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Plasmonics

, Volume 4, Issue 2, pp 181–185 | Cite as

A Simple and Sensitive SPRS Method for Trace H2O2 Based on the TiO2+ Complex and Gold Nanoparticles Aggregation Reactions

  • Xiaoling Wei
  • Yulan Zhang
  • Zhiliang JiangEmail author
  • Aihui Liang
Article

Abstract

In the medium of H2SO4 and in the presence of TiO2+, gold nanoparticles in size of 10 nm exhibited a weak surface plasmon resonance scattering (SPRS) peak at 775 nm. Upon addition of trace H2O2, the yellow complex [TiO(H2O2)]2+ formed that cause the gold nanoparticles aggregations to form bigger gold nanoparticle clusters in size of about 900 nm, and the SPRS intensity at 775 nm (I) enhanced greatly. The enhanced intensity ΔI was linear to the H2O2 concentration in the range of 0.025–48.7 μg/mL, with a detection limit of 0.014 μg/mL H2O2. This SPRS method was applied to determining H2O2 in water samples with satisfactory results.

Keywords

Hydrogen peroxide Gold nanoparticle Aggregation Surface plasmon resonance scattering method 

Notes

Acknowledgments

This work was supported by the Natural Science Foundation of Guangxi (grant 0833260, 0728213).

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  • Xiaoling Wei
    • 1
  • Yulan Zhang
    • 2
  • Zhiliang Jiang
    • 2
    • 3
    Email author
  • Aihui Liang
    • 3
  1. 1.School of Chemistry and Chemical EngineeringGuangxi UniversityNanningChina
  2. 2.School of Environment and ResourceGuangxi Normal UniversityGuilinChina
  3. 3.Department of Material and Chemical EngineeringGuilin University of TechnologyGuilinChina

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