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Solar manipulations of perpendicular magnetic anisotropy for flexible spintronics

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Abstract

Flexible electronics/spintronics attracts researchers’ attention for their application potential abroad in wearable devices, healthcare, and other areas. Those devices’ performance (speed, energy consumption) is highly dependent on manipulating information bits (spin-orientation in flexible spintronics). In this work, we established an organic photovoltaic (OPV)/ ZnO/Pt/Co/Pt heterostructure on flexible PET substrates with perpendicular magnetic anisotropy (PMA). Under sunlight illumination, the photo-electrons generated from the OPV layer transfer into the PMA heterostructure, then they reduce the PMA strength by enhancing the interfacial Rashba field accordingly. The coercive field (Hc) reduces from 800 Oe to 500 Oe at its maximum, and the magnetization can be switched up and down reversibly. The stability of sunlight control of magnetization reversal under various bending conditions is also tested for flexible spintronic applications. Lastly, the voltage output of sunlight-driven PMA is achieved in our prototype device, exhibiting an excellent angular dependence and opening a door towards solar-driven flexible spintronics with much lower energy consumption.

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References

  1. X. T. Zheng, Z. Yang, L. Sutarlie, M. Thangaveloo, Y. Yu, N. Salleh, J. S. Chin, Z. Xiong, D. L. Becker, X. J. Loh, B. C. K. Tee, and X. Su, Battery-free and AI-enabled multiplexed sensor patches for wound monitoring, Sci. Adv. 9(24), eadg6670 (2023)

    Article  Google Scholar 

  2. Y. Zhao, R. Peng, Y. Guo, Z. Liu, Y. Dong, S. Zhao, Y. Li, G. Dong, Y. Hu, J. Zhang, Y. Peng, T. Yang, B. Tian, Y. Zhao, Z. Zhou, Z. Jiang, Z. Luo, and M. Liu, Ultraflexible and malleable Fe/BaTiO3 mulfiferroic heterostructures for functional devices, Adv. Funct. Mater. 31(16), 2009376 (2021)

    Article  Google Scholar 

  3. Y. Cao, N. Wang, H. Tian, J. Guo, Y. Wei, H. Chen, Y. Miao, W. Zou, K. Pan, Y. He, H. Cao, Y. Ke, M. Xu, Y. Wang, M. Yang, K. Du, Z. Fu, D. Kong, D. Dai, Y. Jin, G. Li, H. Li, Q. Peng, J. Wang, and W. Huang, Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures, Nature 562(7726), 249 (2018)

    Article  ADS  Google Scholar 

  4. S. Ota, A. Ando, and D. Chiba, A flexible giant magne-toresistive device for sensing strain direction, Nat. Electron. 1(2), 124 (2018)

    Article  Google Scholar 

  5. S. Park, S. W. Heo, W. Lee, D. Inoue, Z. Jiang, K. Yu, H. Jinno, D. Hashizume, M. Sekino, T. Yokota, K. Fukuda, K. Tajima, and T. Someya, Self-powered ultraflexible electronics via nano-grating-patterned organic photovoltaics, Nature 561(7724), 516 (2018)

    Article  ADS  Google Scholar 

  6. S. Bauer, Flexible electronics: Sophisticated skin, Nat. Mater. 12(10), 871 (2013)

    Article  ADS  Google Scholar 

  7. Y. Lei, Y. Chen, R. Zhang, Y. Li, Q. Yan, S. Lee, Y. Yu, H. Tsai, W. Choi, K. Wang, Y. Luo, Y. Gu, X. Zheng, C. Wang, C. Wang, H. Hu, Y. Li, B. Qi, M. Lin, Z. Zhang, S. A. Dayeh, M. Pharr, D. P. Fenning, Y. H. Lo, J. Luo, K. Yang, J. Yoo, W. Nie, and S. Xu, A fabrication process for flexible single-crystal perovskite devices, Nature 583(7818), 790 (2020)

    Article  ADS  Google Scholar 

  8. J. Viventi, D. H. Kim, L. Vigeland, E. S. Frechette, J. A. Blanco, Y. S. Kim, A. E. Avrin, V. R. Tiruvadi, S. W. Hwang, A. C. Vanleer, D. F. Wulsin, K. Davis, C. E. Gelber, L. Palmer, J. Van der Spiegel, J. Wu, J. Xiao, Y. Huang, D. Contreras, J. A. Rogers, and B. Litt, Flexible, foldable, actively multiplexed, high-density electrode array for mapping brain activity in vivo, Nat. Neurosci. 14(12), 1599 (2011)

