Chinese Science Bulletin

, Volume 57, Issue 19, pp 2352–2360 | Cite as

C-H bond amination by iron-imido/nitrene species

Open Access
Review Special Topic Iron Catalysis in Synthetic Organic Chemistry

Abstract

C-H amination by iron-imido/nitrene species has attracted increasing research interest in recent years because of its potential use in economical and environmentally benign syntheses of amino compounds. With the aim of providing a comprehensive overview of this field, which is of interest to both the synthetic organic and inorganic communities, this paper reviews the status quo of C-H amination chemistry by iron-imido/nitrene intermediates, as well as by well-defined iron-imido/nitrene compounds, with special emphasis on their structure/reactivity correlations. Achievements, problems, and perspectives in this growing field are discussed.

Keywords

iron nitrene imido C-H amination C-H activation 

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Copyright information

© The Author(s) 2012

Authors and Affiliations

  1. 1.State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghaiChina

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