Abstract
Thin-film lithium-ion batteries are the most competitive power sources for various kinds of micro-electro-mechanical systems and have been extensively researched. The present paper reviews the recent progress on Sn-based thin-film anode materials, with particular emphasis on the preparation and performances of pure Sn, Sn-based alloy, and Sn-based oxide thin films. From this survey, several conclusions can be drawn concerning the properties of Sn-based thin-film anodes. Pure Sn thin films deliver high reversible capacity but very poor cyclability due to the huge volume changes that accompany lithium insertion/extraction. The cycle performance of Sn-based intermetallic thin films can be enhanced at the expense of their capacities by alloying with inactive transition metals. In contrast to anodes in which Sn is alloyed with inactive transition metals, Sn-based nanocomposite films deliver high capacity with enhanced cycle performance through the incorporation of active elements. In comparison with pure Sn anodes, Sn-based oxide thin films show greatly enhanced cyclability due to the in situ formation of Sn nanodispersoids in an Li2O matrix, although there is quite a large initial irreversible capacity loss. For all of these anodes, substantial improvements have been achieved by micro-nanostructure tuning of the active materials. Based on the progress that has already been made on the relationship between the properties and microstructures of Sn-based thin-film anodes, it is believed that manipulating the multi-phase and multi-scale structures offers an important means of further improving the capacity and cyclability of Sn-based alloy thin-film anodes.
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References
Patil A, Patil V, Shin D W, et al. Issue and challenges facing rechargeable thin film lithium batteries. Mater Res Bull, 2008, 43: 1913–1942
Bates J B, Dudney N J, Neudecker B, et al. Thin-film lithium and lithium-ion batteries. Solid State Ionics, 2000, 135: 33–45
Tirado J L. Inorganic materials for the negative electrode of lithium-ion batteries: State-of-the-art and future prospects. Mater Sci Eng Res, 2003, 40: 103–136
Winter M, Besenhard J O. Electrochemical lithiation of tin and tin-based intermetallics and composites. Electrochim Acta, 1999, 45: 31–50
Zhang W J. A review of the electrochemical performance of alloy anodes for lithium-ion batteries. J Power Sources, 2011, 196: 13–24
Massalski T B. Binary Alloy Phase Diagram [M/CD]. 2nd ed. ASM International: Materials Park, OH, 1996
Morimoto H, Tobishima S I. Anode behavior of electroplated rough surface Sn thin films for lithium-ion batteries. J Power Sources, 2005, 146: 469–472
Inaba M, Uno T, Tasaka A. Irreversible capacity of electrodeposited Sn thin film anode. J Power Sources, 2005, 146: 473–477
Beaulieu L Y, Hatchard T D, Bonakdarpour A, et al. Reaction of Li with alloy thin films studied by in situ AFM. J Electrochem Soc, 2003, 150: A1457–A1464
Hassoun J, Reale P, Panero S. The role of the interface of tin electrodes in lithium cells: An impedance study. J Power Sources, 2007, 174: 321–327
Chiu K F, Lin H C, Lin K M, et al. The significant role of solid oxide interphase in enhancement of cycling performance of Sn thin-film anodes. J Electrochem Soc, 2006, 153: A1038–A1042
Ui K, Kikuchi S, Kadoma Y, et al. Electrochemical characteristics of Sn film prepared by pulse electrodeposition method as negative electrode for lithium secondary batteries. J Power Sources, 2009, 189: 224–229
Tamura N, Ohshita R, Fujimota M, et al. Study on the anode behavior of Sn and Sn-Cu alloy thin-film electrodes. J Power Sources, 2002, 107: 48–55
