Skip to main content
Log in

Performance evaluation of soil mixtures treated with graphite and used as barrier fill material for high-level radioactive waste repository

  • Research Paper
  • Published:
Acta Geotechnica Aims and scope Submit manuscript

Abstract

Buffer/backfill material is an important engineering barrier in a deep geological repository of high-level radioactive waste (HLW). Its thermo-hydro-mechanical (THM) performance is very important for the safe and stable operation of the HLW repository system. Natural graphite powder mixed with sodium bentonite forms a buffer/backfill material that can dissipate heat quickly and provide strong isolation. In this paper, the THM characteristics of bentonite–sand–graphite–polypropylene fiber (BSGF) mixtures, used as a buffer/backfill material, were studied through a series of laboratory tests. The influence of graphite and polypropylene fiber contents on thermal conductivity, swelling pressure, hydraulic conductivity, and strength properties of BSGF mixtures with different sand contents was analyzed. Experimental results indicated that the graphite content, the maximum graphite mesh number, and the initial dry density of bentonite–graphite mixtures influenced the thermal conductivity of bentonite–graphite mixtures. The addition of polypropylene fiber was found to enhance the shear strength and inhibit cracking without significantly affecting the expansivity, permeability, and thermal conductivity of the BSGF mixtures. This study provides a new buffer/backfill material that can improve the stability, functionality, and thermal efficiency of the HLW repository.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15

Similar content being viewed by others

References

  1. Abichou T, Benson CH, Edil TB (2002) Micro-structure and hydraulic conductivity of simulated sand-bentonite mixtures. Clay Clay Miner 50(5):537–545

    Google Scholar 

  2. Agus SS, Schanz T (2008) A method for predicting swelling pressure of compacted bentonites. Acta Geotech 3(2):125

    Google Scholar 

  3. ASTM D5856-95 (2007) Standard test method for measurement of hydraulic conductivity of porous material using a rigid-wall, compaction-mold permeameter

  4. ASTM. D6528-07 (2007) Standard test method for consolidated undrained direct simple shear testing of cohesive soils. ASTM, West Conshohocken

  5. ASTM D4546-08 (2008) Standard test methods for one-dimensional swell or collapse of cohesive soils

  6. ASTM D5334-08 (2008) Standard test method for determination of thermal conductivity of soil and soft rock by thermal needle probe procedure

  7. Ballarini E, Graupner B, Bauer S (2017) Thermal-hydraulic-mechanical behavior of bentonite and sand-bentonite materials as seal for a nuclear waste repository: numerical simulation of column experiments. Appl Clay Sci 135:289–299

    Google Scholar 

  8. Cai G, Zhang T, Puppala AJ, Liu S (2015) Thermal characterization and prediction model of typical soils in Nanjing area of China. Eng Geol 191:23–30

    Google Scholar 

  9. Cai Y, Shi B, Ng CW, Tang CS (2006) Effect of polypropylene fibre and lime admixture on engineering properties of clayey soil. Eng Geol 87:230–240

    Google Scholar 

  10. Chaduvula U, Viswanadham BVS, Kodikara J (2017) A study on desiccation cracking behavior of polyester fiber-reinforced expansive clay. Appl Clay Sci 142:163–172

    Google Scholar 

  11. Chen L, Liu Y, Wang J, Cao S, Xie J, Ma L, Zhao X, Li Y, Liu J (2014) Investigation of the thermal-hydro-mechanical (THM) behavior of GMZ bentonite in the China-Mock-up test. Eng Geol 172:57–68

    Google Scholar 

  12. Chen ZG, Tang CS, Zhu C, Shi B, Liu YM (2017) Compression, swelling and rebound behavior of GMZ bentonite/additive mixture under coupled hydro-mechanical condition. Eng Geol 221:50–60

