Abstract
Based on the thermodynamics statistic method, the improved variational perturbation theory and the modified quantum mechanics correction model have been used to calculate the equation of state of liquid helium at pressure from 0.7 to 108 GPa. The calculation results are in good agreement with the experimental data. The EXP-6 potential (α = 13.1) can more accurately describe the interaction of helium atoms than other potentials in the scheme. Finally, a comparison is shown between our interatomic potentials and other potentials.
Similar content being viewed by others
References
Loubeyre P, Hansen J P. Isotopic effect on the high pressure melting curves of helium and hydrogen. Phys Lett, 1980, A80(2): 181–184
Nellis W J, Holmes N C, Mitchell A C, et al. Shock compression of liquid helium to 56 GPa. Phys Rev Lett, 1984, 53(13): 1248–1251
Young D A, Mcmahan A K, Ross M. Equation of state and melting curve of helium to very high pressure. Phys Rev B, 1981, 24(5): 5119–5127
Ross M, Young D A. Helium at high density. Phys Rev Lett A, 1986, 118(9): 463–466
Meng C M, Jiao R Z, Shi S C, et al. Theoretical calculated shock-compression properties for liquid helium (in Chinese). Chin J High Pressure Phys, 2002, 16(1): 70–74
Mao H K, Hemley R J, Wu Y, et al. High-pressure phase diagram and equation of state helium from single-crystal X-ray diffraction to 23.3 GPa. Phys Rev Lett, 1988, 60(13): 2649–2652
Vos W L E, van Hinsberg M G, Schouten J A. High-pressure triple point in helium: The melting line of helium up to 240 kbar. Phys Rev B, 1990, 42(10): 6106–6109
Toullec R L, Loubeyre P, Pinceaux J P. Refractive-index measurements of dense helium up to 16 Gpa at t = 298 K: Analysis of its thermodynamic and electronic properties. Phys Rev B, 1989, 40(4): 2368–2378
Ross M. A high-density fluid-perturbation theory based on an inverse 12th-power hard-sphere reference system. J Chem Phys, 1979, 71(4): 1567–1571
Chirat R, Pittion-Rossillon G. A new equation of state for detonation products. J Chem Phys, 1981, 74: 4634–4645
Fiorese G. A theoretical equation of state for molecular hydrogen. J Chem Phys, 1981, 75(3): 1431
Jing F Q. Introduction to Equation of State of Matter Experimentally (in Chinese). 2nd ed. Beijing: Science Press, 1999
Younger S M, Harrison A K, Sugiyama G. Many-electron effects on transport processes in dens helium. Phys Rev A, 1989, 40(9): 5256–5272
de Kuijper A, Vos W L, Barrat J L, et al. Freezing of simple system using density function theory. J Chem Phys, 1990, 93(7): 5187–5193
Kujiper D E A, Smit B, Schouten J A, et al. Fluid-fluid phase separation in a repulsive-exp-6 mixture: A comparison with the full-exp-6 mixture by means of computer simulations. J Europhys Lett, 1990, 13(8): 679–683
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yang, J., Yan, Y. Equation of state and interaction potential of helium under high temperatures and high densities. Sci. China Ser. G-Phys. Mech. Astron. 52, 161–165 (2009). https://doi.org/10.1007/s11433-009-0019-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11433-009-0019-z