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Simultaneous fabrication of porous metals and metallic nanowires via atmospheric pressure plasma-assisted electro-dealloying

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Abstract

Porous metals and metallic nanowires have gained significant attention for their potential applications in catalysis, sensing, and energy storage. Developing a versatile and efficient method for fabricating these functional materials is crucial but remains challenging. Herein, we report a novel and facile electro-dealloying strategy to simultaneously fabricate porous metals and metallic nanowires using atmospheric radio-frequency (RF) capacitively coupled plasmas. The synergistic effect of the heating and plasma sheath’s electric field lead to the nonequilibrium melting of the alloy, resulting continuous ejection of the melted segments to form nanowires and let the unmelted residual parts evolve into a porous structure. This method is applicable to alloys with large melting point differences of their constituent elements, and provides a promising approach to fabricate porous metals and metallic nanowires for a wide range of functional applications.

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References

  1. Gao Y, Ding Y. Nanoporous metals for heterogeneous catalysis: Following the success of raney nickel. Chem Eur J, 2020, 26: 8845–8856

    Article  Google Scholar 

  2. Li H Y, Lu A K, Wang S S. Facile fabrication of free-standing nanoporous cuag structures for high-performance non-enzymatic glucose sensing by dealloying glassy precursors. J Alloys Compd, 2022, 921: 165995

    Article  Google Scholar 

  3. Ma W, Liu X, Li C, et al. Rechargeable Al-CO2 batteries for reversible utilization of CO2. Adv Mater, 2018, 30: 1801152

    Article  Google Scholar 

  4. An Y, Tian Y, Wei H, et al. Porosity- and graphitization-controlled fabrication of nanoporous silicon@carbon for lithium storage and its conjugation with mxene for lithium-metal anode. Adv Funct Mater, 2019, 30: 1908721

    Article  Google Scholar 

  5. An Y, Tian Y, Wei C, et al. Scalable and physical synthesis of 2D silicon from bulk layered alloy for lithium-ion batteries and lithium metal batteries. ACS Nano, 2019, 13: 13690–13701

    Article  Google Scholar 

  6. Singh S B, Tran D T, Jeong K U, et al. A flexible and transparent zinc-nanofiber network electrode for wearable electrochromic, rechargeable Zn-ion battery. Small, 2022, 18: 2104462

    Article  Google Scholar 

  7. Wu H, Kong D, Ruan Z, et al. A transparent electrode based on a metal nanotrough network. Nat Nanotech, 2013, 8: 421–425

    Article  Google Scholar 

  8. Zhang J, Li C M. Nanoporous metals: Fabrication strategies and advanced electrochemical applications in catalysis, sensing and energy systems. Chem Soc Rev, 2012, 41: 7016–7031

    Article  Google Scholar 

  9. Liu J, Jia D, Gardner J M, et al. Metal nanowire networks: Recent advances and challenges for new generation photovoltaics. Mater Today Energy, 2019, 13: 152–185

    Article  Google Scholar 

  10. Jiang B, Song H, Kang Y, et al. A mesoporous non-precious metal boride system: Synthesis of mesoporous cobalt boride by strictly controlled chemical reduction. Chem Sci, 2020, 11: 791–796

    Article  Google Scholar 

  11. Kang Y, Jiang B, Malgras V, et al. Heterostructuring mesoporous 2D iridium nanosheets with amorphous nickel boron oxide layers to improve electrolytic water splitting. Small Methods, 2021, 5: 2100679

    Article  Google Scholar 

  12. Lim H, Kani K, Henzie J, et al. A universal approach for the synthesis of mesoporous gold, palladium and platinum films for applications in electrocatalysis. Nat Protoc, 2020, 15: 2980–3008

    Article  Google Scholar 

  13. Sang Q, Hao S, Han J, et al. Dealloyed nanoporous materials for electrochemical energy conversion and storage. EnergyChem, 2022, 4: 100069

    Article  Google Scholar 

  14. An Y, Tian Y, Wei C, et al. Dealloying: An effective method for scalable fabrication of 0D, 1D, 2D, 3D materials and its application in energy storage. Nano Today, 2021, 37: 101094

    Article  Google Scholar 

  15. Zhao H, Lei D, He Y B, et al. Compact 3D copper with uniform porous structure derived by electrochemical dealloying as dendrite-free lithium metal anode current collector. Adv Energy Mater, 2018, 8: 1800266

    Article  Google Scholar 

  16. Yun Q, He Y B, Lv W, et al. Chemical dealloying derived 3D porous current collector for Li metal anodes. Adv Mater, 2016, 28: 6932–6939

    Article  Google Scholar 

  17. Guo X, Zhang C, Tian Q, et al. Liquid metals dealloying as a general approach for the selective extraction of metals and the fabrication of nanoporous metals: A review. Mater Today Commun, 2021, 26: 102007

    Article  Google Scholar 

  18. Lai L, Gaskey B, Chuang A, et al. Topological control of liquid-metal-dealloyed structures. Nat Commun, 2022, 13: 2918

    Article  Google Scholar 

  19. Lu Z, Li C, Han J, et al. Three-dimensional bicontinuous nanoporous materials by vapor phase dealloying. Nat Commun, 2018, 9: 276