    Google Scholar 

  13. Cho WJ, Lee JO, Kwon S (2011) An empirical model for the thermal conductivity of compacted bentonite and a bentonite–sand mixture. Heat Mass Transf 47:1385–1393

    Google Scholar 

  14. Cho WJ, Lee JO, Kang CH (2000) Hydraulic conductivity of benonite-sand mixture for a potential backfill material for a high-level radioactive waste repository. J Korean Nucl Soc 32:495–503

    Google Scholar 

  15. Cui SL, Zhang HY, Zhang M (2012) Swelling characteristics of compacted GMZ bentonite–sand mixtures as a buffer/backfill material in China. Eng Geol 141:65–73

    MathSciNet  Google Scholar 

  16. Delaleux F, Py X, Olives R, Dominguez A (2012) Enhancement of geothermal borehole heat exchangers performances by improvement of bentonite grouts conductivity. Appl Therm Eng 33:92–99

    Google Scholar 

  17. Dixon D, Gray M, Thomas A (1985) A study of the compaction properties of potential clay-sand buffer mixtures for use in nuclear fuel waste disposal. Eng Geol 21:247–255

    Google Scholar 

  18. Erol S, François B (2014) Efficiency of various grouting materials for borehole heat exchangers. Appl Therm Eng 70:788–799

    Google Scholar 

  19. Erzin Y, Erol O (2007) Swell pressure prediction by suction methods. Eng Geol 92:133–145

    Google Scholar 

  20. Ferber V, Auriol JC, Cui YJ, Magnan JP (2009) On the swelling potential of compacted high plasticity clays. Eng Geol 104:200–210

    Google Scholar 

  21. Gilart PM, Martínez ÁY, Barriuso MG, Martínez CM (2012) Development of PCM/carbon-based composite materials. ol. Energ Mat Sol C 107:205–211

    Google Scholar 

  22. Gray M, Cheung S, Dixon D (1984) The influence of sand content on swelling pressures and structure developed in statically compacted Na-bentonite. Atomic Energy of Canada Ltd

  23. Hedin A (2006) Long-term safety for KBS-3 repositories at Forsmark and Laxemar-a first evaluation. Main Report of the SR-Can project. Swedish Nuclear Fuel and Waste Management Co

  24. Jiang H, Cai Y, Liu J (2010) Engineering properties of soils reinforced by short discrete polypropylene fiber. J Mater Civil Eng 22:1315–1322

    Google Scholar 

  25. Jobmann M, Buntebarth G (2009) Influence of graphite and quartz addition on the thermo–physical properties of bentonite for sealing heat-generating radioactive waste. Appl Clay Sci 44:206–210

    Google Scholar 

  26. Kamon M, Zhang H, Katsumi T, Sawa N (2002) Redox effect on the hydraulic conductivity of clay liner. Soils Found 42:79–91

    Google Scholar 

  27. Karaipekli A, Sarı A, Kaygusuz K (2007) Thermal conductivity improvement of stearic acid using expanded graphite and carbon fiber for energy storage applications. Renew Energ 32:2201–2210

    Google Scholar 

  28. Kim JS, Kwon SK, Sanchez M, Cho GC (2011) Geological storage of high level nuclear waste. KSCE J Civ Eng 15:721–737

    Google Scholar 

  29. Klemens P, Pedraza D (1994) Thermal conductivity of graphite in the basal plane. Carbon 32:735–741

    Google Scholar 

  30. Komine H (2004) Simplified evaluation for swelling characteristics of bentonites. Eng Geol 71:265–279

    Google Scholar 

  31. Komine H (2010) Predicting hydraulic conductivity of sand-bentonite mixture backfill before and after swelling deformation for underground disposal of radioactive wastes. Eng Geol 114:123–134

    Google Scholar 

  32. Komine H, Ogata N (1999) Experimental study on swelling characteristics of sand-bentonite mixture for nuclear waste disposal. Soils Found 39:83–97

