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Preparation, characterization and photodegradation of methylene blue based on TiO2 microparticles modified with thiophene substituents

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  • Materials Science
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  • Published: 07 September 2012
  • Volume 57, pages 4381–4386, (2012)
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Chinese Science Bulletin
Preparation, characterization and photodegradation of methylene blue based on TiO2 microparticles modified with thiophene substituents
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  • Pei Liu1,
  • Peng Zhang1,
  • DongLiang Cao1 &
  • …
  • WenTing Xue1 
  • 2306 Accesses

  • 4 Citations

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Abstract

The new microparticles, 2-formylthiophene (FT)/TiO2 and (E)-1,2-bis(5-formyl-2-thienyl) ethylene (EBFTE)/TiO2 were synthesized with a silane coupling agent. The prepared TiO2 composites were characterized using Ultraviolet-Vis absorption (UV-Vis), X-ray diffraction (XRD), scanning electron microscope (SEM) and thermogravimetric analyzer (TGA). Methylene blue was used as a model material to examine the photocatalytic activities of the prepared catalysts under both Ultraviolet-Vis (UV) and visible (Vis) light. The enhanced photocatalytic activities were observed in the presence of (FT)/TiO2 and EBFTE/TiO2 under Vis light. It suggests that FT or EBFTE plays a block or active role in the photodegradation mechanisms under UV and Vis light irradiation, respectively.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Southwest University, Chongqing, 400715, China

    Pei Liu, Peng Zhang, DongLiang Cao & WenTing Xue

Authors
  1. Pei Liu
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  2. Peng Zhang
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  3. DongLiang Cao
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Corresponding author

Correspondence to Peng Zhang.

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Cite this article

Liu, P., Zhang, P., Cao, D. et al. Preparation, characterization and photodegradation of methylene blue based on TiO2 microparticles modified with thiophene substituents. Chin. Sci. Bull. 57, 4381–4386 (2012). https://doi.org/10.1007/s11434-012-5447-x

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  • Received: 20 June 2012

  • Accepted: 23 July 2012

  • Published: 07 September 2012

  • Issue Date: November 2012

  • DOI: https://doi.org/10.1007/s11434-012-5447-x

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Keywords

  • TiO2
  • methylene blue
  • microparticles
  • photocatalytic degradation
  • thiophene
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