Abstract
A new method of using phenolphthalein loaded with 1-(2-pyridylazo)-2-naphthol (PAN) as solid phase extractant to separate and enrich trace copper in diverse water samples has been developed. The effects of different parameters, such as the amounts of PAN and phenolphthalein, stirring time, various salts and metal ions on the enrichment yield of Cu(II) have been investigated to select the experimental conditions. Under the optimum conditions, Cu(II) can be totally adsorbed on the surface of microcrystalline phenolphthalein. By controlling appropriate acidity (pH=1.0), Cu(II) is completely separated from Cd(II), Pb(II), Mn(II), Co(II), Fe(III), Ni(II), Al(III), Zn(II) and Hg(II) in the solution. The possible reaction mechanism of the enrichment of copper is discussed in detail in this paper. The detection limit of this proposed method is found to be 0.03 μg·L−1 with the enrichment factor of 200. The recovery is in a range of 96.8%–105%. The standard deviation is less than 2.5%. The proposed method has been successfully applied to the determination of trace copper in different water samples with satisfactory results.
Similar content being viewed by others
References
Takara E A, Pasini-Cabello S D, Cerutti S, et al. On-line preconcentration/determination of copper in parenteral solutions using activated carbon by inductively coupled plasma optical emission spectrometry. J Pharmaceut Biomed, 2005, 39(3–4): 735–739
Chen J P, Yoon J-T, Yiacoumi S. Effects of chemical and physical properties of influent on copper sorption onto activated carbon fixed-bed columns. Carbon, 2003, 41(8): 1635–1644
Silva E L, Martins A O, Valentini A, et al. Application of silica gel organofunctionalized with 3(1-imidazolyl)propyl in an on-line preconcentration system for the determination of copper by FAAS. Talanta, 2004, 64(1): 181–189
Čundeva K, Stafilov T, Pavlovska G. Flotation separation of cobalt and copper from fresh waters and their determination by electrothermal atomic absorption spectrometry. Microchem J, 2000, 65(2): 165–175
Diniz M C T, Filho O F, Rohwedder J J R. An automated system for liquid-liquid extraction based on a new micro-batch extraction chamber with on-line detection Preconcentration and determination of copper(II). Anal Chim Acta, 2004, 525(2): 281–287
Soylak M, Saracoglu S, Divrikli U, et al. Coprecipitation of heavy metals with erbium hydroxide for their flame atomic absorption spectrometric determinations in environmental samples. Talanta, 2005, 66(5): 1098–1102
Pesavento M, Profumo A, Alberti G, et al. Adsorption of lead(II) and copper(II) on activated carbon by complexation with surface functional groups. Anal Chim Acta, 2003, 480(1): 171–180
Ferreira S L C, Ferreira J R, Dantas A F, et al. Copper determination in natural water samples by using FAAS after preconcentration onto amberlite XAD-2 loaded with calmagite. Talanta, 2000, 50(6): 1253–1259
Lemos V A, Baliza P X, Yamaki R T, et al. Synthesis and application of a functionalized resin in on-line system for copper preconcentration and determination in foods by flame atomic absorption spectrometry. Talanta, 2003, 61(5): 675–682
Anthemidis A N, Zachariadis G A, Stratis J A. On-line preconcentration and determination of copper, lead and chromium(VI) using unloaded polyurethane foam packed column by flame atomic absorption spectrometry in natural waters and biological samples. Talanta, 2002, 58(5): 831–840
Silva E L, Martins A O, Valentini A, et al. Application of silica gel organofunctionalized with 3(1-imidazolyl)propyl in an on-line preconcentration system for the determination of copper by FAAS. Talanta, 2004, 64(1): 181–189
Taher M A. Determination of trace copper in biological and environmental samples by third derivative spectrophotometry after preconcentration with the ion pair of nitroso-R and tetradecyldimethyl-benzylammonium chloride on microcrystalline naphthalene. Anal Chim Acta, 2000, 408(1–2): 153–161
Oliveros M C C, Blas O J, Pavón J L P, et al. Cloud point preconcentration and flame atomic absorption spectrometry: Application to the determination of nickel and zinc. J Anal At Spectrom, 1998, 13(6): 547–550
Thakur M, Deb M K. The use of 1-[pyridyl-(2)-azo]-naphthol-(2) in the presence of TX-100 and N,N%-diphenylbenzamidine for the spectrophotometric determination of copper in real samples. Talanta, 1999, 49(3): 561–569
Khan M R, Khoo S B. 1-(2-Pyridylazo)-2-naphthol modified carbon paste electrode for trace cobalt(II) determination by differential pulse cathodic voltammetry. Analyst, 1998, 123(6): 1351–1357
Zhu X H, Zhu X S, Wang B S. Cloud point extraction for speciation analysis of inorganic tin in water samples by graphite furnace atomic absorption spectrometry. J Anal At Spectrom, 2006, 21(2): 69–73
Bohrer D, Nascimento P C, Guterres M, et al. Electrothermal atomic absorption spectrometric determination of lead, cadmium, copper and zinc in high-salt content samples after simultaneous separation on polyethylene powder impregnated with 1-(2-pyridylazo)-2-naphthol: Application to the analysis of hemodialysis fluids. Analyst, 1999, 124(9): 1345–1350
Taher M A. Atomic absorption spectrometric determination of trace zinc in alloys and biological samples after preconcentration with [1-(2-pyridylazo)-2-naphthol] on microcrystalline naphthalene. Analyst, 2000, 125(10): 1865–1868
Yebra M C, Carro N, Enríquez M F, et al. Field sample preconcentration of copper in sea water using chelating minicolumns subsequently incorporated on a flow-injection-flame atomic absorption spectrometry system. Analyst, 2001, 126(6): 933–937
Author information
Authors and Affiliations
Corresponding author
Additional information
Supported by the Natural Science Foundation of Henan Province (Grant No. 0511020500) and Innovation Project Foundation of University in Henan Province (Grant No. [2001]513)
About this article
Cite this article
Li, Q., Zhao, X., Jiang, K. et al. Study of spectrophotometric method for determination of trace copper after the separation and enrichment with solid phase extractant-microcrystalline phenolphthalein. CHINESE SCI BULL 52, 65–70 (2007). https://doi.org/10.1007/s11434-007-0018-2
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s11434-007-0018-2