Abstract
2-(4-Pyridyl)imino nitroxide and tetraphenylporphyrin zinc(II) formed a stable complex by noncovalent bonding in a nonpolar solution. Nicotine displaced 2-(4-pyridyl)imino nitroxide when it was added to a solution of 2-(4-pyridyl)imino nitroxide-tetraphenylporphyrin zinc(II). The fluorescence intensity of tetraphenylporphyrin zinc(II) was altered by sequentially addition of 2-(4-pyridyl)imino nitroxide and nicotine. This was used to develop a new method for detection of nicotine.
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Han, H., Zhang, G. & Wang, H. 2-(4-Pyridyl)imino nitroxide-tetraphenylporphyrin zinc(II): A chemosensing ensemble for nicotine. Chin. Sci. Bull. 57, 1609–1611 (2012). https://doi.org/10.1007/s11434-012-5030-5
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DOI: https://doi.org/10.1007/s11434-012-5030-5