Skip to main content
Log in

Two different mathematical schemes for solving chemical dissolution-front instability problems in fluid-saturated rocks

  • Article
  • Published:
Science China Technological Sciences Aims and scope Submit manuscript

Abstract

Chemical dissolution-front instability (CDFI) problems usually involve multiple temporal and spatial scales, as well as multiple processes. A key issue associated with solving a CDFI problem in a fluid-saturated rock is to mathematically establish a theoretical criterion, which can be used to judge the instability of a chemical dissolution-front (CDF) propagating in the fluid-saturated rock. This theoretical paper deals with how two different mathematical schemes can be used to precisely establish such a theoretical criterion in a purely mathematical manner, rather than in a numerical simulation manner. The main distinguishment between these two different mathematical schemes is that in the first mathematical scheme, a curved surface coordinate system is used, while in the second mathematical scheme, a planar surface coordinate system is employed. In particular, all the key mathematical deduction steps associated with using these two different mathematical schemes are described and discussed in great detail. The main theoretical outcomes of this study have demonstrated that (1) two different mathematical schemes under consideration can produce exactly the same theoretical criterion; (2) the main advantage of using the first mathematical scheme is that the interface conditions at the curved interface between the downstream and upstream regions can be easily described mathematically; (3) the main advantage of using the second mathematical scheme is that the first-order perturbation equations of the CDFI problem can be easily described in a purely mathematical manner.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Chadam J, Hoff D, Merino E, et al. Reactive infiltration instabilities. IMA J Appl Math, 1986, 36: 207–221

    Article  MathSciNet  Google Scholar 

  2. Chadam J, Ortoleva P, Sen A. A weekly nonlinear stability analysis of the reactive infiltration interface. IMA J App Math, 1988, 48: 1362–1378

    MATH  Google Scholar 

  3. Ortoleva P, Chadam J, Merino E, et al. Geochemical self-organization II; the reactive-infiltration instability. Am J Sci, 1987, 287: 1008–1040

    Article  Google Scholar 

  4. Sherwood J D. Stability of a plane reaction front in a porous medium. Chem Eng Sci, 1987, 42: 1823–1829

    Article  Google Scholar 

  5. Hinch E J, Bhatt B S. Stability of an acid front moving through porous rock. J Fluid Mech, 1990, 212: 279–288

    Article  Google Scholar 

  6. Zhao C, Hobbs B E, Hornby P, et al. Theoretical and numerical analyses of chemical-dissolution front instability in fluid-saturated porous rocks. Int J Numer Anal Meth Geomech, 2008, 32: 1107–1130

    Article  Google Scholar 

  7. Ormond A, Ortoleva P. Numerical modeling of reaction-induced cavities in a porous rock. J Geophys Res, 2000, 105: 16737–16747

    Article  Google Scholar 

  8. Chen J S, Liu C W. Numerical simulation of the evolution of aquifer porosity and species concentrations during reactive transport. Comput Geosciences, 2002, 28: 485–499

    Article  Google Scholar 

  9. Chen J S, Liu C W. Interaction of reactive fronts during transport in a homogeneous porous medium with initial small non-uniformity. J Contam Hydrol, 2004, 72: 47–66

    Article  Google Scholar 

  10. Zhao C, Hobbs B E, Ord A. Theoretical analyses of acidization dissolution front instability in fluid-saturated carbonate rocks. Int J Numer Anal Meth Geomech, 2013, 37: 2084–2105

    Article  Google Scholar 

  11. Fredd C N, Fogler H S. Influence of transport and reaction on wormhole formation in porous media. AIChE J, 1998, 44: 1933–1949

    Article  Google Scholar 

  12. Golfier F, Zarcone C, Bazin B, et al. On the ability of a Darcy-scale model to capture wormhole formation during the dissolution of a porous medium. J Fluid Mech, 2002, 457: 213–254

    Article  Google Scholar 

  13. Panga M K R, Ziauddin M, Balakotaiah V. Two-scale continuum model for simulation of wormholes in carbonate acidization. AIChE J, 2005, 51: 3231–3248

    Article  Google Scholar 

  14. Cohen C E, Ding D, Quintard M, et al. From pore scale to wellbore scale: Impact of geometry on wormhole growth in carbonate acidization. Chem Eng Sci, 2008, 63: 3088–3099

