Abstract
The aligned array and thin film of zeolites and molecular sieves possess a variety of potential applications in membrane separation and catalysis, chemical sensors, and microelectronic devices. There are two main synthesis methods for manufacturing the aligned arrays and thin films of zeolites and molecular sieves, i.e. in situ hydrothermal reaction and self-assembly of crystal grains on substrates. Both of them have attracted much attention in the scientific community worldwide. A series of significant progress has been made in recent years. By the in situ hydrothermal synthesis, the oriented nucleation and growth of zeolite and molecular sieve crystals can be achieved by modifying the surface properties of substrates or by changing the composition of synthesis solutions, leading to the formation of uniformly oriented multicrystal-aligned arrays or thin films. On the other hand, the crystal grains of zeolites and molecular sieves can be assembled onto the substrate surface in required orientation using different bondages, for instance, the microstructure in the array or thin film can be controlled. This review is going to summarize and comment the significant results and progress reported recently in manufacturing highly covered and uniformly aligned arrays or thin films of zeolites and molecular sieves. It involves (1) in situ growth of highly aligned zeolite arrays and thin films via embedding functional groups on the substrate surface, modifying the surface microstructure of substrates, as well as varying the composition of synthesis solutions; (2) assembly of zeolite and molecular sieve crystals on various substrates to form aligned arrays and thin films with full coverage by covalent, ionic, and intermolecular coupling interactions between crystals and substrates; (3) coupling surface assembly with microcontact printing or photoetching technique to produce patterned zeolite arrays and thin films. Finally, the functionality and applications of zeolite arrays and thin films are briefly introduced. Some critical issues are addressed for future studies.
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References
Jiang H Y, Zhang B Q, Lin Y S, et al. Synthesis of zeolite membranes. Chin Sci Bull, 2004, 49(24): 2547–2554
Feng S, Bein T. Growth of oriented molecular sieve crystals on organophosphonate films. Nature, 1994, 368: 834–836
Feng S, Bein T. Vertical aluminophosphate molecular sieve crystals grown at inorganic-organic interface. Science, 1994, 265:1839–1841
Lee J S, Lee Y J, Yoon K B, et al. Synthesis of zeolite as ordered multicrystal arrays. Science, 2003, 301: 818–821
Lee Y, Ryu W, Cho G, et al. Oriented growth of TS-1 zeolite ultrathin films on poly(ethylene oxide) monolayer templates. Langmuir, 2005, 21(13): 5651–5654
Wang X D, Zhang B Q, Liu X F, et al. Synthesis of b-oriented TS-1 films on chitosan-modified α-Al2O3 substrates. Adv Mater, 2006, 18(24): 3261–3265
Lang L. In situ growth of continuous b-oriented silicalite-1 membranes. Dissertation for the Master Degree. Tianjin: Tianjin University, 2006. 36–37
Wu C N, Chao K J, Shih H C, et al. Oriented growth of molecular sieves on inorganic membranes. Adv Mater, 1996, 8(12): 1008–1012
Tsai T G, Chao K J, Shih H C, et al. Aligned aluminophosphate molecular sieves crystallized on flouting anodized alumina by hydrothermal microwave heating. Adv Mater, 1997, 9(15): 1154–1157
Munoz T, Balkus K J. Preparation of oriented zeolite UTD-1 membranes via pulsed laser ablation. J Am Chem Soc, 1999, 121(1):139–146
Lang L, Zhang B Q, Liu X F. Synthesis of oriented silicalite-1 films on glass plate and its growth mechanism. J Chem Ind Eng (China), 2006, 57(9): 230–233