    Article  Google Scholar 

  9. X. Cai, Y. Liu, J. Zha, F. Tan, B. Zhang, W. Yan, J. Zhao, B. Lu, J. Zhou, and C. Tan, A flexible and safe planar zinc-ion micro-battery with ultrahigh energy density enabled by interfacial engineering for wearable sensing systems, Adv. Funct. Mater. 33(29), 2303009 (2023)

    Article  Google Scholar 

  10. Y. Zhang, Y. Wang, C. Wang, Y. Zhao, W. Jing, S. Wang, Y. Zhang, X. Xu, F. Zhang, K. Yu, Q. Mao, Q. Lin, F. Han, B. Tian, Z. Zhou, L. Zhao, W. Ren, M. Liu, and Z. Jiang, Superior performances via designed multiple embossments within interfaces for flexible pressure sensors, Chem. Eng. J. 454, 139990 (2023)

    Article  Google Scholar 

  11. G. Dong, Z. Zhou, X. Xue, Y. Zhang, B. Peng, M. Guan, S. Zhao, Z. Hu, W. Ren, Z. G. Ye, and M. Liu, Ferroelectric phase transition induced a large FMR tuning in self-assembled BaTiO3:Y3Fe5O12 multiferroic composites, ACS Appl. Mater. Interfaces 9(36), 30733 (2017)

    Article  Google Scholar 

  12. C. Wu, X. Pan, F. Lin, Z. Cui, Y. He, G. Chen, Y. Zeng, X. Liu, Q. Chen, D. Sun, and Z. Hai, TiB2/SiCN thin-film strain gauges fabricated by direct writing for high-temperature application, IEEE Sens. J. 22(12), 11517 (2022)

    Article  ADS  Google Scholar 

  13. L. Zhu, Switching of perpendicular magnetization by spin–orbit torque, Adv. Mater. 35(48), 2300853 (2023)

    Article  Google Scholar 

  14. H. Yang, M. Ormaza, Z. Chi, E. Dolan, J. Ingla-Aynes, C. K. Safeer, F. Herling, N. Ontoso, M. Gobbi, B. Martin-Garcia, F. Schiller, L. E. Hueso, and F. Casanova, Gate-tunable spin hall effect in an all-lightelement heterostructure: Graphene with copper oxide, Nano Lett. 23(10), 4406 (2023)

    Article  ADS  Google Scholar 

  15. J. Han, P. Zhang, J. T. Hou, S. A. Siddiqui, and L. Liu, Mutual control of coherent spin waves and magnetic domain walls in a magnonic device, Science 366(6469), 1121 (2019)

    Article  ADS  Google Scholar 

  16. H. Fulara, M. Zahedinejad, R. Khymyn, A. A. Awad, S. Muralidhar, M. Dvornik, and J. Akerman, Spin–orbit torque-driven propagating spin waves, Sci. Adv. 5(9), eaax8467 (2019)

    Article  ADS  Google Scholar 

  17. X. Shao, C. Zhu, P. Kumar, Y. Wang, J. Lu, M. Cha, L. Yao, Y. Cao, X. Mao, H. Heinz, and N. A. Kotov, Voltage modulated untwist deformations and multispectral optical effects from ion intercalation into chiral ceramic nanoparticles, Adv. Mater. 35(16), 2370116 (2023)

    Article  Google Scholar 

  18. W. J. Peng, L. Wang, Y. J. Li, Y. J. Du, Z. X. He, C. Y. Wang, Y. F. Zhao, Z. D. Jiang, Z. Y. Zhou, and M. Liu, Voltage manipulation of synthetic antiferromag-netism in CoFeB/Ta/CoFeB heterostructure for spintronic application, Adv. Mater. Interfaces 9(14), 2200007 (2022)

    Article  Google Scholar 

  19. B. Peng, Q. Lu, H. Tang, Y. Zhang, Y. Cheng, R. Qiu, Y. Guo, Z. Zhou, and M. Liu, Large in-plane piezo-strain enhanced voltage control of magnetic anisotropy in Si-compatible multiferroic thin films, Mater. Horiz. 9(12), 3013 (2022)

