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Influence of an Electron Beam Exposure on the Surface Plasmon Resonance of Gold Nanoparticles

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Abstract

Electron beam imaging is a common technique used for characterizing the morphology of plasmonic nanostructures. During the imaging process, the electron beam interacts with traces of organic material in the chamber and produces a well-know layer of amorphous carbon over the specimen under investigation. In this paper, we investigate the effect of this carbon adsorbate on the spectral position of the surface plasmon in individual gold nanoparticles as a function of electron exposure dose. We find an optimum dose for which the plasmonic response of the nanoparticle is not affected by the imaging process.

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References

  1. Stewart ME, Anderton CR, Thompson LB, Maria J, Gray SK, Rogers JA, Nuzzo RG (2008) Chem Rev 108:494

    Article  CAS  Google Scholar 

  2. Mayer KM, Hafner JH (2011) Chem Rev 111(6):3828

    Article  CAS  Google Scholar 

  3. Halas NJ, Lal S, Chang WS, Link S, Nordlander P (2011) Chem Rev 111(6):3913

    Article  CAS  Google Scholar 

  4. Aimovi SS, Kreuzer MP, Gonzlez MU, Quidant R (2009) ACS Nano 3(5):1231

    Article  Google Scholar 

  5. Mayer KM, Hao F, Lee S, Nordlander P, Hafner JH (2010) Nanotech 21(25):255503

    Article  Google Scholar 

  6. Zijlstra P, Paulo M, Pedro MR, Orrit M (2012) Nature Nanotech 7:379

    Article  CAS  Google Scholar 

  7. Ament I, Prasad J, Henkel A, Schmachtel S, Sönnichsen C (2012) Nano Lett 12(2):1092

    Article  CAS  Google Scholar 

  8. Hu M, Novo C, Funston A, Wang H, Staleva H, Zou S, Mulvaney P, Xia Y, Hartland GV (2008) J Mater Chem 18:1949

    Article  CAS  Google Scholar 

  9. Liu N, Hentschel M, Weiss T, Alivisatos AP, Giessen H (2011) Science 332(6036):1407

    Article  CAS  Google Scholar 

  10. Margueritat J, Gehan H, Grand J, Lévi G, Aubard J, Félidj N, Bouhelier A, Colas-Des-Francs G, Markey L, Marco De Lucas C, Dereux A (2011) E Finot, ACS Nano 5(3):1630

    Article  CAS  Google Scholar 

  11. Chang WS, Lassiter JB, Swanglap P, Sobhani H, Khatua S, Nordlander P, Halas NJ, Link S (2012) Nano Lett 12(9):4977

    Article  CAS  Google Scholar 

  12. Sau TK, Rogach AL (2012) Complex-shaped metal nanoparticles: bottom-up syntheses and applications. Wiley-VCH Verlag GmbH & Co

  13. Isabell TC, Fischione PE, O’Keefe C, Guruz MU, Dravid VP (1999) Microsc Microana l5:126

    Article  CAS  Google Scholar 

  14. Graells S, Aćimovíc S, Volpe G, Quidant R (2010) Plasmo 5:135

    Article  CAS  Google Scholar 

  15. Schiffmann KI (1993) Nanotech 4(3):163

    Article  CAS  Google Scholar 

  16. Antognozzi M, Sentimenti A, Valdrè U (1997) Microanal Microstruct 8(6):355

    Article  CAS  Google Scholar 

  17. Johnson S, Hasko D, Teo K, Milne W, Ahmed H (2002) Microelectr Eng 6162(0):665

    Article  Google Scholar 

  18. Djenizian T, Santinacci L, Hildebrand H, Schmuki P (2003) Surf Sci 524(13):40

    Article  CAS  Google Scholar 

  19. Griffiths AJV, Walther T (2010) Phys J Conf Ser 241(1):012017

    Article  Google Scholar 

  20. Toth M, Lobo CJ, Lysaght MJ, Vladár AE, Postek MT (2009) J Appl Phys 106(3):034306

    Article  Google Scholar 

  21. Horiuchi S, Hanada T, Ebisawa M (2008) In: Luysberg M, Tillmann K, Weirich T (eds)EMC 2008 14th European microscopy congress 15 September 2008, Aachen, Germany. Springer, Berlin/Heidelberg, pp 387–388

  22. Morgan CG, Vane R (2012) In: Starikov A (ed)Proceedings SPIE, metrology, inspection, and process control for microlithography XXVI, vol 8324

  23. Mock J, Barbic M, Smith DR, Schultz DA, Schultz S (2002) J Chem Phys 116:6755

    Article  CAS  Google Scholar 

  24. Bouhelier A, Bachelot R, Im J, Wiederrecht GP, Lerondel G, Kostcheev S, Royer P (2005) J Phys Chem B 109:3195

    Article  CAS  Google Scholar 

  25. Kelly KL, Coronado E, Zhao LL, Schatz GC (2003) J Phys Chem B 107(3):668

    Article  CAS  Google Scholar 

  26. McFarland AD, Van Duyne RP (2003) Nano Lett 3(8):1057

    Article  CAS  Google Scholar 

  27. Ogawa T, Akabori M, Motohisa J, Fukui T (1999) Phys B: Cond Mat 270(34):313

    Article  CAS  Google Scholar 

  28. Storm AJ, Chen JH, Ling XS, Zandbergen HW, Dekker C (2005) J Appl Phys 98(1):014307

    Article  Google Scholar 

  29. Kotera M, Akiba Y (2010) Jap J Appl Phys 49(6):06GE08

    Article  Google Scholar 

  30. Toth M, Lobo CJ, Hartigan G, Knowles WR (2007) J Appl Phys 101:054309

    Article  Google Scholar 

  31. Reimer L (1998) Scanning electron microscopy: physics of image formation and microanalysis (Springer Series in Optical Sciences)

  32. Buffat Ph, Borel J-P (1976) Phys Rev A 13(6):2287

    Article  CAS  Google Scholar 

  33. Egerton RF, Li P, Malac M (2004) Micron 35:399

    Article  CAS  Google Scholar 

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Acknowledgments

The research leading to these results has received funding from the European Research Council under the European Community’s Seventh Framework Program FP7/2007-2013 Grant Agreement no 306772. This project is in cooperation with the regional council of Burgundy under PARI SMT3 and the Labex ACTION program (contract ANR-11-LABX-01-01). M. S. acknowledges the support of the Jiangsu Specially-Appointed Professor Program (R2012T01) and the Foundation for special project on the Integration of Industry, Education and Research of Jiangsu Province (BY2012028).

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Correspondence to A. Bouhelier.

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Song, M., des Francs, G.C. & Bouhelier, A. Influence of an Electron Beam Exposure on the Surface Plasmon Resonance of Gold Nanoparticles. Plasmonics 9, 343–348 (2014). https://doi.org/10.1007/s11468-013-9630-y

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  • DOI: https://doi.org/10.1007/s11468-013-9630-y

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