Abstract
In the fabrication process of nanoelectronic device arrays based on single-wall carbon nanotube (SWCNT), oriented alignment of SWCNTs and property modification of metallic SWCNTs in the array are the key problems to be solved. Pulse gas alignment with substrate downward tilt is proposed to realize the controllable alignment of SWCNTs. Experimental results demonstrate that 84% SWCNTs are aligned in −15°−15° angular to the pulse gas direction. A modified nanomanipulation technology based on atomic force microscope (AFM) is utilized to perform various kinds of SWCNT manipulation, such as SWCNT separation from the “Y” CNT, catalyst removal from the SWCNT end, continual nano buckles fabrication on SWCNT and even stretching to break, which provides a feasible way to modify the size, shape and the electrical property of SWCNTs.
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References
Iijima S, Ichihashi T. Single-shell carbon nanotubes of 1 nm diameter. Nature, 1993, 363: 603–604
Baughman R H, Zakhidov A A, de Heer W A. Carbon nanotubes-The route toward applications. Science, 2002, 297: 787–792
McEuen P L, Fuhrer M S, Park H K. Single-walled carbon nanotube electronics. IEEE Tran Nanotech, 2002, 1(1): 78–85
Avouris P, Appenzeller J, Martel R, et al. Carbon nanotube electronics. J Proc IEEE, 2003, 91(11): 1172–1784
Dai H J, Javey A, Pop A, Mann D, et al. Electrical transport properties and field-effect transistors of carbon nanotubes. NANO Brief Rep Rev, 2006, 1(1): 1–4
Cheng C X, Zhang Y F. Multi-channel field effect transstor constructed by carbon nanotube. Sci Chin Ser E Eng & Mat Sci, 2005, 35(11): 1156–1165
Li P J, Zhang W J, Zhang Q F, et al. Nanoelectronic logic circuits with carbon nanotube transistors. Acta Phys Sin, 2007, 56(2): 1054–1060
Hu Y F, Yao K, Wang S, et al. Fabrication of high performance top-gate complementary inverter using a single carbon nanotube and via a simple process. Appl Phys Lett, 2007, 90: 223116–223118
Huang S M, Cai X Y, Liu J. Growth of millimeter-long and horizontally aligned single-walled carbon nanotubes on flat substrates. J Am Chem Soc, 2003, 125: 5636–5637
Han S, Liu X, Zhou C. Template-free directional growth of single-walled carbon nanotubes on a-and r-plane sapphire. J Am Chem, 2005, 127: 5294–5295
Marcus D L, Novak J P, Snow E S. Simple route to large-scale ordered arrays of liquid-deposited carbon nanotubes. Nano Lett, 2004, 4(4): 603–606
Yan Y H, Li S, Chen L Q, et al. Large-scale submicron horizontally aligned single-walled carbon nanotube surface arrays on various substrates produced by a fluidic assembly method. Nanotechnology, 2006, 17: 5696–5701
Rao S G, Huang L, Setyawan W Y, et al. Large-scale assembly of carbon nanotubes. Nature, 2003, 425: 36–37
Huang L M, Cui X D, Dukovic G. Self-organizing high-density single-walled carbon nanotube arrays from surfactant suspensions. Nanotechnology, 2004, 15: 1450–1454
Strobl C J, Schäflein C, Beierlein U. Carbon nanotube alignment by surface acoustic waves. Appl Phys Lett, 2004, 85: 1427–1429
Chen Z, Yang Y L, Chen F, et al. Controllable interconnection of single-walled carbon nanotubes under AC electric field. J Phys Chem B, 2005, 109(23): 11420-11423
Yu G, Cao A, Lieber C M. Large-area blown bubble films of aligned nanowires and carbon nanotubes. Nat Nano, 2007, 2: 372–377
Krupke R, Hennrich F, Lohneysen H V, et al. Separatin of metallic from semiconducting single walled carbon nanotubes. Science, 2003, 301: 344–347
Postma H W C, Teepen T, Yao Z, et al. Carbon nanotube single-electron transistors at room temperature. Science, 2001, 293: 76–79
Zhang Y J, Li P, Hu Y Z. Manipulation and cut of carbon nanotube. Chin Sci bull, 2002, 47(14): 1066–1070
Tian X J, Wang Y C, Xi N, et al., Study on single CNT’s accurate assembly and electrical contact for fabricating nanoelectronic device. J Chin Electr Micr Soc, 2006, 25(6): 490–493
Liu S J, Shen Z Y, Hou S M, et al. Study on the manipulation of carbon nanotubes with atomic force microscopy. Acta Physico-Chimica Sin, 2003, 3: 233–236
Postma H W C, Sellmeijer A, Dekker C. Manipulation and imaging of individual single-walled carbon nanotubes with an atomic force microscope. Adv Mater, 2000, 12(17): 1299–1302
Zhang Y J, Li P, Hu Y Z, et al., Atomic force microscopic measurement of lateral pushing forces during nanomanipulation. J Tsinghua Univ (Sci Tech), 2004, 44(8): 1025–1028
Vigolo B, Penicaud A, Coulon C, et al. Macroscopic fibers and ribbons of oriented carbon nanotubes. Science, 2000, 290: 1331–1334
Li J Q, Zhang Q, Peng N, et al. Manipulation of carbon nanotubes using AC dielectrophoresis. Appl Phys Lett, 2005, 86: 153116–153118
Tian X J, Wang Y C, Liu L Q, et al.. AFM based nanomanipulation system with 3D force feedback. Chin J Sci Instr, 2006, 27(7): 661–665
Cheng H M. Carbon nanotubes: synthesis, microstructure, properties and applications. Beijing: Chemical Industry Press, 2002
Bhushan B. Nanotribology and nanomechanics, In: Springer Handbook of Nanotechnology. Berlin: Springer Berlin Heidelberg, 2004
Larsson P, Larsson J A, Ahuja R, et al. Calculating carbon nanotube catalyst adhesion strengths. Phys Rev B, 2007, 75(11): 115419–115424
Zhang X H, Lou P T, Zhang Z Q, et al. Studies on nanobubbles formed at solid/liquid interface. J Chin Electr Micro Soc, 2003, 22(2): 136–141
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Supported by the National High Technology Research and Development Program (863 Program No. 2006AA04Z320) and Excellent Young Scholars Training Grant of Liaoning Province (Grant No. 2005220025)
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Tian, X., Wang, Y., Xi, N. et al. Pulse gas alignment and AFM manipulation of single-wall carbon nanotube. Chin. Sci. Bull. 53, 3590–3596 (2008). https://doi.org/10.1007/s11434-008-0496-x
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DOI: https://doi.org/10.1007/s11434-008-0496-x