Skip to main content
Log in

Near-field performance of chemical dissolution-front instability around a circular acid-injection-well in fluid-saturated porous media

  • Article
  • Published:
Science China Technological Sciences Aims and scope Submit manuscript

Abstract

This paper investigates the near-field performance of chemical dissolution-front instability (CDFI) around a circular acid-injection-well in fluid-saturated porous media (FSPM) through using purely mathematical deductions. After the mathematical governing equations of the CDFI problem involving radially divergent flow are briefly described, both analytical base solutions and perturbation solutions for the considered problem are mathematically derived These analytical solutions lead to the theoretical expression of the perturbation induced dimensionless growth-rate and the following two new findings. The first new finding is that the critical Peclet number of a chemical dissolution system (CDS) associated with radially divergent flow in FSPM is not only a function of the permeability ratio between the undissolved and dissolved regions as well as the dimensionless wavenumber, but also a function of the circular chemical dissolution-front location relative to the circular acid-injection-well in FSPM. The second new finding is that as the direct result of considering a nonzero radius of the circular acid-injection-well, there exits a critical closeness number, which may be used to assess where the circular chemical dissolution-front starts becoming unstable in the CDS associated with radially divergent flow. Based on these two new findings, a theoretical criterion of two parts has been established. The first part of the established theoretical criterion answers the scientific question when a circular chemical dissolution-front can become unstable, while the second part of the established theoretical criterion answers the scientific question where a circular chemical dissolution-front can become unstable. Through applying the established theoretical criterion, a long-term existing mystery why the wormhole pattern of fractal nature and the compact pattern of fingering nature are formed at different locations away from the circular acid-injection-well circumference in fluid-saturated carbonate rocks has been successfully revealed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Fredd C N, Fogler H S. Influence of transport and reaction on wormhole formation in porous media. AIChE J, 1998, 44: 1933–1949

    Article  Google Scholar 

  2. Golfier F, Zarcone C, Bazin B, et al. On the ability of a Darcy-scale model to capture wormhole formation during the dissolution of a porous medium. J Fluid Mech, 2002, 457: 213–254

    Article  MATH  Google Scholar 

  3. Panga M K R, Ziauddin M, Balakotaiah V. Two-scale continuum model for simulation of wormholes in carbonate acidization. AIChE J, 2005, 51: 3231–3248

    Article  Google Scholar 

  4. Cohen C E, Ding D, Quintard M, et al. From pore scale to wellbore scale: Impact of geometry on wormhole growth in carbonate acidization. Chem Eng Sci, 2008, 63: 3088–3099

    Article  Google Scholar 

  5. Kalia N, Balakotaiah V. Modeling and analysis of wormhole formation in reactive dissolution of carbonate rocks. Chem Eng Sci, 2007, 62: 919–928

    Article  Google Scholar 

  6. Kalia N, Balakotaiah V. Effect ofmedium heterogeneities on reactive dissolution ofcarbonates. Chem Eng Sci, 2009, 64: 376–390

    Article  Google Scholar 

  7. Zhao C, Hobbs B E, Ord A. Theoretical analyses of acidization dissolution front instability in fluid-saturated carbonate rocks. Int J Numer Anal Meth Geomech, 2013, 37: 2084–2105

    Article  Google Scholar 

  8. Zhao C, Hobbs B E, Ord A. Analytical solution for dissolution-timescale reactive transport in fluid-saturated porous rocks. Int J Geomech, 2018, 18: 1–10

    Article  Google Scholar 

  9. Zhao C, Hobbs B, Ord A. A novel algorithm for implementing perturbations in computational simulations of chemical dissolution-front instability problems within fluid-saturated porous media. Num Anal Meth GeoMech, 2022, 46: 2115–2137

    Article  Google Scholar 

  10. Chadam J, Hoff D, Merino E, et al. Reactive infiltration instabilities. IMA J Appl Math, 1986, 36: 207–221

    Article  MathSciNet  MATH  Google Scholar 

  11. Ortoleva P, Chadam J, Merino E, et al. Geochemical self-organization II; the reactive-infiltration instability. Am J Sci, 1987, 287: 1008–1040

