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A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2-(ip)6]·6H2O with a non-interpenetrated α-Po net

  • Articles / Inorganic Chemistry
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Chinese Science Bulletin

Abstract

A new 3-D porous Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2(ip)6]·6H2O (1) (bpy = 2,2′-bipyridine, H2ip = isophthalic acid) has been hydrothermally synthesized and structurally characterized. Compound 1 crystallizes in the triclinic space group P \( \bar 1 \) and displays a 3-D non-interpenetrated α-Po network with 1-D channels filled transversely by the hexa-nuclear chain-like (H2O)6. The EPR and thermal stability of 1 were investigated.

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, 350002, China

    XiangLi Jia, Jian Zhou, ShouTian Zheng & GuoYu Yang

  2. College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475000, China

    JunWei Zhao

  3. College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002, China

    ZhaoHui Li

Authors
  1. XiangLi Jia
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  2. Jian Zhou
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  3. JunWei Zhao
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  4. ZhaoHui Li
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  5. ShouTian Zheng
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  6. GuoYu Yang
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Corresponding author

Correspondence to GuoYu Yang.

Additional information

Supported by the National Natural Science Foundation for Distinguished Young Scholars of China (Grant No. 20725101), Major State Basic Research Development Program of China (Grant No. 2006CB932904), Natural Science Foundation of Fujian Province (Grant Nos. E0510030, 2008F3120), National Natural Science Fund of China (Grant Nos. 50872133, 20821061), and Knowledge Innovation Program of the CAS (Grant No. KJCX2.YW.H01)

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Jia, X., Zhou, J., Zhao, J. et al. A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2-(ip)6]·6H2O with a non-interpenetrated α-Po net. Chin. Sci. Bull. 54, 4272–4276 (2009). https://doi.org/10.1007/s11434-009-0549-9

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  • DOI: https://doi.org/10.1007/s11434-009-0549-9

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