Skip to main content
SpringerLink
Log in

Preparation of Rh-TPPTS complex intercalated layered double hydroxide and influences of host and guest compositions on its catalytic performances in hydroformylation reaction

  • Articles
  • Applied Chemistry
  • Published:
Chinese Science Bulletin

Abstract

Based on the concept of intercalation chemistry of layered double hydroxides (LDHs), RhCl(CO)-(TPPTS)2(TPPTS: P(m-C6H4SO3Na)3) and TPPTS co-intercalated LDHs were successfully synthesized by in situ complexation method. Characterizations of structure and composition of composite materials by powder XRD, FT-IR, and ICP-AES techniques confirmed the supramolecular structures of the catalytic species intercalated LDHs. The correlation between catalytic performance of intercalated catalyst and the composition of both host layers and interlayer guest species was also investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Dickson R S. Homogeneous Catalysis with Compounds of Rhodium and Iridium. New York: Springer, 1985

    Google Scholar 

  2. Cum G, Famulari P, Marchetti M, et al. Hydroformylation by rhodium catalysts supported on oligomeric arylamides. J Mol Catal A-Chem, 2004, 218(2): 211–216

    Article  CAS  Google Scholar 

  3. Hung K G W, Papadias D, Björnbom P, et al. Reverse-flow operation for application of imperfectly immobilized catalysts. AIChE J, 2003, 49(1): 151–167

    Article  CAS  Google Scholar 

  4. Lenarda M, Storaro L, Ganzerla R. Hydroformylation of simple olefins catalyzed by metals and clusters supported on unfunctionalized inorganic carriers. J Mol Catal A, 1996, 111(3): 203–237

    Article  Google Scholar 

  5. Huang L, Kawi S. An active and stable Wilkinson’s complex-derived SiO2-tethered catalyst via an amine ligand for cyclohexene hydroformylation. Catal Lett, 2004, 92(1–2): 57–62

    Article  CAS  Google Scholar 

  6. Ichikawa M. Catalytic hydroformylation of olefins over the rhodium, bimetallic Rh-Co, and cobalt carbonyl clusters supported with some metal oxides. J Catal, 1979, 59(1): 67–78

    Article  CAS  Google Scholar 

  7. Zhu H J, Ding Y J, Yin H M, et al. Supported rhodium and supported aqueous-phase catalyst, and supported rhodium catalyst modified with water-soluble TPPTS ligands. Appl Catal A-General, 2003, 245(1): 111–117

    Article  CAS  Google Scholar 

  8. Cavani F, Trifirò F, Vaccari A. Hydrotalcite-type anionic clays: preparation, properties and application. Catal Today, 1991, 11(2): 173–301

    Article  CAS  Google Scholar 

  9. Khan A I, O’Hare D. Intercalation chemistry of layered double hydroxides: recent developments and applications. J Mater Chem, 2002, 12(11): 3191–3198

    Article  CAS  Google Scholar 

  10. Meyn M, Beneke K, Lagaly G. Anion-exchange reactions of layered double hydroxides. Inorg Chem, 1990, 29(26): 5201–5207

    Article  CAS  Google Scholar 

  11. Jakupca M, Dutta P K. Thermal and spectroscopic analysis of a fatty acid-layered double-metal hydroxide and its application as a chromatographic stationary phase. Chem Mater, 1995, 7(5): 989–994

    Article  Google Scholar 

  12. Wei M, Yuan Q, Evans D G, et al. Layered solids as a “molecular container” for pharmaceuticalagents: L-tyrosine-intercalated layered double hydroxiedes. J Mater Chem, 2005, 15(11): 1197–1203

    Article  Google Scholar 

  13. Khan A I, Lei L, Norquist A J, et al. Intercalation and controlled release of pharmaceutically active compounds from a layered double hydroxide. Chem Commun, 2001, 1(22):2342–2343

    Article  Google Scholar 

  14. Tyner K M, Schiffman S R, Giannelis E P. Nanobiohybrids as delivery vehicles for camptothecin. J Control Release, 2004, 95(3): 501–514

    Article  PubMed  CAS  Google Scholar 

  15. Choudary B M, Chowdari N S, Jyothi K, et al. Catalytic asymmetric dihydroxylation of olefins with reusable OsO4 2− on ion-exchangers: The scope and reactivity using various cooxidants. J Am Chem Soc, 2002, 124(19): 5341–5349

    Article  PubMed  CAS  Google Scholar 

  16. Bhattacharjee S, Dines T J, Anderson J A. Synthesis and application of layered double hydroxide-hosted catalysts for stereoselective epoxidation using molecular oxygen or air. J Catal, 2004, 225(2): 398–407

    Article  CAS  Google Scholar 

  17. Sels B, Vos D D, Buntinx M, et al. Layered double hydroxides exchanged with tungstate as biomimetic catalysts for mild oxidative bromination. Nature, 1999, 400(6747): 855–857

    Article  CAS  Google Scholar 

  18. Wei M, Zhang X, Li X J, et al. Rh-TPPTS intercalated layered double hydroxides as hydroformylation catalyst. AIChE J, 2007, 53(11): 2916–2924

    Article  CAS  Google Scholar 

  19. Xie X M. Study on preparation of [ZnAl-LDH]. J Inorg Mater (in Chinese), 1999, 14(2): 245–250

    CAS  Google Scholar 

  20. Xie X M. Preparation and characterization of Ni-Al hydrotalcite like compound. J Inorg Chem (in Chinese), 2000, 16(1): 43–46

    CAS  Google Scholar 

  21. Pagano M A, Forano C, Besse J P. Delamination of layered double hydroxides by use of surfactants. Chem Comm, 2000, (1): 91–92