    Google Scholar 

  33. Kwon S, Cho W, Lee J (2013) An analysis of the thermal and mechanical behavior of engineered barriers in a high-level radioactive waste repository. Nucl Eng Technol 45:41–52

    Google Scholar 

  34. Lee JO, Choi H, Lee JY (2016) Thermal conductivity of compacted bentonite as a buffer material for a high-level radioactive waste repository. Ann Nucl Engery 94:848–855

    Google Scholar 

  35. Liu L, Cai G, Liu S (2018) Compression properties and micro-mechanisms of rubber-sand particle mixtures considering grain breakage. Constr Build Mater 187:1061–1072

    Google Scholar 

  36. Liu L, Cai G, Liu X, Puppala AJ (2019) Evaluation of thermal-mechanical properties of quartz sand-bentonite-carbon fiber mixtures as the borehole backfilling material in ground source heat pump. Energ Build 202:109407

    Google Scholar 

  37. Liu X, Cai G, Liu L, Liu S, Puppala AJ (2019) Thermo-hydro-mechanical properties of bentonite-sand-graphite-polypropylene fiber mixtures as buffer materials for a high-level radioactive waste repository. Int Heat Mass Tran 141:981–994

    Google Scholar 

  38. Manca D, Ferrari A, Laloui L (2016) Fabric evolution and the related swelling behaviour of a sand/bentonite mixture upon hydro-chemo-mechanical loadings. Géotechnique 66(1):41–57

    Google Scholar 

  39. NEA A (2003) Engineered barrier systems and the safety of deep geological repositories. OECD-NEA Paris

  40. Pacovsky J (2002) Some results from geotechnical research on bentonite. CTU reports-experimental investigation of building materials and technologies, pp 107–116

  41. Pacovský J, Svoboda J, Zapletal L (2007) Saturation development in the bentonite barrier of the Mock-Up-CZ geotechnical experiment. Phys Chem Earth 32:767–779

    Google Scholar 

  42. Pakbaz MC, Khayat N (2004) The effect of sand on strength of mixtures of bentonite-sand. Engineering geology for infrastructure planning in Europe. Springer, New York, pp 316–320

    Google Scholar 

  43. Park SS (2009) Effect of fiber reinforcement and distribution on unconfined compressive strength of fiber-reinforced cemented sand. Geotext Geomembr 27:162–166

    Google Scholar 

  44. Punthutaecha K, Puppala AJ, Vanapalli SK, Inyang H (2006) Volume change behaviors of expansive soils stabilized with recycled ashes and fibers. J Mater Civil Eng 18(2):295–306

    Google Scholar 

  45. Puppala AJ, Musenda C (2000) Effects of fiber reinforcement on strength and volume change in expansive soils. Transp Res Rec 1736(1):134–140

    Google Scholar 

  46. Pusch R (2009) Geological storage of highly radioactive waste: current concepts and plans for radioactive waste disposal. Springer, New York

    Google Scholar 

  47. Santoni RL, Tingle JS, Webster SL (2001) Engineering properties of sand-fiber mixtures for road construction. J Geotech Geoenviron 127:258–268

    Google Scholar 

  48. Sivapullaiah P, Sridharan A, Stalin V (1996) Swelling behaviour of soil bentonite mixtures. Can Geotech J 33:808–814

    Google Scholar 

  49. SKB SKA (2006) Long-term safety for KBS-3 repositories at Forsmark and Laxemar—a first evaluation. Main Report of the SR-Can Project. SKB Stockholm, Sweden

  50. Sun DA, Cui H, Sun W (2009) Swelling of compacted sand–bentonite mixtures. Appl Clay Sci 43:485–492

    Google Scholar 

  51. Sun DA, Zhang J, Zhang J, Zhang L (2013) Swelling characteristics of GMZ bentonite and its mixtures with sand. Appl Clay Sci 83:224–230