    Article  Google Scholar 

  15. Kalia N, Balakotaiah V. Modeling and analysis of wormhole formation in reactive dissolution of carbonate rocks. Chem Eng Sci, 2007, 62: 919–928

    Article  Google Scholar 

  16. Kalia N, Balakotaiah V. Effect of medium heterogeneities on reactive dissolution of carbonates. Chem Eng Sci, 2009, 64: 376–390

    Article  Google Scholar 

  17. Imhoff P T, Miller C T. Dissolution fingering during the solubilization of nonaqueous phase liquids in saturated porous media: 1. Model predictions. Water Resour Res, 1996, 32: 1919–1928

    Article  Google Scholar 

  18. Chen J S, Liu C W, Lai G X, et al. Effects of mechanical dispersion on the morphological evolution of a chemical dissolution front in a fluid-saturated porous medium. J Hydrol, 2009, 373: 96–102

    Article  Google Scholar 

  19. Wangen M. Stability of reaction-fronts in porous media. Appl Math Model, 2013, 37: 4860–4873

    Article  MathSciNet  Google Scholar 

  20. Zhao C B, Hobbs B, Ord A. A new alternative approach for investigating acidization dissolution front propagation in fluid-saturated carbonate rocks. Sci China Tech Sci, 2017, 60: 1197–1210

    Article  Google Scholar 

  21. Zhao C B, Hobbs B, Ord A. A unified theory for sharp dissolution front propagation in chemical dissolution of fluid-saturated porous rocks. Sci China Tech Sci, 2019, 62: 163–174

    Article  Google Scholar 

  22. Szymczak P, Ladd A J C. Reactive-infiltration instabilities in rocks. Part 2. Dissolution of a porous matrix. J Fluid Mech, 2014, 738: 591–630

    Article  MathSciNet  Google Scholar 

  23. Lai K H, Chen J S, Liu C W, et al. Effect of medium permeability anisotropy on the morphological evolution of two non-uniformities in a geochemical dissolution system. J Hydrol, 2016, 533: 224–233

    Article  Google Scholar 

  24. Zhao C, Hobbs B, Ord A. Effects of different numerical algorithms on simulation of chemical dissolution-front instability in fluid-saturated porous rocks. J Cent South Univ, 2018, 25: 1966–1975

    Article  Google Scholar 

  25. Zhao C, Hobbs B E, Ord A. Analytical solution for dissolution-timescale reactive transport in fluid-saturated porous rocks. Int J Geomech, 2018, 18: 04018037

    Article  Google Scholar 

  26. Zhao C, Hobbs B E, Ord A. An interface-condition substitution strategy for theoretical study of dissolution-timescale reactive infiltration instability in fluid-saturated porous rocks. Int J Numer Anal Methods Geomech, 2019, 43: 1576–1593

    Article  Google Scholar 

  27. Zhao C B, Hobbs B, Ord A. Transient-state instability analysis of dissolution-timescale reactive infiltration in fluid-saturated porous rocks: Purely mathematical approach. Sci China Tech Sci, 2020, 63: 319–328

    Article  Google Scholar 

  28. Grodzki P, Szymczak P. Reactive-infiltration instability in radial geometry: From dissolution fingers to star patterns. Phys Rev E, 2019, 100: 033108

    Article  MathSciNet  Google Scholar 

  29. Carman P C. Flow of Gases through Porous Media. New York: Academic Press, 1956

    MATH  Google Scholar 

  30. Zhao C, Hobbs B E, Ord A. Chemical dissolution-front instability associated with water-rock reactions in groundwater hydrology: Analyses of porosity-permeability relationship effects. J Hydrol, 2016, 540: 1078–1087

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to ChongBin Zhao.

Additional information

This work was supported by the National Natural Science Foundation of China (Grant Nos. 42030809 and 72088101).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhao, C., Hobbs, B. & Ord, A. Two different mathematical schemes for solving chemical dissolution-front instability problems in fluid-saturated rocks. Sci. China Technol. Sci. 65, 147–156 (2022). https://doi.org/10.1007/s11431-021-1878-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11431-021-1878-9

Keywords

Navigation