Skip to main content
Log in

Luminescence properties of Eu2+ doped BaAl2Si2O8 phosphor for white LEDs

  • Research Paper
  • Published:
Science China Physics, Mechanics and Astronomy Aims and scope Submit manuscript

Abstract

The BaAl2Si2O8:Eu2+ blue emitting phosphor was obtained through the one-step calcination process of precursors prepared by chemical co-precipitation method. The phase structure and luminescence propertied of the phosphor were investigated using X-ray diffraction (XRD) and a fluorescence spectrophotometer. The excitation spectrum exhibited a broad band between 230 nm and 400 nm and the emission peaking at about 470 nm was observed, which originated from the allowed f-d transition of Eu2+ ions at Ba2+ sites. Owing to the different optimal concentrations under different excitation wavelengths (254 nm and 365 nm), the energy-transfer mechanism in this phosphor has changed from the dipole-dipole interaction to the exchange interaction of Eu2+ ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Ishida K, Mitsuishi I, Hattori Y, et al. A revised Kubelka-Munk theory for spectral simulation of phosphor-based white light-emitting diodes. Appl Phsy Lett, 2008, 93: 241910

    Article  ADS  Google Scholar 

  2. Haque M M, Lee H I, Kim D K. Luminescent properties of Eu3+-activated molybdate-based novel red-emitting phosphors for LEDs. J Alloys Compd, 2009, 481: 792–796

    Article  Google Scholar 

  3. Xie R J, Hirosaki N, Liu X J, et al. Crystal structure and photoluminescence of Mn2+-Mg2+ codoped gamma aluminum oxynitride (gamma-AlON): A promising green phosphor for white light-emitting diodes. Appl phys Lett, 2008, 92: 201905

    Article  ADS  Google Scholar 

  4. Allen S C, Steckl A J. A nearly ideal phosphor-converted white light-emitting diode. Appl Phys Lett, 2008, 92: 143309

    Article  ADS  Google Scholar 

  5. Tang Y S, Hu S F, Lin C C, et al. Thermally stable luminescence of KSrPO4:Eu2+ phosphor for white light UV light-emitting diodes. Appl Phys Lett, 2007, 90: 151108

    Article  ADS  Google Scholar 

  6. Neeraj S, Kijima N, Cheetham A K. Novel red phosphors for solid-state lighting: The system NaM(WO4)2−x(MoO4)x:Eu3+ (M=Gd, Y, Bi). Chem Phys Lett, 2004, 387: 2–6

    Article  ADS  Google Scholar 

  7. Justel T, Nikol H. Optimization of luminescent materials for plasma display panels. Adv Mater, 2000, 12: 527–530

    Article  Google Scholar 

  8. Wu Z C, Shi J X, Wang J, et al. A novel blue-emitting phosphor LiS-rPO4:Eu2+ for white LEDs. J Solid State Chem, 2006, 179: 2356–2360

    Article  ADS  Google Scholar 

  9. Zhang Q, Wang J, Zhang M, et al. Enhanced photoluminescence of Ca2Al2SiO7:Eu3+ by charge compensation method. Appl Phys A, 2007, 88: 805–809

    Article  ADS  Google Scholar 

  10. Sohn K S, Cho B, Park H D. Excitation energy-dependent photoluminescence behavior in Zn2SiO4:Mn phosphors. Mater Lett, 1999, 41: 303–308

    Article  Google Scholar 

  11. Im W B, Kim Y I, Jeon D Y. Thermal stability study of BaAl2Si2O8: Eu2+ phosphor using its polymorphism for plasma display panel application. Chem Mater, 2006, 18: 1190–1195

    Article  Google Scholar 

  12. Ma M X, Zhu D C, Tu M J. The effect of Eu2+ doping concentration on luminescence properties of BaAl2Si2O8:Eu2+ blue phosphor (in Chinese). Acta Phys Sin, 2009, 58: 5826–5830

    Google Scholar 

  13. Blasse G. Energy transfer in oxidic phosphors. Philips Res Rep, 1969, 24: 131–144

    Google Scholar 

  14. Dexter D L. A theory of sensitized luminescence in solids. J Chem Phys, 1953, 21: 836–850

    Article  ADS  Google Scholar 

  15. Van Uitert L G. Characterization of energy transfer interactions between rare earth ions. J Electrochem Soc, 1967, 114: 1048–1053

    Article  Google Scholar 

  16. Ozawa L, Jaffe P M. The mechanism of the emission color shift with activator concentration in Eu3+ activated phosphors. J Electrochem Soc, 1971, 118: 1678–1679

    Article  Google Scholar 

  17. Reisfeld R, Greenberg E, Velapodi R, et al. Luminescence quantum efficiency of Gd and Tb in borate glasses and the mechanism of energy transfer between them. J Chem Phys, 1972, 56: 1698–1705

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to DaChuan Zhu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ma, M., Zhu, D., Zhao, C. et al. Luminescence properties of Eu2+ doped BaAl2Si2O8 phosphor for white LEDs. Sci. China Phys. Mech. Astron. 54, 1783 (2011). https://doi.org/10.1007/s11433-011-4465-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11433-011-4465-z

Keywords

Navigation