    Google Scholar 

  52. Tang CS, Shi B, Zhao LZ (2010) Interfacial shear strength of fiber reinforced soil. Geotext Geomembr 28:54–62

    Google Scholar 

  53. Tiedje E, Guo P (2013) Thermal conductivity of bentonite grout containing graphite or chopped carbon fibers. J Mater Civil Eng 26:06014013

    Google Scholar 

  54. Twinkle S, Sayida M (2011) Effect of polypropylene fibre and lime admixture on engineering properties of expansive soil. In: Proceedings of Indian geotechnical conference, December 15–17, Kochi

  55. Villar M, Cuevas J, Martin P (1996) Effects of heat/water flow interaction on compacted bentonite: preliminary results. Eng Geol 41:257–267

    Google Scholar 

  56. Villar MV, Lloret A (2008) Influence of dry density and water content on the swelling of a compacted bentonite. Appl Clay Sci 39:38–49

    Google Scholar 

  57. Wang J (2010) High-level radioactive waste disposal in China: update 2010. J Rock Mech Geotech Eng 2:1–11

    Google Scholar 

  58. Wang Q, Cui YJ, Tang AM, Barnichon JD, Saba S, Ye WM (2013) Hydraulic conductivity and microstructure changes of compacted bentonite/sand mixture during hydration. Eng Geol 164:67–76

    Google Scholar 

  59. Wang Q, Tang AM, Cui YJ, Delage P, Barnichon JD, Ye WM (2013) The effects of technological voids on the hydro-mechanical behaviour of compacted bentonite–sand mixture. Soils Found 53(2):232–245

    Google Scholar 

  60. Xu L, Ye WM, Chen B, Chen YG, Cui YJ (2016) Experimental investigations on thermo-hydro-mechanical properties of compacted GMZ01 bentonite-sand mixture using as buffer materials. Eng Geol 213:46–54

    Google Scholar 

  61. Yang SY, Yeh HD (2009) Modeling transient heat transfer in nuclear waste repositories. J Hazard Mater 169:108–112

    Google Scholar 

  62. Ye WM, Cui YJ, Qian LX, Chen B (2009) An experimental study of the water transfer through confined compacted GMZ bentonite. Eng Geol 108:169–176

    Google Scholar 

  63. Yen C, Tseng H, Wang Y, Hsieh KH (1991) Thermal conductivity of glass fiber reinforced polypropylene under high pressure. J Appl Polym Sci 42:1179–1184

    Google Scholar 

  64. Zhang M, Zhang H, Cui S, Jia L, Zhou L, Chen H (2012) Engineering properties of GMZ bentonite-sand as buffer/backfilling material for high-level waste disposal. Eur J Environ Civ En 16:1216–1237

    Google Scholar 

  65. Zhang M, Zhang H, Zhou L, Wang B, Wang S (2014) Hydro-mechanical analysis of GMZ bentonite-sand mixtures in the water infiltration process as the buffer/backfill mixture in an engineered nuclear barrier. Appl Clay Sci 97:115–124

    Google Scholar 

  66. Zhang T, Cai G, Liu S, Puppala AJ (2017) Investigation on thermal characteristics and prediction models of soils. Int Heat Mass Trans 106:1074–1086

    Google Scholar 

Download references

Acknowledgments

This research was supported by the National Key R&D Program of China (2020YFC1807200), National Natural Science Foundation of China (No. 41672294, No. 41877231, No. 42072299), Project of Jiangsu Province Transportation Engineering Construction Bureau (CX-2019GC02), and Scientific Research Foundation of Graduate School of Southeast University (Grant No. YBPY1977).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guojun Cai.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, X., Congress, S.S.C., Cai, G. et al. Performance evaluation of soil mixtures treated with graphite and used as barrier fill material for high-level radioactive waste repository. Acta Geotech. 16, 1487–1507 (2021). https://doi.org/10.1007/s11440-020-01102-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11440-020-01102-8

Keywords

Navigation