Abstract
“Click chemistry” was used to covalently attach acetylene-bearing cyclophane to azide-terminated BDD surfaces. The azide termination was obtained through an esterification reaction between 4-azidobenzoic acid and the terminal hydroxyl groups of oxidized BDD surfaces. The resulting surfaces were characterized using X-ray photoelectron spectroscopy (XPS), water contact angle and electrochemical measurements. As a result, alkyne-functionalized cyclophane can undergo click chemistry to conveniently attach these units onto a preformed azide-functionalized BDD surface.
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Wang, M. Clicking cyclophane to boron doped diamond surfaces. Chin. Sci. Bull. 58, 2898–2902 (2013). https://doi.org/10.1007/s11434-013-5703-8
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DOI: https://doi.org/10.1007/s11434-013-5703-8