Wang Z, Yan Y. Controlling crystal orientation in zeolite MFI thin films by direct in situ crystallization. Chem Mater, 2001, 13(3):1101–1107
Wang Z, Wang H, Yan Y, et al. Pure-silica zeolite low-k dielectric thin films. Adv Mater, 2001, 13(10): 746–749
Li S, Wang X, Yan Y, et al. Molecular sieving in a nanoporous boriented pure-silica-zeolite MFI monocrystal film. J Am Chem Soc, 2004, 126(13): 4122–4123
Li S, Li Z, Yan Y, et al. TEM investigation of formation mechanism of monocrystal-thick b-oriented pure silica zeolite MFI film. J Am Chem Soc, 2004, 126(34): 10732–10737
Zhou M, Zhang B Q, Liu X F. Oriented growth of MFI zeolite membrane without transition zone by in-situ method. Chin J Inorg Chem, 2006, 22(10): 1750–1754
Seike T, Matsuda M, Miyake M. Preparation of b-axis-oriented MFI zeolite thin films using slow dissolution of source material. J Am Ceram Soc, 2004, 87(8): 1585–1587
Yoon K B. Organization of zeolite microcrystals for production of functional materials. Acc Chem Res, 2007, 40(1): 29–40
Yan Y, Bein T. Zeolite thin films with tunable molecular sieve function. J Am Chem Soc, 1995, 117(40): 9990–9994
Mintova S, Mo S, Bein T. Nanosized AlPO4-5 molecular sieves and ultrathin films prepared by microwave synthesis. Chem Mater, 1998, 10(12): 4030–4036
Kulak A, Lee Y J, Yoon K B, et al. Orientation-controlled monolayer assembly of zeolite crystals on glass and mica by covalent linkage of surface-bound epoxide and amine groups. Angew Chem Int Ed, 2000, 39(5): 950–953
Choi S Y, Lee Y J, Yoon K B, et al. Monolayer assembly of zeolite crystals on glass with fullerene as the covalent linker. J Am Chem Soc, 2000, 122(21): 5201–5209
Lee G S, Lee Y J, Yoon K B, et al. Orientation-controlled monolayer assembly of zeolite crystals on glass using terephthaldicarboxaldehyde as a covalent linker. Tetrahedron, 2000, 56(36): 6965–6968
Chun Y S, Ha K, Yoon K B, et al. Diisocyanates as novel molecular binders for monolayer assembly of zeolite crystals on glass. Chem Commun, 2002, (17): 1846–1847
Ha K, Lee Y J, Yoon K B, et al. Facile assembly of zeolite monolayers on glass, silica, alumina, and other zeolites using 3-halopropylsilyl reagents as covalent linkers. Adv Mater, 2000, 12(15):1114–1117
Lai Z, Bonilla G, Tsapatsis M, et al. Microstructural optimization of a zeolite membrane for organic vapor separation. Science, 2003, 300:456–460
Choi J, Lai Z, Tsapatsis M, et al. Uniformly a-oriented MFI zeolite films by secondary growth. Angew Chem Int Ed, 2006, 45(7):1154–1158
Lee G S, Lee Y J, Yoon K B, et al. Preparation of flexible zeolite-tethering vegetable fibers. Adv Mater, 2001, 13(19): 1491–1495
Park J S, Lee Y J, Yoon K B. Marked increase in the binding strength between the substrate and the covalently attached monolayers of zeolite microcrystals by lateral molecular cross-linking between the neighboring microcrystals. J Am Chem Soc, 2004, 126(7): 1934–1935
Kulak A, Park Y S, Yoon K B, et al. Polyamines as strong molecular linkers for monolayer assembly of zeolite crystals on flat and curved Glass. J Am Chem Soc, 2000, 122(38): 9308–9309
Ha K, Park J S, Yoon K B, et al. Aligned monolayer assembly of zeolite crystals on platinum, gold, and indium-tin oxide surfaces with molecular linkages. Micropor Mesopor Mater, 2004, 72(1–3):91–98
Lee J S, Ha K, Yoon K B, et al. Ultrasound-aided remarkably fast assembly of monolayers of zeolite crystals on glass with a very high degree of lateral close packing. Adv Mater, 2005, 17(7): 837–841
Lee J S, Lim H, Yoon K B, et al. Facile Monolayer Assembly of fluorophore-containing zeolite rods in uniform orientations for anisotropic photoluminescence. Angew Chem Int Ed, 2006, 45(32):5288–5292