Zhao H P, Jiang C Y, He X M, et al. Electrodeposited tin based alloy with composite structure used as anode materials for lithium ion batteries (in Chinese). Acta Metall Sin, 2007, 43: 775–779
Pu W H, He X M, Ren J G, et al. Electrodeposition of Sn-Cu alloy anodes for lithium batteries. Electrochim Acta, 2005, 50: 4140–4145
Kim R H, Nam D H, Kwon H S. Electrochemical performance of a tin electrodeposit with a multi-layered structure for Li-ion batteries. J Power Sources, 2010, 195: 5067–5070
Park J W, Eom J Y, Kwon H S. Charge-discharge characteristics of a layered-structure electroplated Cu/Sn anode for Li-ion batteries. Electrochim Acta, 2010, 55: 1825–1828
Fan X Y, Zhuang Q C, Xu J M, et al. Preparation and capacity fading mechanism of tin thin film as anode of lithium-ion battery (in Chinese). Acta Chim Sin, 2007, 65: 165–169
Zhao L Z, Hub S J, Ru Q, et al. Effects of graphite on electrochemical performance of Sn/C composite thin film anodes. J Power Sources, 2008, 184: 481–484
Li C M, Huang Q M, Zhang R Y, et al. A comparative study on the performances of thin film and granular tin as Li ion insertion electrodes prepared by electrodeposition (in Chinese). Acta Metall Sin, 2007, 43: 515–520
Song S W, Baek S W. Electrochemical thin film studies of Sn metals for rechargeable lithium batteries. ECS Trans, 2008, 11: 71–78
Hu R Z, Zhang Y, Zhu M. Microstructure and electrochemical properties of electron-beam deposited Sn-Cu thin film anodes for thin film lithium ion batteries. Electrochem Acta, 2008, 53: 3377–3385
Bai H M, Tao Z L, Cheng F Y, et al. Preparation and electrochemical properties of Sn thin film as anode materials for lithium-ion batteries (in Chinese). J Electrochem, 2011, 17: 43–47
Beattie S D, Dahn J R. Single bath, pulsed electrodeposition of coppertin alloy negative electrodes for lithium ion batteries. J Electrochem Soc, 2003, 150: A894–A898
Hu R Z, Zeng M Q, Zhu M. Cyclic durable high capacity Sn/Cu6Sn5 composite thin film anodes for lithium ion batteries prepared by electronbeam evaporation deposition. Electrochim Acta, 2009, 54: 2843–2850
Shin H C, Liu M L. Three-dimensional porous copper-tin alloy electrodes for rechargeable lithium batteries. Adv Funct Mater, 2005, 15: 582–586
Jiang T, Zhang S C, Qiu X P, et al. Preparation and characterization of tin-based three-dimensional cellular anode for lithium ion battery. J Power Sources, 2007, 166: 503–508
Du Z J, Zhang S C, Jiang T, et al. Preparation and characterization of three-dimensional tin thin-film anode with good cycle performance. Electrochim Acta, 2010, 55: 3537–3541
Zhao H, Jiang C, He X, et al. Advanced structures in electrodeposited tin base anodes for lithium ion batteries. Electrochim Acta, 2007, 52: 7820–7826
Ke F S, Huang L, Cai J S, et al. Electroplating synthesis and electrochemical properties of macroporous Sn-Cu alloy electrode for lithium ion batteries. Electrochim Acta 2007, 52: 6741–6747
Beattie S D, Dahn J R. Single-bath electrodeposition of a combinatorial library of binary Cu1−x Snx alloys. J Electrochem Soc, 2003, 150: C457–C460
Lee H Y, Jang S W, Lee S M. Lithium storage properties of nanocrystalline Ni3Sn4 alloys prepared by mechanical alloying. J Power Sources, 2002, 112: 8–12
Han X Y, Zhang F, Xiang J F, et al. Preparation and electrochemical performance of micro-nanostructured nickel. Electrochim Acta, 2009, 54: 6161–6165
Kim Y L, Lee H Y, Jang S W, et al. Nanostructured Ni3Sn2 thin films as anodes for thin film rechargeable lithium batteries. Solid State Ionics, 2003, 160: 235–240
Mukaibo H, Sumi T, Yokoshima T, et al. Electrodeposited Sn-Ni alloy film as a high capacity anode material for lithium-ion secondary batteries. Electrochem Solid-State Lett, 2003, 6: A218–A220
