Abstract
This paper reports the synthesis of a water soluble conjugated polymer poly(p-phenylene vinylene-co-sodium methacrylate) (ws-P(PV-co-SMA)) and the multilayer of the derived copolymer assembling poly(diallyl dimethyl ammanium chloride) (PDDA). The self-assembling process of the multilayer was monitored by UV-vis absorption spectroscopy, and the data indicated a linear increase in film thickness with a number of ws-P(PV-co-SMA)/PDDA bilayers. The alternative deposition of ws-P (PV-co-SMA) and PDDA allowed the insertion of a non-conjugated layer between the conjugated layers, thus the migration of the photogenerated polarons was effectively confined in the isolated ws-P (PV-co-SMA) chains. Consequently, the photoluminescence quantum yield reached 0.68, 30 times higher than that of pure poly(p-phenylen vinylene). The distinct electronic interactions between conjugated segments were confirmed by comparative analyses of the excitation spectra and time-resolved photoluminescence spectra of ws-P(PV-co-SMA) solid film and the assembled multilayers. The confinement effect of the PDDA layer on the photogenerated carriers was verified by the surface photovoltage spectroscopic measurement on both ws-P(PV-co-SMA) solid film and self-assembled multilayers.
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Supported by the National Basic Research Program of China (Grant No. 2007CB 808000) and Open Project of State Key Laboratory of Supramolecular Structure and Materials (Grant No. SKLSSM200705)
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Zhang, B., Lin, H., Tang, J. et al. A novel water-soluble anionic conjugated copolymer containing poly(p-phenylene vinylene) segments: Copolymer synthesis and multilayer construction by assembling poly(diallyl dimethyl ammonium chloride). Chin. Sci. Bull. 54, 3515–3520 (2009). https://doi.org/10.1007/s11434-009-0512-9
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DOI: https://doi.org/10.1007/s11434-009-0512-9