Zhang B Q, Zhou M, Liu X F, et al. Monolayer assembly of oriented zeolite crystals on α-Al2O3 supported polymer thin films. Adv Mater, doi:10.1002/adma.200701271
Chau J L H, Leung A Y L, Yeung K L. Zeolite micromembranes. Lab Chip, 2003, 3(2): 53–55
Yang G, Zhang X, Yeung K L, et al. A novel method for the assembly of nano-zeolite crystals on porous stainless steel microchannel and then zeolite film growth. J Phys Chem Solids, 2007, 68(1):26–31
Lee G S, Lee Y J, Yoon K B. Layer-by-layer assembly of zeolite crystals on glass with polyelectrolytes as ionic linkers. J Am Chem Soc, 2001, 123(40): 9769–9779
Wang Y J, Tang Y, Wang X D, et al. Fabrication of zeolite coatings on stainless steel grids. J Mater Sci Lett, 2001, 20(23): 2091–2094
Hedlund J, Mintova S, Sterte J. Controlling the preferred orientation in silicalite-1 films synthesized by seeding. Micropor Mesopor Mater, 1999, 28(1): 185–194
Hedlund J, Jareman F, Bons A J, et al. A masking technique for high quality MFI membranes. J Membr Sci, 2003, 222(1–2): 163–179
Hedlund J, Schoeman B, Sterte J. Ultrathin oriented zeolite LTA films. Chem Commun, 1997, (13): 1193–1194
Kornic S, Baker M. Nanoporous zeolite film electrodes. Chem Commun, 2002, (16): 1700–1701
Mintova S, Hedlund J, Sterte J, et al. Continuous films of zeolite ZSM-5 on modified gold surfaces. Chem Commun, 1997, (1): 15–16
Engstrom V, Mihailova B, Sterte J, et al. The effect of seed size on the growth of silicalite-1 films on gold surfaces. Micropor Mesopor Mater, 2000, 38(1): 51–60
Boudreau L C, Kuck J A, Tsapatsis M. Deposition of oriented zeolite A films: in situ and secondary growth. J Membr Sci, 1999, 152(1):41–59
Park J S, Lee G S, Yoon K B. Micropatterned monolayer assembly of zeolite microcrystals on glass by ionic linkages. Micropor Mesopor Mater, 2006, 96(1–3): 1–8
Park J S, Lee G S, Yoon K B, et al. Organization of microcrystals on glass by adenine-thymine hydrogen bonding. J Am Chem Soc, 2002, 124(45): 13366–13367
Cho G, Lee J S, Glatzhofer D T, et al. Ultra-thin zeolite films through simple self-assembled processes. Adv Mater, 1999, 11(6):497–499
Yin X, Zhu G, Yang W, et al. Stainless-steel-net-supported zeolite NaA membrane with high permeance and high permselectivity for oxygen over nitrogen. Adv Mater, 2005, 17(16): 2006–2010
Guo H, Yang W, Qiu S, et al. Hierarchical growth of large-scale ordered zeolite silicalite-1 membranes with high permeability and selectivity for recycling CO2. Angew Chem Int Ed, 2006, 45(42):7053–7056
Jung K T, Shul Y G. Preparation of ZSM-5 zeolite film and its formation mechanism. J Membr Sci, 2001, 191(1–2): 189–197
Lovallo M C, Tsapatsis M. Preferentially oriented submicron silicalite membrane. AIChE J, 1996, 42(11): 3020–3029
Ban T, Ohwaki T, Ohya Y, et al. Preparation of a completely oriented molecular sieve membrane. Angew Chem Int Ed, 1999, 38(22):3324–3326
Mintova S, Bein T. Microporous films prepared by spin-coating stable colloidal suspensions of zeolites. Adv Mater, 2001, 13(24):1880–1883
Pan M, Lin Y S. Template-free secondary growth synthesis of MFI type zeolite membranes. Micropor Mesopor Mater, 2001, 43(3):391–327
Yuan W H, Lin Y S, Yang W S. Molecular sieving MFI-type zeolite membranes for pervaporation separation of xylene isomers. J Am Chem Soc, 2004, 126(15): 4776–4777
Liu X F. Synthesis of MFI-type zeolite membranes and application in selective ethanol permeation. Dissertation for the Doctoral Degree. Tianjin: Tianjin Universtiy, 2007. 63–80
Huang L, Yan Y, Zhao D, et al. Fabrication of ordered porous structures by self-assembly of zeolite nanocrystals. J Am Chem Soc, 2000, 122(14): 3530–3531
