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Structural diversity and reactivity of d10 metal-(4-pyridylthio)acetate system

  • Articles / Inorganic Chemistry
  • Published:
Chinese Science Bulletin

Abstract

The hydrothermal synthesis and crystal structures of four coordination polymers, namely, 2D [Zn(μ3-ta)(pytaH)] n (1), 2D [Zn(μ3-pyta)Cl] n (2), 1D [Cd(μ-pyta)2(H2O)] n (3), and 3D [Cd(μ3-pyta)(μ-Cl)] n (4) (pyta = (4-pyridylthio)acetate, ta = thioglycolate), are reported. They are based on (4-pyridylthio)acetate and its derived ligand. The ta2− ligand present in 1 was generated from an in situ C(sp2)-S bond cleavage of the pyta ligand. In these compounds, versatile intermolecular interactions, such as close S…S interactions and strong (O-H…O/N/S) or weak (C-H…O/S, C-H…Cl) hydrogen bonding interactions, play an important role in the formation of three-dimensional supramolecular networks in the solid state.

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Authors and Affiliations

  1. Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, China

    YueHua Zhang, Jing Wang, LingLing Zheng, Sheng Hu, ZhuoJia Lin & MingLiang Tong

Authors
  1. YueHua Zhang
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  2. Jing Wang
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  3. LingLing Zheng
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  4. Sheng Hu
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  5. ZhuoJia Lin
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  6. MingLiang Tong
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Corresponding authors

Correspondence to ZhuoJia Lin or MingLiang Tong.

Additional information

Supported by the National Natural Science Foundation of China (Grant No. 20525102), Specialized Research Foundation for the Doctoral Program of Higher Education (Grant No. 20060558081), “Hundred Talents” Foundation of Sun Yat-Sen University, Doctoral Foudation of Ministry of Education of China for New Scholar (Grant No. 200805581015), and Natural Science Foundation of Guangdong Province (Grant No. 8451027501001515)

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Zhang, Y., Wang, J., Zheng, L. et al. Structural diversity and reactivity of d10 metal-(4-pyridylthio)acetate system. Chin. Sci. Bull. 54, 4277–4284 (2009). https://doi.org/10.1007/s11434-009-0673-6

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  • DOI: https://doi.org/10.1007/s11434-009-0673-6

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