    Article  Google Scholar 

  20. Lu Z, Zhang F, Wei D, et al. Vapor phase dealloying kinetics of MnZn alloys. Acta Mater, 2021, 212: 116916

    Article  Google Scholar 

  21. Xu W, Song Y, Xu R X, et al. Electrohydrodynamic and hydroelectric effects at the water-solid interface: From fundamentals to applications. Adv Mater Interfaces, 2020, 8: 2000670

    Article  Google Scholar 

  22. Xue J, Wu T, Dai Y, et al. Electrospinning and electrospun nanofibers: Methods, materials, and applications. Chem Rev, 2019, 119: 5298–5415

    Article  Google Scholar 

  23. Gañán-Calvo A M, López-Herrera J M, Herrada M A, et al. Review on the physics of electrospray: From electrokinetics to the operating conditions of single and coaxial taylor cone-jets, and AC electrospray. J Aerosol Sci, 2018, 125: 32–56

    Article  Google Scholar 

  24. Jaworek A. Micro- and nanoparticle production by electrospraying. Powder Tech, 2007, 176: 18–35

    Article  Google Scholar 

  25. Holgate J T, Coppins M. Enhancement of droplet ejection from molten and liquid plasma-facing surfaces by the electric field of the sheath. J Phys D-Appl Phys, 2019, 53: 105204

    Article  Google Scholar 

  26. Holgate J T, Coppins M, Allen J E. Electrohydrodynamic stability of a plasma-liquid interface. Appl Phys Lett, 2018, 112: 024101

    Article  Google Scholar 

  27. Ahlers M. Martensite and equilibrium phases in Cu-Zn and Cu-Zn-Al alloys. Prog Mater Sci, 1986, 30: 135–186

    Article  Google Scholar 

  28. Haq A U, Askari S, McLister A, et al. Size-dependent stability of ultra-small α-/β-phase tin nanocrystals synthesized by microplasma. Nat Commun, 2019, 10: 817

    Article  Google Scholar 

  29. Neyts E C, Ostrikov K K, Sunkara M K, et al. Plasma catalysis: Synergistic effects at the nanoscale. Chem Rev, 2015, 115: 13408–13446

    Article  Google Scholar 

  30. Chiang W H, Mariotti D, Sankaran R M, et al. Microplasmas for advanced materials and devices. Adv Mater, 2020, 32: 1905508

    Article  Google Scholar 

  31. Liu D W, Iza F, Kong M G. Electron heating in radio-frequency capacitively coupled atmospheric-pressure plasmas. Appl Phys Lett, 2008, 93: 261503

    Article  Google Scholar 

  32. Li S, Gu F, Tang B, et al. Numerical analysis of the momentum and heat transfer in an atmospheric pressure dielectric barrier discharge. AIP Adv, 2019, 9: 035219

    Article  Google Scholar 

  33. Lu X, Laroussi M, Puech V. On atmospheric-pressure non-equilibrium plasma jets and plasma bullets. Plasma Sources Sci Technol, 2012, 21: 034005

    Article  Google Scholar 

  34. Vanraes P, Bogaerts A. The essential role of the plasma sheath in plasma-liquid interaction and its applications—A perspective. J Appl Phys, 2021, 129: 220901

    Article  Google Scholar 

  35. Zhang Y T, Shang W L. The recovery of glow-plasma structure in atmospheric radio frequency microplasmas at very small gaps. Phys Plasmas, 2011, 18: 110701

    Article  Google Scholar 

  36. Shi J J, Liu D W, Kong M G. Plasma stability control using dielectric barriers in radio-frequency atmospheric pressure glow discharges. Appl Phys Lett, 2006, 89: 081502

    Article  Google Scholar 

  37. Shi Y, Zhang Y, Qin J, et al. Macro-/micro-coupling regulation of nanoporous metals via vapor phase alloying-dealloying. Sci China Mater, 2021, 64: 1521–1533

    Article  Google Scholar 

  38. Han J, Li C, Lu Z, et al. Vapor phase dealloying: A versatile approach for fabricating 3D porous materials. Acta Mater, 2019, 163: 161–172

    Article  Google Scholar 

  39. Saito G, Hosokai S, Tsubota M, et al. Ripple formation on a nickel electrode during a glow discharge in a solution. Appl Phys Lett, 2012, 100: 181601

    Article  Google Scholar 

  40. Sun J Y, Zhang Q Z, Wang Y N. Observation of nonlinear sheath oscillations in symmetric capacitive discharges at low pressures. Phys Plasmas, 2021, 28: 013509

    Article  Google Scholar 

  41. Gubicza J, Lábár J L, Agócs E, et al. Effect of nano-quasicrystals on viscosity of a Zr-based bulk metallic glass. Scripta Mater, 2008, 58: 291–294

    Article  Google Scholar 

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Correspondence to Yao Yu.

Additional information

This work was supported by the National Natural Science Foundation of China (Grant No. 51872105). The authors are grateful to the Analytical and Testing Center of HUST for technical assistance.

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The supporting information is available online at tech.scichina.com and link.springer.com. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.

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11431_2022_2259_MOESM1_ESM.doc

Simultaneous fabrication of porous metals and metallic nanowires via atmospheric pressure plasma assisted electro-dealloying, approximately 21.4 MB.

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Lu, A., Li, H., Yu, Y. et al. Simultaneous fabrication of porous metals and metallic nanowires via atmospheric pressure plasma-assisted electro-dealloying. Sci. China Technol. Sci. 66, 165–172 (2023). https://doi.org/10.1007/s11431-022-2259-0

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  • DOI: https://doi.org/10.1007/s11431-022-2259-0

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