  22. Hussein M Z B, Hwa T K. Synthesis and properties of layered organic-inorganic hybrid material: Zn-Al layered double hydroxide-dioctyl sulfosuccinate nanocomposite. J Nanoparticle Res, 2000, 2(3): 293–298

    Article  CAS  Google Scholar 

  23. Bookin A S, Drits V. Polytype diversity of the hydrotalcite-like minerals. I. Possible polytypes and their diffraction features. Clays Clay Miner, 1993, 41(5): 551–557

    Article  CAS  Google Scholar 

  24. Vaysse C, Guerlou-Demourgues L, Delmas C. Thermal evolution of carbonate pillared layered hydroxides with (Ni, L) (L = Fe, Co) based slabs: Grafting or nongrafting of carbonate anions. Inorg Chem, 2002, 41(25): 6905–6913

    Article  PubMed  CAS  Google Scholar 

  25. Prevot V, Forano C, Besse J P, et al. Syntheses and thermal and chemical behavior of tartrate and succinate intercalated Zn3Al and Zn2Cr layered double hydroxides. Inorg Chem, 1998, 37(17): 4293–4301

    Article  PubMed  CAS  Google Scholar 

  26. Herrmann W A, Kellner J, Riepl H. Wasserlösliche Metallkomplexe und Katalysatoren. III. Neue wasserlösliche Metallkomplexe des sulfonierten Triphenylphosphans (TPPTS): Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Ag, Au. J Organomet Chem, 1990, 389(1): 103–128

    Article  CAS  Google Scholar 

  27. Kanezaki E. Intercalation of naphthalene-2,6-disulfonate between layers of Mg and Al double hydroxide: Preparation, powder X-Ray diffraction, fourier transform infrared spectra and X-Ray photoelectron spectra. Mater Res Bull, 1999, 34(9): 1435–1440

    Article  CAS  Google Scholar 

  28. Kanezaki E. Unexchangeable interlayer anions; synthesis and characterization of Zn/Al-and Mg/Al-layered double hydroxides with interlayer alizarin red S. J Incl Phenom Macrocyclic Chem, 2003, 46(1–2): 89–95

    Article  CAS  Google Scholar 

  29. He Q, Yin S, Sato T. Synthesis and photochemical properties of zinc-aluminum layered double hydroxide/organic UV ray absorbing molecule/silica nanocomposites. J Phys Chem Solids, 2004, 65(2–3): 395–402

    Article  CAS  Google Scholar 

  30. Choy J H, Jung J S, Oh J M, et al. Layered double hydroxide as an efficient drug reservoir for folate derivatives. Biomaterials, 2004, 25(15): 3059–3064

    Article  PubMed  CAS  Google Scholar 

  31. Dean J A. Lange’s Handbook of Chemistry (in Chinese). Ver. 2. Beijing: Science Press, 2003

    Google Scholar 

  32. Wang Z, Yuan G, Zhou Q Z. Studies on hydroformylation of 1-hexene catalyzed by with water-soluble Rhodium-phosphine complex. Petrochem Technol (in Chinese), 1987, 16(10): 691–698

    CAS  Google Scholar 

  33. Wu J C, Yuan G, Zhou Q Z. Preparation of high-carbon aldehydes with water-soluble Rhodium-phosphine complex. Petrochem Technol (in Chinese), 1991, 20(2): 79–89

    CAS  Google Scholar 

  34. Park M, Lee C, Lee E J, et al. Layered double hydroxides as potential solid base for beneficial remediation of endosulfan-contaminated soils. J Phys Chem Solids, 2004, 65(2–3): 513–516

    Article  CAS  Google Scholar 

  35. Zhang H, Qi R, Liu L, et al. Studies on particle size controlled synthesis and selectivity of crystal growth direction of MgFe layered double hydroxides. Chin J Chem Phys (in Chinese), 2003, 16(1): 45–50

    Google Scholar 

  36. Choudary B M, Kantam M L, Reddy N M, et al. Layered-double-hydroxide-supported Pd(TPPTS)2Cl2: A new heterogeneous catalyst for Heck arylation of olefins. Catal Lett, 2002, 82(1–2): 79–83

    Article  CAS  Google Scholar 

  37. Choudary B M, Chowdari N S, Kantam M L, et al. Catalytic asymmetric dihydroxylation of olefins with new catalysts: The first example of heterogenization of OsO4 2− by ion-exchange technique. J Am Chem Soc, 2001, 123(37): 9220–9221

    Article  PubMed  CAS  Google Scholar 

  38. Ding H, Hanson B E, Glass T E. The effect of salt on selectivity in water-soluble hydroformylation catalysis. Inorg Chim Acta, 1995, 229(1): 329–333

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, China

    Xian Zhang, Jun Lu, Lan Jin & Min Wei

Authors
  1. Xian Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jun Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lan Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Min Wei
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Min Wei.

Additional information

Supported by the Major International Joint Research Program of the National Natural Science Foundation of China (Grant No. 20620130108), the National Natural Science Foundation of China (Grant No. 20601001), the Program for New Century Excellent Talents in University (Grant No. NCET-05-121), the 111 Project (Grant No. B07004) and the Program for Changjing Scholars and Innovative Research Team in University (Grant No. IRT0406)

About this article

Cite this article

Zhang, X., Lu, J., Jin, L. et al. Preparation of Rh-TPPTS complex intercalated layered double hydroxide and influences of host and guest compositions on its catalytic performances in hydroformylation reaction. Chin. Sci. Bull. 53, 1329–1336 (2008). https://doi.org/10.1007/s11434-008-0071-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11434-008-0071-5

Keywords

Search

Navigation