Abstract
The observation of friction anisotropy on graphene by friction measurement at atomic scale has been reported in this paper. Atomic-scale friction measurement revealed friction anisotropy with a periodicity of 60°, which is consistent with the hexagonal periodicity of the graphene. Both experiments and theory show that the value of the friction force is related to the graphene lattice orientation, and the friction force along armchair orientation is also larger than the one along zigzag orientation. These results will play a critical role in the use of graphene to manufacture nanoscale devices.
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Ko J S, Gellman A J. Friction anisotropy at Ni (100)/Ni (100) interfaces. Langmuir, 2000, 16: 8343–8351
Kwaka M, Shindo H. Frictional force microscopic detection of frictional asymmetry and anisotropy at (1014) surface of calcite. Phys Chem Chem Phys, 2004, 6: 129–133
Shindo H, Namai Y. Frictional force microscopic observation of anisotropy at corrugated CaSO4 (001) surface. Phys Chem Chem Phys, 2003, 5: 616–619
Park J Y, Ogletree D F, Salmeron M, et al. High frictional anisotropy of periodic and aperiodic directions on a quasicrystal surface. Science, 2005, 309: 1354–1356
Lucas M, Zhang X H, Palaci I, et al. Hindered rolling and friction an isotropy in supported carbon nanotubes. Nat Mater, 2009, 8: 876–881
Mancinelli C M, Gellman A J. Friction anisotropy at Pd (100)/Pd (100) interfaces. Langmuir, 2004, 20: 1680–1687
Li X L, Wang X R, Zhang L, et al. Chemically derived, ultrasmooth graphene nanoribbon semiconductors. Science, 2008, 319: 1229–1232
Wang X R, Ouyang Y J, Li X L, et al. Room-temperature all-semiconducting sub-10-nm graphene nanoribbon field-effect transistors. Phys Rev Lett, 2008, 100: 206803
Lin Y M, Dimitrakopoulos C, Jenkins K A, et al. 100-GHz transistors from wafer-scale epitaxial graphene. Science, 2010, 327: 662
Grosse K L, Bae M H, Lian F, et al. Nanoscale Joule heating, Peltier cooling and current crowding at graphene-metal contacts. Nat Nanotechnol, 2011, 6: 287–390
Wu Y Q, Lin Y M, Bol A A, et al. High-frequency, scaled graphene transistors on diamond-like carbon. Nature, 2011, 472: 74–78
Schedin F, Geim A K, Morozov S V, et al. Detection of individual gas molecules adsorbed on graphene. Nat Mater, 2007, 6: 652–655
Merchant C A, Healy K, Wanunu M, et al. DNA translocation through graphene nanopores. Nano Lett, 2010, 10: 3163–3167
Garaj S, Hubbard W, Reina A, et al. Graphene as a subnanometre trans-electrode membrane. Nature, 2010, 467: 190–193
Miler J R, Outlaw R A, Holloway B C. Graphene double-layer capacitor with ac line-filtering performance. Science, 2010, 329: 1637–1639
Wang X, Zhi L J, Müllen K. Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett, 2008, 8: 323–327
Han M Y, Oezyilmaz B, Zhang Y, et al. Energy band gap engineering in graphene nanoribbons. Phys Rev Lett, 2007, 98: 206805
Ponomarenko L A, Schedin F, Katsnelson M I, et al. Chaotic dirac billiard in graphene quantum dots. Science, 2008, 320: 356–358
Kobayashi Y, Fukui K, Enoki T, et al. Observation of zigzag and armchair edges of graphite using scanning tunneling microscopy and spectroscopy. Phys Rev B, 2005, 71: 193406
Son Y, Cohen M L, Louie S G. Half-metallic graphene nanoribbons. Nature, 2006, 444: 347–349
Datta S S, Strachan D R, Khamis S M, et al. Crystallographic etching of few-layer graphene. Nano Lett, 2008, 8: 1912–1915
Ci L, Xu Z P, Wang L L, et al. Controlled nanocutting of graphene. Nano Res, 2008, 1: 116–122
Campos L C, Manfrinato V R, Sanchez J D, et al. Anisotropic etching and nanoribbon formation in single-layer graphene. Nano Lett, 2009, 9: 2600–2604
Gao L, Ren W C, Liu B L, et al. Crystallographic tailoring of graphene by nonmetal SiOx nanoparticles. J Am Chem Soc, 2009, 131: 13934–13936
Giesbers A J M, Zeitler U, Neubeck S, et al. Nanolithography and manipulation of graphene using an atomic force microscope. Solid State Commun, 2008, 147: 366–369
Tapaszto L, Dobrik G, Lambin P, et al. Tailoring the atomic structure of graphene nanoribbons by scanning tunneling microscope lithography. Nat Nanotechnol, 2008, 3: 397–401
Weng L, Zhang L Y, Chen Y P, et al. Atomic force microscope local oxidation nanolithography of graphene. Appl Phys Lett, 2008, 3: 093107
Fischbein M D, Drndic M. Electron beam nanosculpting of suspended graphene sheets. Appl Phys Lett, 2008, 93: 113107
Bell D C, Lemme M C, Stern L A, et al. Precision cutting and patterning of graphene with helium ions. Nanotechnology, 2009, 20: 455301
Lemme M C, Bell D C, Williams J R, et al. Etching of graphene devices with a helium ion beam. ACS Nano, 2009, 3: 2674–2676
Lu G, Zhou X Z, Li H, et al. Nanolithography of single-layer graphene oxide films by atomic force microscopy. Langmuir, 2010, 26: 6164–6166
Choi J S, Kim J S, Byun I S, et al. Friction anisotropy-driven domain imaging on exfoliated monolayer graphene. Science, 2011, 333: 607–610
Holscher H, Schwarz U D, Zwomer O, et al. Condequences of the stick-slip movement for the scanning force microscopy imaging of graphite. Phys Rew Lett, 1998, 57: 2477
Novoselov K S, Geim A K, Morozov S V. Electric field effect in atomically thin carbon films. Science, 2004, 306: 666–669
Zhang Y, Liu L, Xi N, et al. Cutting graphene using an atomic force microscope based nanorobot. In: Proceedings of IEEE International Conference on Nanotechnology. Seoul: IEEE, 2010. 639–644
Filleter T, McChesney J L, Bostwick A, et al. Friction and dissipation in epitaxial graphene films. Phys Rew Lett, 2009, 102: 086102
Lee C, Li Q, Kalb W, et al. Frictional characteristics of atomically thin sheets. Science, 2010, 328: 76–80
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Zhang, Y., Liu, L., Xi, N. et al. Friction anisotropy dependence on lattice orientation of graphene. Sci. China Phys. Mech. Astron. 57, 663–667 (2014). https://doi.org/10.1007/s11433-013-5206-2
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DOI: https://doi.org/10.1007/s11433-013-5206-2