    Article  Google Scholar 

  20. B. Prasad, Y. L. Huang, R. V. Chopdekar, Z. Chen, J. Steffes, S. Das, Q. Li, M. Yang, C. C. Lin, T. Gosavi, D. E. Nikonov, Z. Q. Qiu, L. W. Martin, B. D. Huey, I. Young, J. Iniguez, S. Manipatruni, and R. Ramesh, Ultralow voltage manipulation of ferromagnetism, Adv. Mater. 32(28), 2001943 (2020)

    Article  Google Scholar 

  21. C. Song, B. Cui, F. Li, X. J. Zhou, and F. Pan, Recent progress in voltage control of magnetism: Materials, mechanisms, and performance, Prog. Mater. Sci. 87, 33 (2017)

    Article  Google Scholar 

  22. J. M. Hu, Z. Li, L. Q. Chen, and C. W. Nan, High-density magnetoresistive random access memory operating at ultralow voltage at room temperature, Nat. Commun. 2(1), 553 (2011)

    Article  ADS  Google Scholar 

  23. S. Yang, J. W. Son, T. S. Ju, D. M. Tran, H. S. Han, S. Park, B. H. Park, K. W. Moon, and C. Hwang, Magnetic skyrmion transistor gated with voltage-controlled magnetic anisotropy, Adv. Mater. 35(9), 2208881 (2023)

    Article  Google Scholar 

  24. H. J. Kim, K. W. Moon, B. X. Tran, S. Yoon, C. Kim, S. Yang, J. H. Ha, K. An, T. S. Ju, J. I. Hong, and C. Hwang, Field-free switching of magnetization by tilting the perpendicular magnetic anisotropy of Gd/Co multilayers, Adv. Funct. Mater. 32(26), 2112561 (2022)

    Article  Google Scholar 

  25. Z. Tan, J. de Rojas, S. Martins, A. Lopeandia, A. Quintana, M. Cialone, J. Herrero-Martin, J. Meersschaut, A. Vantomme, J. L. Costa-Kramer, J. Sort, and E. Menendez, Frequency-dependent stimulated and post-stimulated voltage control of magnetism in transition metal nitrides: Towards brain-inspired magneto-ionics, Mater. Horiz. 10, 88 (2023)

    Article  Google Scholar 

  26. M. Ameziane, R. Mansell, V. Havu, P. Rinke, and S. van Dijken, Lithium-ion battery technology for voltage control of perpendicular magnetization, Adv. Funct. Mater. 32(29), 2113118 (2022)

    Article  Google Scholar 

  27. M. Huang, M. U. Hasan, K. Klyukin, D. Zhang, D. Lyu, P. Gargiani, M. Valvidares, S. Sheffels, A. Churikova, F. Buttner, J. Zehner, L. Caretta, K. Y. Lee, J. Chang, J. P. Wang, K. Leistner, B. Yildiz, and G. S. D. Beach, Voltage control of ferrimagnetic order and voltage-assisted writing of ferrimagnetic spin textures, Nat. Nanotechnol. 16(9), 981 (2021)

    Article  ADS  Google Scholar 

  28. S. Zhao, Z. Zhou, C. Li, B. Peng, Z. Hu, and M. Liu, Low-voltage control of (Co/Pt)x perpendicular magnetic anisotropy heterostructure for flexible spintronics, ACS Nano 12(7), 7167 (2018)

    Article  Google Scholar 

  29. S. Zhao, L. Wang, Z. Zhou, C. Li, G. Dong, L. Zhang, B. Peng, T. Min, Z. Hu, J. Ma, W. Ren, Z. G. Ye, W. Chen, P. Yu, C. W. Nan, and M. Liu, Ionic liquid gating control of spin reorientation transition and switching of perpendicular magnetic anisotropy, Adv. Mater. 30(30), 1801639 (2018)

    Article  Google Scholar 

  30. B. Peng, Z. Zhou, T. Nan, G. Dong, M. Feng, Q. Yang, X. Wang, S. Zhao, D. Xian, Z. D. Jiang, W. Ren, Z. G. Ye, N. X. Sun, and M. Liu, Deterministic switching of perpendicular magnetic anisotropy by voltage control of spin reorientation transition in (Co/Pt)3/Pb(Mg1/3Nb2/3) O3-PbTiO3 multiferroic heterostructures, ACS Nano 11(4), 4337 (2017)

