Abstract
L10 FePt films were deposited on MgO (001) substrates heated to 700°C by magnetron sputtering. Assisted by the misfit of lattice between film and substrate, strong (001) texture was formed. The film at nominal thickness t N = 5 nm was composed of nanoparticles with a size of ∼70 nm, and showed a high coercivity of ∼105 kOe at 4.2 K. At t N =∼50 nm, as the film changed from discontinuous to continuous, the coercivity dropped about one order of magnitude. Micromagnetic simulation implies that the magnetization reversal is a vortex-like nuclear type. The ideal coercivity of a separated single-domain L10 FePt nanoparticle with a size of 70 nm× 70 nm× 5 nm is ∼121 kOe. This tells us that the experimental coercivity has nearly reached the limit of ideal single crystalline nanoparticles.
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Xiao M, Do H, Weresin W, et al. Recording studies of perpendicular media leading to 230 Gb/in2. J Appl Phys, 2006, 99: 08E712
Lodder J C. Magnetic structures in Co-Cr media for perpendicular magnetic recording. J Magn Magn Mater, 1996, 159: 238–248
Ouchi K. Recent advancements in perpendicular magnetic recording. IEEE Trans Magn, 2001, 37: 1217–1222
Wood R. The feasibility of magnetic recording at 1 Terabit per square inch. IEEE Trans Magn, 2000, 36: 36–42
Zhuang Z. Effects of stoichiometry on the magnetic and structural properties of perpendicular barium ferrite thin film media. IEEE Trans Magn, 2000, 36: 2405–2407
Speliotis D E. Magnetic recording beyond the first 100 years. J Magn Magn Mater, 1999, 193: 29–35
Weller D, Moser A, Folks L, et al. High K u materials approach to 100 Gbits/in2. IEEE Trans Magn, 2000, 36: 10–15
Verdes C, Chantrell R W, Satoh A, et al. Self-organization, orientation and magnetic properties of FePt nanoparticle arrays. J Magn Magn Mater, 2006, 304: 27–31
Kuo C M, Kuo P C, Wu H C. Microstructure and magnetic properties of Fe100-x Ptx alloy films. J Appl Phys, 1999, 85: 2264–2269
Xu Y F, Chen J S, Wang J P. In situ ordering of FePt thin films with face-centered-tetragonal (001) texture on Cr100-x Rux underlayer at low substrate temperature. Appl Phys Lett, 2002, 80: 3325–3327
Suzuki T, Honda N, Ouchi K. Magnetization reversal process in polycrystalline ordered Fe-Pt (001) thin films. J Appl Phys, 1999, 85: 4301–4303
Jeong S, Hsu Y N, Laughlin D E, et al. Magnetic properties of nanostructured CoPt and FePt thin films. IEEE Trans Magn, 2000, 36: 2336–2338
Zeng H, Yan M L, Sellmyer D J. Orientation-controlled nonepitaxial L10 CoPt and FePt films. Appl Phys Lett, 2002, 80: 2350–2352
Coffey K, Parker M A, Howard J K. High anisotropy L10 thin films for longitudinal recording. IEEE Trans Magn, 1995, 31: 2737–2739
Platt C L, Wierman K W, Svedberg E B, et al. L10 ordering and microstructure of FePt thin films with Cu, Ag, and Au additive. J Appl Phys, 2002, 92: 6104–6109
Maeda T, Kai T, Kikitsu A, et al. Reduction of ordering temperature of an FePt ordered alloy by addition of Cu. Appl Phys Lett, 2002, 80: 2147–2149
Luo C P, Sellmyer D J. Magnetic properties and structure of Fe/Pt thin films. IEEE Trans Magn, 1995, 31: 2764–2766
Shima T, Moriguchi T, Mitani S, et al. Low temperature fabrication of L10 ordered FePt alloy by alternate monatomic layer deposition. Appl Phys Lett, 2002, 80: 288–290
Lin J J, Zhang T, Lee P, et al. Magnetic trapping induced low temperature phase transition from fcc to fct in pulsed laser deposition of FePt:Al2O3 nanocomposite thin films. Appl Phys Lett, 2007, 91: 063120
Pan Z Y, Lin J J, Zhang T, et al. Lowering of L10 phase transition temperature of FePt thin films by single shot H+ ion exposure using plasma focus device. Thin Solid Films, 2009, 517: 2753–2757
Zhang Z G, Singh A K, Yin J H, et al. Double-layered perpendicular magnetic recording media of granular-type FePt-MgO films. J Magn Magn Mater, 2005, 287: 224–228
Suzuki T, Honda N, Ouchi K. Fe-Pt media for perpendicular magnetic recording. IEEE Trans Magn, 1999, 35: 2748–2750
Jeong S K, McHenry M E, Laughlim D E. Growth and characterization of L10 FePt and CoPt (001) textured polycrystalline thin films. IEEE Trans Magn, 2001, 37: 1309–1311
Zhang Z G, Kang K, Suzuki T. FePt (001) texture development on an Fe-Ta-C magnetic soft underlayer with SiO2/MgO as an intermediate layer. Appl Phys Lett, 2003, 83: 1785–1787
Kim H, Lee S. Texture development and magnetic properties of sputter-deposited FePt-MgO nanocomposite films. J Appl Phys, 2005, 97: 10H304
Sun S, Murray C B, Weller D, et al. Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices. Science, 2000, 287: 1989–1992
Sun S, Fullerton E E, Weller D, et al. Compositionally controlled FePt nanoparticle materials. IEEE Trans Magn, 2001, 37: 1239–1243
Hu J F, Chen J S, Lim B C, et al. Underlayer diffusion-induced enhancement of coercivity in high anisotropy FePt thin films. J Magn Magn Mater, 2008, 320: 3068–3070
Xu X H, Wu H S, Li X L, et al. Structure and magnetic properties of FePt and FePt/C thin films by post-annealing. Physica B, 2004, 348: 436–439
Watanabe M, Masumoto T, Ping D H, et al. Microstructure and magnetic properties of FePt-Al-O granular thin films. Appl Phys Lett, 2000, 76: 3971–3973
Ito H, Kusunoki T, Saito H, et al. The study on the ordering mechanism in FePt thin films with rapid thermal annealing process. J Magn Magn Mater, 2004, 272–276: 2180–2181
Shima T, Takanashi K, Takanashi Y K, et al. Coercivity exceeding 100 kOe in epitaxially grown FePt sputtered films. Appl Phys Lett, 2004, 85: 2571–2573
Li G Q, Takahoshi H, Ito H, et al. Morphology and domain pattern of L10 ordered FePt films. J Appl Phys, 2003, 94: 5672–5677
Donahue M J, Porter D G. OOMMF User’s Guide Version 1.0, 1999
Li G Q, Takahoshi H, Ito H, et al. Mechanism of magnetization process of island-like L10 FePt films. J Magn Magn Mater, 2005, 287: 219–223
Li G Q, Saito H, Ishio S, et al. Asymmetric initial magnetization process of elongated particles in nucleation-type L10 FePt films. J Magn Magn Mater, 2007, 315: 126–131
Li G Q, Saito H, Ishio S, et al. Morphology and domain pattern of epitaxially grown L10 FePt elongated particles. J Magn Magn Mater, 2007, 319: 73–79
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Mo, X., Xiang, H., Li, G. et al. Magnetic properties of perpendicularly orientated L10 FePt nanoparticles. Chin. Sci. Bull. 55, 680–686 (2010). https://doi.org/10.1007/s11434-010-0077-7
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DOI: https://doi.org/10.1007/s11434-010-0077-7