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Optical Absorption Modeling of Plasmonic Organic Solar Cells Embedding Silica-Coated Silver Nanospheres

Plasmonics volume 13, pages 297–303 (2018)Cite this article

Abstract

We numerically study plasmonic solar cells in which a square periodic array of core–shell Ag@SiO2 nanospheres (NSs) are placed on top of the indium tin oxide (ITO) layer using a 3D finite-difference time-domain (FDTD) method. We investigate the influence of various parameters such as the periodicity of the array, the Ag core diameter, the active layer thickness, the shell thickness, and the refractive index of the shell materials on the optical performance of the organic solar cells (OSC). Our results show that the optimal periodicity of the array of NSs is dependent on the size of Ag core NSs in order to maximize optical absorption in the active layer. A very thin active layer (<70 nm) and an ultrathin (<5 nm) SiO2 shell are needed in order to obtain the highest optical absorption enhancement. Strong electric field localization is observed around the plasmonic core–shell nanoparticles as a result of localized surface plasmon resonance (LSPR) excited by Ag NSs with and without silica shell. Embedding 50 nm Ag NSs with 1-nm-thick SiO2 shell thickness on top of ITO leads to an enhanced intrinsic optical absorption in a 40-nm-thick poly(3-hexylthiophene):phenyl-C61-butyric acid methyl ester (P3HT:PCBM) active layer by 24.7% relative to that without the NSs. The use of 1-nm-thick ZnO shell instead of SiO2 leads to an enhanced intrinsic absorption in a 40-nm-thick P3HT:PCBM active layer by 27%.

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Acknowledgements

The authors acknowledge the IDB Merit Scholarship Programme for High Technology (MSP) for the financial support.

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Authors and Affiliations

  1. Aix-Marseille University, IM2NP, CNRS-UMR 7334, Domaine Universitaire de Saint-Jérôme, Service 231, 13397, Marseille Cedex 20, France

    Kekeli N’Konou, Leo Peres & Philippe Torchio

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  1. Kekeli N’Konou
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  2. Leo Peres
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  3. Philippe Torchio
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Correspondence to Philippe Torchio.

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N’Konou, K., Peres, L. & Torchio, P. Optical Absorption Modeling of Plasmonic Organic Solar Cells Embedding Silica-Coated Silver Nanospheres. Plasmonics 13, 297–303 (2018). https://doi.org/10.1007/s11468-017-0514-4

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  • DOI: https://doi.org/10.1007/s11468-017-0514-4

Keywords

  • Core–shell nanoparticle
  • 3D FDTD modeling
  • Plasmon effect
  • Organic solar cell