Mukaibo H, Momma T, Osaka T. Changes of electro-deposited Sn-Ni alloy thin film for lithium ion battery anodes during charge-discharge cycling. J Power Sources, 2005, 146: 457–463
Crosnier O, Brousse T, Devaux X, et al. New anode systems for lithium ion cells. J. Power Sources, 2001, 94: 169–174
Zhang D W, Yang C G, Dai J, et al. Fabrication of Sn-Ni alloy film anode for Li-ion batteries by electrochemical deposition. Trans Nonferrous Metals Soc Chin, 2009, 19: 1489–1493
Hassoun J, Panero S, Scrosati B. Electrodeposited Ni-Sn intermetallic electrodes for advanced lithium ion batteries. J Power Sources, 2006, 160: 1336–1341
Tamura N, Kato Y, Mikami A, et al. Study on Sn-Co alloy anodes for lithium secondary batteries I. Amorphous system. J Electrochem Soc, 2006, 153: A1626–A1632
Tamura N, Kato Y, Mikami A, et al. Study on Sn-Co alloy electrodes for lithium secondary batteries II. Nanocomposite system. J Electrochem Soc, 2006, 153: A2227–A2231
Ke F S, Huang L, Wei H B, et al. Fabrication and properties of macroporous tin-cobalt alloy film electrodes for lithium-ion batteries. J Power Sources, 2007, 170: 450–455
Fan X Y, Ke F S, Wei G Z, et al. Sn-Co alloy anode using porous Cu as current collector for lithium ion battery. J Alloy Compd, 2009, 476: 70–73
Xue L J, Huang L, Ke F S, et al. Preparation and electrochemical performance of three-dimensional porous SnCo alloy electrode (in Chinese). J Electrochem, 2010, 16: 161–167
Bonakdarpour A, Hewitt K C, Turner R L, et al. Electrochemical and in-situ XRD studies of the lithium reaction with combinatorially sputtered Mo1−x Snx (0<x<0.50) thin films. J Electrochem Soc, 2004, 151: A470–A483
Beaulieu L Y, Hewitt K C, Turner R L, et al. The electrochemical reaction of Li with amorphous Si-Sn alloys. J Electrochem Soc, 2003, 150: A149–A156
Beaulieu L Y, Hatchard T D, Bonakdarpour A, et al. The reaction of Li with thin films studied by atomic force microscopy. J Electrochem Soc, 2003, 150: A1457–A1464
Hatchard T D. Study of the electrochemical performance of sputtered Si1-xSn film. J Electrochem Soc, 2004, 151: A1628–A1635
Hatchard T D, Topple J M, Fleischauer M D, et al. Study of the electrochemical performance of SiAlSn films prepared by combinatorial sputtering. Electrochem Solid State Lett, 2003, 6: A129–A132
Dahn J R, Mar R E, Fleischauer M D, et al. The impact of the addition of rare earth elements to Si1−x Snx negative electrode materials for Li-ion batteries. J Electrochem Soc, 2006, 153: A1211–A1220
Zhao L Z, Hu S J, Ru Q, et al. Effects of graphite on electrochemical performance of Sn/C composite thin film anodes. J Power Sources, 2008, 184: 481–484
Marcinek M, Hardwick L J, Richardson T J, et al. Microwave plasma chemical vapor deposition of nano-structured Sn/C composite thin-film anodes for Li-ion batteries. J Power Sources, 2007, 173: 965–971
Hu R Z, Liu H, Zeng M Q, et al. Core/shell and multi-scale structures enhance anode performance of Sn-C-Ni composite thin film in lithium ion battery. J Mater Chem, 2011, 21: 4629–4635
Hu R Z, Zhang L, Liu X, et al. Investigation of immiscible alloy system of Al-Sn thin films as anodes for lithium ion batteries. Electrochem Commun, 2008, 10: 1109–1112
Hu R Z, Zeng M Q, Li C Y, et al. Microstructure and electrochemical performance of thin film anodes for lithium ion batteries in immiscible Al-Sn system. J Power Sources, 2009, 118: 268–273
Hu R Z, Shi Q, Wang H, et al. Influences of composition on the electrochemical performance in immiscible Sn-Al thin films as anodes for lithium ion batteries. J Phys Chem C, 2009, 113: 18953–18961
