliveira JH, Radovanovic E, Brolo AG, Girotto EM (2016) Microfluidic plasmonic biosensor for breast cancer antigen detection. Plasmonics 11:45–52. https://doi.org/10.1007/s11468-015-0016-1
Zhang T, Wang M, Yang Y, Fan F, Lee T, Liua H, Xiang D (2018) An on-chip hybrid plasmonic light steering concentrator with ∼96% coupling efficiency. Nanoscale 10:5097–5104. https://doi.org/10.1039/c8nr00213d
Ganeshan D, Xie F, Sun Q, Li Y, Wei M (2018) Plasmonic effects of silver nanoparticles embedded in the counter electrode on the enhanced performance of dye-sensitized solar cells. Langmuir 34:5367–5373. https://doi.org/10.1021/acs.langmuir.7b03086
Cobley CM, Skrabalak SE, Campbell DJ, Xia Y (2009) Shape-controlled synthesis of silver nanoparticles for plasmonic and sensing applications. Plasmonics 4:171–179. https://doi.org/10.1007/s11468-009-9088-0
Campos A, Troc N, Cottancin E, Pellarin M, Weissker HC, Lermé J, Kociak M, Hillenkamp M (2019) Plasmonic quantum size effects in silver nanoparticles are dominated by interfaces and local environments. Nat Phys 15:275–280. https://doi.org/10.1038/s41567-018-0345-z
Ringe E, McMahon JM, Sohn K, Cobley C, Xia Y, Huang J, Schatz GC, Marks LD, Duyne RPV (2010) Unraveling the effects of size, composition, and substrate on the localized surface plasmon resonance frequencies of gold and silver nanocubes: a systematic single-particle approach. J Phys Chem C 114:12511–12516. https://doi.org/10.1021/jp104366r
Yang X, Yu Y, Gao Z (2014) A highly sensitive plasmonic DNA assay–based on triangular silver nanoprism etching. ACS Nano 8:4902–4907. https://doi.org/10.1021/nn5008786
Hu S, Yi T, Huang Z, Liu B, Wang J, Yi X, Liu J (2019) Etching silver nanoparticles using DNA. Mater Horiz 6:155–159. https://doi.org/10.1039/C8MH01126E
Li L, Zhang L, Zhao Y, Chen Z (2018) Colorimetric detection of Hg(II) by measurement the color alterations from the “before” and “after” RGB images of etched triangular silver nanoplates. Microchim Acta 185:235–241. https://doi.org/10.1007/s00604-018-2759-9
Szychowski B, Leng H, Pelton H, Daniel MC (2018) Controlled etching and tapering of Au nanorods using cysteamine. Nanoscale 10:16830–16838. https://doi.org/10.1039/c8nr05325a
Kamat PV, Flumiani M, Hartland GV (1998) Picosecond dynamics of silver nanoclusters. Photoejection of Electrons and Fragmentation. J Phys Chem B 102:3123–3128. https://doi.org/10.1021/jp980009b
Jeon JW, Yoon S, Choi HW, Kim J, Farson D, Cho SH (2018) The effect of laser pulse widths on laser—Ag nanoparticle interaction: femto- to nanosecond lasers. Appl Sci 8:112–125. https://doi.org/10.3390/app8010112
Takami A, Kurita H, Koda S (1999) Laser-induced size reduction of noble metal particles. J Phys Chem B 103:1226–1232. https://doi.org/10.1021/jp983503o
Pyatenko A, Wang H, Koshizaki N, Tsuji T (2013) Mechanism of pulse laser interaction with colloidal nanoparticles. Laser Photonics Rev 7:596–604. https://doi.org/10.1002/lpor.201300013
Link S, Burda C, Mohamed MB, Nikoobakht B, El-Sayed MA (1999) Laser photothermal melting and fragmentation of gold nanorods: energy and laser pulse-width dependence. J Phys Chem A 103:1165–1170. https://doi.org/10.1021/jp983141k
Fales AM, Vogt WC, Pfefer TJ, Ilev IK (2017) Quantitative evaluation of nanosecond pulsed laser-induced photomodifcation of plasmonic gold nanoparticles. Sci Rep 7:15704–15715. https://doi.org/10.1038/s41598-017-16052-7
Chaudhari K, Subramanian V, Ahuja T, Murugesan V, Ganayee MA, Thundat T, Pradeep T (2019) Appearance of SERS activity in single silver nanoparticles by laser-induced reshaping. Nanoscale 11:321–330. https://doi.org/10.1039/c8nr06497k
Biswas S, Kole AK, Tiwary CS, Kumbhakar PK (2016) Observation of size-dependent electron–phonon scattering and temperature-dependent photoluminescence quenching in triangular-shaped silver nanoparticles. Plasmonics 11:593–600. https://doi.org/10.1007/s11468-015-0072-6
Tang B, Xu S, An J, Zhao B, Xu W, Lombard RJ (2009) Kinetic effects of halide ions on the morphological evolution of silver nanoplates. Phys Chem Chem Phys 11:10286-10292. https://doi.org/10.1039/b912985e
Rubio GG, Martínez AG, Liz-Marzan LM (2016) Reshaping, fragmentation, and assembly of gold nanoparticles assisted by pulse lasers. Acc Chem Res 49:678–686. https://doi.org/10.1021/acs.accounts.6b00041
Jiang L, Wang AD, Li BO, Cui TH, Lu YF (2018) Electrons dynamics control by shaping femtosecond laser pulses in micro/nanofabrication: modelling, method, measurement and application. Light: Sci Appl 7:17134–17161. https://doi.org/10.1038/lsa.2017.134
Ruditskiy A, Xia Y (2017) The science and art of carving metal nanocrystals. ACS Nano 11:23–27. https://doi.org/10.1021/acsnano.6b08556
Abkhalimov EV, Timofeev AA, Ershov BG (2018) Electrochemical mechanism of silver nanoprisms transformation in aqueous solutions containing the halide ions. J Nanopart Res 20:26–38. https://doi.org/10.1007/s11051-018-4133-6
Gangishetty MK, Scott RWJ, Kelly TL (2016) Thermal degradation mechanism of triangular Ag@SiO2 nanoparticles. Dalton Trans 45:9827–9834. https://doi.org/10.1039/c6dt00169f
Marzbanrad E, Rivers G, Peng P, Zhaoac B, Zhou NY (2015) How morphology and surface crystal texture affect thermal stability of a metallic nanoparticle: the case of silver nanobelts and pentagonal silver nanowires. Phys Chem Chem Phys 17:315–324. https://doi.org/10.1039/c4cp04129a
Acknowledgements
KM is thankful to Dr. A. K. Kole and Dr. R. Sarkar for the helpful discussions.
Funding
Authors are grateful to CSIR (project Grant No: 03(1328)/14/EMR-II dt. 03.11.2014). KM is thankful to UGC, GOI for the scholarship.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic Supplementary Material
ESM 1
(DOCX 469 kb)
Rights and permissions
About this article
Cite this article
Mondal, K., Biswas, S. & Kumbhakar, P. Nanosecond Laser–Assisted Tuning of the Plasmon Band of Triangular-Shaped Ag Nanostructures and Development of a Broadband Visible-Near Infrared Light Absorber. Plasmonics 15, 145–153 (2020). https://doi.org/10.1007/s11468-019-01016-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11468-019-01016-6