    Article  Google Scholar 

  31. B. Peng, M. Feng, Q. Yang, S. Zhao, Y. Zhang, Z. Zhou, and M. Liu, Ferroelastic strain-mediated nonvolatile tuning of perpendicular magnetic anisotropy in (Co/Pt)3/(1 1 1) Pb(Mg1/3Nb2/3)O3-PbTiO3 multiferroic heterostructures, IEEE Magn. Lett. 8, 1 (2017)

    Google Scholar 

  32. Q. Yang, Z. Zhou, L. Wang, H. Zhang, Y. Cheng, Z. Hu, B. Peng, and M. Liu, Ionic gel modulation of RKKY interactions in synthetic anti-ferromagnetic nanostructures for low power wearable spintronic devices, Adv. Mater. 30(22), 1800449 (2018)

    Article  Google Scholar 

  33. Q. Yang, L. Wang, Z. Zhou, L. Wang, Y. Zhang, S. Zhao, G. Dong, Y. Cheng, T. Min, Z. Hu, W. Chen, K. Xia, and M. Liu, Ionic liquid gating control of RKKY interaction in FeCoB/Ru/FeCoB and (Pt/Co)2/Ru/(Co /Pt)2 multilayers, Nat. Commun. 9(1), 991 (2018)

    Article  ADS  Google Scholar 

  34. X. Wang, Q. Yang, L. Wang, Z. Zhou, T. Min, M. Liu, and N. X. Sun, E-field control of the RKKY interaction in FeCoB/Ru/FeCoB/PMN-PT (011) multiferroic heterostructures, Adv. Mater. 30(39), 1803612 (2018)

    Article  Google Scholar 

  35. Y. F. Zhao, Y. J. Du, L. Wang, K. Chen, Z. L. Luo, W. S. Yan, Q. Li, Z. D. Jiang, M. Liu, and Z. Y. Zhou, Sunlight-induced tri-state spin memory in photovoltaic/ ferromagnetic heterostructure, Nano Today 46, 101605 (2022)

    Article  Google Scholar 

  36. C. L. Li, Y. J. Li, Y. F. Zhao, Y. J. Du, M. Zhao, W. J. Peng, Y. Y. Wu, M. Liu, and Z. Y. Zhou, Sunlight control of ferromagnetic damping in photovoltaic/ferromagnetic heterostructures, Adv. Funct. Mater. 32(16), 2111652 (2022)

    Article  Google Scholar 

  37. Y. J. Du, S. P. Wang, L. Wang, S. Y. Jin, Y. F. Zhao, T. Min, Z. D. Jiang, Z. Y. Zhou, and M. Liu, Improving solar control of magnetism in ternary organic photovoltaic system with enhanced photo-induced electrons doping, Nano Res. 15(3), 2626 (2022)

    Article  ADS  Google Scholar 

  38. Y. Zhao, S. Zhao, L. Wang, S. Wang, Y. Du, Y. Zhao, S. Jin, T. Min, B. Tian, Z. Jiang, Z. Zhou, and M. Liu, Photovoltaic modulation of ferromagnetism within a FM metal/P–N junction Si heterostructure, Nanoscale 13(1), 272 (2021)

    Article  Google Scholar 

  39. Y. Zhao, S. Zhao, L. Wang, Z. Zhou, J. Liu, T. Min, B. Peng, Z. Hu, S. Jin, and M. Liu, Sunlight control of interfacial magnetism for solar driven spintronic applications, Adv. Sci. (Weinh.) 6(24), 1901994 (2019)

    Google Scholar 

  40. M. Zhao, L. Wang, Y. Zhao, Y. Du, Z. He, K. Chen, Z. Luo, W. Yan, Q. Li, C. Wang, Z. Jiang, M. Liu, and Z. Zhou, Deterministic magnetic switching in perpendicular magnetic trilayers through sunlight-induced photoelectron injection, Small 19(28), 2301955 (2023)

    Article  Google Scholar 

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Acknowledgements

The work was supported by the National Key R&D Program of China (Grant No. 2022YFB3203903), the National Natural Science Foundation of China (Grant Nos. 52172126 and 62001366), and the China Postdoctoral Science Foundation (Grant No. 2022M722509).

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Correspondence to Yifan Zhao, Ming Liu or Ziyao Zhou.

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He, Z., Zhao, Y., Du, Y. et al. Solar manipulations of perpendicular magnetic anisotropy for flexible spintronics. Front. Phys. 19, 43206 (2024). https://doi.org/10.1007/s11467-023-1377-0

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