Ha K, Lee Y J, Yoon K B, et al. Micropatterning of oriented zeolite monolayers on glass by covalent linkage. Adv Mater, 2000, 12(21):1614–1617
Ha K, Lee Y J, Yoon K B, et al. Photochemical pattern transfer and patterning of continuous zeolite films on glass by direct dipping in synthesis gel. Adv Mater, 2001, 13(8): 594–596
Li S, Demmelmaier C, Yan Y, et al. Micropatterned oriented zeolite monolayer films by direct in situ crystallization. Chem Mater, 2003, 15(14): 2687–2689
Sun W, Lam K F, Yeung K L, et al. Zeolite micropattern for biological applications. Chem Commun, 2005, (39): 4911–4912
Wang H, Wang Z, Yan Y, et al. Surface patterned porous films by convection-assisted dynamic self-assembly of zeolite nanoparticles. Langmuir, 2001, 17(9): 2572–2574
Hwang Y K, Lee U H, Park S E, et al. Microwave-induced fabrication of MFI zeolite crystal films onto various metal oxide substrates. Chem Lett, 2005, 34(12): 1596–1597
Kim H S, Lee S M, Yoon K B, et al. Aligned inclusion of hemicyanine dyes into silica zeolite films for second harmonic generation. J Am Chem Soc, 2004, 126(2): 673–682
Mass H, Calzaferri G. Trapping energy from and injecting energy into dye-zeolite nanoantennae. Angew Chem Int Ed, 2002, 41(13):2284–2288
Calzaferri G, Huber S, Maas H, et al. Host-guest antenna materials. Angew Chem Int Ed, 2003, 42(32): 3732–3758
Ruiz A Z, Li H, Calzaferri G. Organizing supramolecular functional dye-zeolite crystals. Angew Chem Int Ed, 2006, 45(32): 5282–5287
Huber S, Ruiz A Z, Calzaferri G, et al. Optical spectroscopy of inorganic-organic host-guest nanocrystals organized as oriented monolayers. Inorg Chim Acta, 2007, 360(3): 869–875
Li Z, Johnson M C, Yan Y, et al. Mechanical and dielectric properties of pure-silica-zeolite low-k materials. Angew Chem Int Ed, 2006, 45(38): 6329–6332
Li Z, Li S, Yan Y, et al. Effects of crystallinity in spin-on pure-silica-zeolite MFI low-dielectric-constant films. Adv Funct Mater, 2004, 14(10): 1019–1024
Chen Z, Holmberg B, Yan Y, et al. Nafion/zeolite nanocomposite membrane by in situ crystallization for a direct methanol fuel cell. Chem Mater, 2006, 18(24): 5669–5675
Li S, Martinek J G, Noble R D, et al. High-pressure CO2/CH4 separation using SAPO-34 membranes. Ind Eng Chem Res, 2005, 44(9):3220–3228
Arruebo M, Falconer J L, Noble R D. Separation of binary C5 and C6 hydrocarbon mixtures through MFI zeolite membranes. J Membr Sci, 2006, 269(1–2): 171–176
Choi J, Ghosh S, Tsapatsis M. MFI zeolite membranes from a-and randomly oriented monolayers. Adsorption, 2006, 12(5–6): 339–360
Bowen T C, Noble R D, Falconer J L. Fundamentals and applications of pervaporation through zeolite membranes. J Membr Sci, 2004, 245(1-2): 1–33
McLeary E E, Jansen J C, Kapteijn F. Zeolite based films, membranes and membrane reactors: Progress and prospects. Micropor Mesopor Mater, 2006, 90(1–3): 198–220
Whitesides G M, Grzybowski B. Self-assembly at all scales. Science, 2002, 295: 2418–2421
Glotzer S C, Solomon M J, Kotov N A. Self-assembly: From nanoscale to microscale colloids. AIChE J, 2004, 50(12): 2978–2985
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Supported by the National Natural Science Foundation of China (Grant Nos. 20476074 and 20636030) and the Natural Science Foundation of Tianjin (Grant No. 06YFJMJC04700)
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Zhou, M., Zhang, B. & Liu, X. Oriented growth and assembly of zeolite crystals on substrates. Chin. Sci. Bull. 53, 801–816 (2008). https://doi.org/10.1007/s11434-008-0021-2
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DOI: https://doi.org/10.1007/s11434-008-0021-2