    Article  Google Scholar 

  12. Sherwood J D. Stability of a plane reaction front in a porous medium. Chem Eng Sci, 1987, 42: 1823–1829

    Article  Google Scholar 

  13. Hinch E J, Bhatt B S. Stability of an acid front moving through porous rock. J Fluid Mech, 1990, 212: 279–288

    Article  MATH  Google Scholar 

  14. Zhao C, Hobbs B E, Hornby P, et al. Theoretical and numerical analyses of chemical-dissolution front instability in fluid-saturated porous rocks. Int J Numer Anal Meth Geomech, 2008, 32: 1107–1130

    Article  MATH  Google Scholar 

  15. Ormond A, Ortoleva P. Numerical modeling of reaction-induced cavities in a porous rock. J Geophys Res, 2000, 105: 16737–16747

    Article  Google Scholar 

  16. Chen J S, Liu C W. Numerical simulation of the evolution of aquifer porosity and species concentrations during reactive transport. Comput Geoscis, 2002, 28: 485–499

    Article  Google Scholar 

  17. Chen J S, Liu C W. Interaction of reactive fronts during transport in a homogeneous porous medium with initial small non-uniformity. J Contam Hydrol, 2004, 72: 47–66

    Article  Google Scholar 

  18. Imhoff P T, Mann A S, Mercer M, et al. Scaling DNAPL migration from the laboratory to the field. J Contam Hydrol, 2003, 64: 73–92

    Article  Google Scholar 

  19. Imhoff P T, Miller C T. Dissolution fingering during the solubilization of nonaqueous phase liquids in saturated porous media: 1. Model predictions. Water Resour Res, 1996, 32: 1919–1928

    Article  Google Scholar 

  20. Imhoff P T, Thyrum G P, Miller C T. Dissolution fingering during the solubilization of nonaqueous phase liquids in saturated porous media: 2. Experimental observations. Water Resour Res, 1996, 32: 1929–1942

    Article  Google Scholar 

  21. Maji R, Sudicky E A. Influence of mass transfer characteristics for DNAPL source depletion and contaminant flux in a highly characterized glaciofluvial aquifer. J Contam Hydrol, 2008, 102: 105–119

    Article  Google Scholar 

  22. Soerens T S, Sabatini D A, Harwell J H. Effects of flow bypassing and nonuniform NAPL distribution on the mass transfer characteristics of NAPL dissolution. Water Resour Res, 1998, 34: 1657–1673

    Article  Google Scholar 

  23. Zhang C, Werth C J, Webb A G. Characterization of NAPL source zone architecture and dissolution kinetics in heterogeneous porous media using magnetic resonance imaging. Environ Sci Technol, 2007, 41: 3672–3678

    Article  Google Scholar 

  24. Zhao C B, Hobbs B, Ord A. Transient-state instability analysis of dissolution-timescale reactive infiltration in fluid-saturated porous rocks: Purely mathematical approach. Sci China Tech Sci, 2020, 63: 319–328

    Article  Google Scholar 

  25. Chen J S, Liu C W, Lai G X, et al. Effects of mechanical dispersion on the morphological evolution of a chemical dissolution front in a fluid-saturated porous medium. J Hydrol, 2009, 373: 96–102

    Article  Google Scholar 

  26. Zhao C, Hobbs B E, Ord A. Analytical solutions of nonaqueous-phase-liquid dissolution problems associated with radial flow in fluid-saturated porous media. J Hydrol, 2013, 494: 96–106

    Article  Google Scholar 

  27. Lai K H, Chen J S, Liu C W, et al. Effect of medium permeability anisotropy on the morphological evolution of two non-uniformities in a geochemical dissolution system. J Hydrol, 2016, 533: 224–233