Bazin L, Mitra S, Taberna P L, et al. High rate capability pure Sn-based nanoarchitectured electrode assembly for rechargeable lithium batteries. J Power Sources, 2009, 578–582
Hassoun J, Panero S, Simon P, et al. High-rate, long-life Ni-Sn nanostructured electrodes for lithium-ion batteries. Adv Mater, 2007, 19: 1632–1635
Idota Y, Kubota T, Matsufuji A. Tin-based amorphous oxide: A high-capacity lithium-ion-storage material. Science, 1997, 276: 1395–1397
Santos-Pena J, Brousse T, Sanchez L, et al. Antimony doping effect on the electrochemical behavior of SnO2 thin film electrode. J Power Sources, 2001, 97/98: 232–234
Brousse T, Retoux R, Herterich U, et al. Thin-film crystalline SnO2-lithium electrodes. J Electrochem Soc, 1998, 145: 1–4
Mohamedi M, Lee S J, Takahashi D. Amorphous tin oxide films: Preparation and characterization as an anode active material for lithium ion batteries. Electrochim Acta, 2001, 46: 1161–1168
Zhao Y M, Zhou Q, Liu L, et al. A novel and facile route of ink-jet printing to thin film SnO2 anode for rechargeable lithium ion batteries. Electrochim Acta, 2006, 51: 2639–2645
Li N C, Martin C R, Scrosati B. A high-rate, high-capacity, nanostructured tin oxide electrode for lithium-ion battery applications. Electrochem Solid-State Lett, 2000, 3: 316–318
Nam S C, Yoon Y S, Yun K S, et al. Reduction of irreversibility in the first charge of tin oxide thin film negative electrodes. J Electrochem Soc, 2001, 148: A220–A223
Nam S C, Yoon Y S, Cho W I, et al. Enhancement of thin film tin oxide negative electrodes for lithium batteries. Electrochem Commun, 2001, 3: 6–10
Li Y N, Zhao S L, Qin Q Z. Nanocrystalline tin oxides and nickel oxide film anodes for Li-ion batteries. J Power Sources, 2003, 114: 113–120
Kim Y I, Lee W H, Moon H S, et al. Effect of Si addition to thin-film SnO2 micro-battery anodes on cycling performance. J Power Sources, 2001, 101: 253–258
Kim Y I, Yoon C S, Park J W. Microstructural evolution of electrochemically cycled Si-doped SnO2-lithium thin-film battery. J Solid State Chem, 2001, 160: 388–393
Zhang J, Chen L B, Li C C, et al. Amorphous SnO2-SiO2 thin films with reticular porous morphology for lithium-ion batteries. Appl Phys Lett, 2008, 93: 264102–264104
Ahn H J, Kim Y S, Seong T Y. Improvement of the electrochemical properties of SnO2 electrodes for lithium rechargeable battery using protective Ta2O5 thin films. Solid-State Ionics, 2005, 176: 699–702
Li Y, Tu J P, Huang X H, et al. Net-like SnS/carbon nanocomposite film anode material for lithium ion batteries. Electrochem Commun, 2007, 9: 49–53
Xue M Z, Cheng S C, Yao J, et al. Electrochemical properties of SnSe thin film electrode fabricated by pulsed laser deposition (in Chinese). Acta Phys Chim Sin, 2006, 22: 383–387
Park K S, Park Y J, Kim M K, et al. Characteristics of tin nitride thin film negative electrode for thin film microbattery. J Power Sources, 2001, 103: 67–71
Li Y. Synthesis and electrochemical performances of SnS anode and Sn-Ag-O, etc. thin films anodes for lithium ion batteries (in Chinese). Dissertation for the Doctoral Degree. Hangzhou: Zhejiang University, 2006. 80–101
Zhu J X, Guo Z P, Zhang P, et al. Highly porous reticular tin-obalt oxide composite thin film anodes for lithium ion batteries. J Mater Chem, 2009, 19: 8360–8365
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Hu, R., Liu, H., Zeng, M. et al. Progress on Sn-based thin-film anode materials for lithium-ion batteries. Chin. Sci. Bull. 57, 4119–4130 (2012). https://doi.org/10.1007/s11434-012-5303-z
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DOI: https://doi.org/10.1007/s11434-012-5303-z