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Characterization of polybenzoxazine and its electrochemical polymerization mechanism

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Frontiers of Chemistry in China

Abstract

Poly(3-(p-methyl)benzyl-3,4-dihydro-6-methyl-2H-1,3-benzoxazine) (poly(pCpT)), which was obtained from electrochemical polymerization in acetonitrile/alkali aqueous solution, was characterized by FT-IR, UV-Vis and 1H-NMR. The results indicate a ring-opening structure of the polymer. By using a rotating-ring disc electrode (RRDE), the electrochemical behaviors of polymerization were studied and the polymerization mechanism was proposed.

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Authors and Affiliations

  1. Department of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, National Lab of Microstructure Studies, Nanjing University, Nanjing, 210093, China

    Wei Chen, Jinbo He & Liang Li

Authors
  1. Wei Chen
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  2. Jinbo He
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  3. Liang Li
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Correspondence to Wei Chen.

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Chen, W., He, J. & Li, L. Characterization of polybenzoxazine and its electrochemical polymerization mechanism. Front. Chem. China 4, 390–395 (2009). https://doi.org/10.1007/s11458-009-0105-9

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  • DOI: https://doi.org/10.1007/s11458-009-0105-9

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