    Article  Google Scholar 

  28. Zhao C, Hobbs B E, Ord A. Mixed solutions of mathematical and numerical methods for reactive mass transport problems of two different porosity regions in fluid-saturated porous media. J Hydrol, 2020, 580: 124145

    Article  Google Scholar 

  29. Zhao C, Hobbs B E, Ord A. Effects of mathematical transforms on theoretical analysis and computational simulation of chemical dissolution-front instability within fluid-saturated porous media. J Hydrol, 2021, 600: 126531

    Article  Google Scholar 

  30. Zhao C B, Hobbs B, Ord A. Two different mathematical schemes for solving chemical dissolution-front instability problems in fluid-saturated rocks. Sci China Tech Sci, 2022, 65: 147–156

    Google Scholar 

  31. Grodzki P, Szymczak P. Reactive-infiltration instability in radial geometry: From dissolution fingers to star patterns. Phys Rev E, 2019, 100: 033108

    Article  MathSciNet  Google Scholar 

  32. Daccord G, Touboul E, Lenormand R. Carbonate acidizing: Toward a quantitative model of the wormholing phenomenon. SPE Product Eng, 1989, 4: 63–68

    Article  Google Scholar 

  33. Daccord G, Lenormand R, Liétard O. Chemical dissolution of a porous medium by a reactive fluid—I. Model for the “wormholing” phenomenon. Chem Eng Sci, 1993, 48: 169–178

    Article  Google Scholar 

  34. Chen C S. Analytical and approximate solutions to radial dispersion from an injection well to a geological unit with simultaneous diffusion into adjacent strata. Water Resour Res, 1985, 21: 1069–1076

    Article  Google Scholar 

  35. Chen C S. Solutions for radionuclide transport from an injection well into a single fracture in a porous formation. Water Resour Res, 1986, 22: 508–518

    Article  Google Scholar 

  36. Chen J S, Chen C S, Chen C Y. Analysis of solute transport in a divergent flow tracer test with scale-dependent dispersion. Hydrol Process, 2007, 21: 2526–2536

    Article  Google Scholar 

  37. Chen C S. Analytical solutions for radial dispersion with Cauchy boundary at injection well. Water Resour Res, 1987, 23: 1217–1224

    Article  Google Scholar 

  38. Schmidt Mumm A, Brugger J, Zhao C, et al. Fluids in geological processes — The present state and future outlook. J GeoChem Explor, 2010, 106: 1–7

    Article  Google Scholar 

  39. Awadh S M, Ali K K, Alazzawi A T. Geochemical exploration using surveys of spring water, hydrocarbon and gas seepage, and geobotany for determining the surface extension of Abu-Jir Fault Zone in Iraq: A new way for determining geometrical shapes of computational simulation models. J GeoChem Explor, 2013, 124: 218–229

    Article  Google Scholar 

  40. Zhao C, Hobbs B E, Ord A. Effects of domain shapes on the morphological evolution of nonaqueous-phase-liquid dissolution fronts in fluid-saturated porous media. J Contam Hydrol, 2012, 138–139: 123–140

    Article  Google Scholar 

  41. Carman P C. Flow of Gases through Porous Media. New York: Academic Press, 1956

    MATH  Google Scholar 

  42. Zhao C, Hobbs B E, Regenauer-Lieb K, et al. Computational simulation for the morphological evolution of nonaqueous phase liquid dissolution fronts in two-dimensional fluid-saturated porous media. Comput Geosci, 2011, 15: 167–183

    Article  MATH  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to ChongBin Zhao.

Additional information

This work was supported by the National Natural Science Foundation of China (Grant Nos. 42030809 and 72088101)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhao, C., Hobbs, B. & Ord, A. Near-field performance of chemical dissolution-front instability around a circular acid-injection-well in fluid-saturated porous media. Sci. China Technol. Sci. 66, 2025–2035 (2023). https://doi.org/10.1007/s11431-022-2185-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11431-022-2185-8

Navigation