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Enhancing the sensitivity of crack-based strain sensor assembled by functionalized graphene for human motion detection

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Abstract

Human motion detection needs sensors with flexibility, high sensitivity and linearity. However, conventional strain sensors are rigid and not suitable for human motion detection applications. Graphene-based strain sensors can overcome the above challenges but currently are still in the infancy of their development. In this work, properties of graphene-based crack-type strain sensors are investigated and guidelines to improve the sensitivity of graphene films as sensing elements are developed. First, it is found that the pre-strains influences the crack morphology and density, which further results in different sensor sensitivities and linearity. Second, the graphene film thickness influences the crack density due to the sliding between graphene layers; namely, a thinner graphene film with more cracks exhibits higher sensitivity. Third, the substrate influences the bonding strength with the graphene film, leading to different crack formations, which results in adjusted sensitivity. The cracks on PDMS are channel cracks while those on epoxy are isolated short cracks. The channel cracks are preferred to cause high sensitivity while the isolated short cracks hardly have a blocking effect on the current transport. Finally, the optimized graphene strain sensors are used to detect various human motions and exhibit high sensitivity.

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References

  1. Ray T R, Choi J, Bandodkar A J, et al. Bio-integrated wearable systems: A comprehensive review. Chem Rev, 2019, 119: 5461–5533

    Article  Google Scholar 

  2. Jung Y H, Park B, Kim J U, et al. Bioinspired electronics for artificial sensory systems. Adv Mater, 2019, 31: 1803637

    Article  Google Scholar 

  3. Bai N, Wang L, Wang Q, et al. Graded intrafillable architecture-based iontronic pressure sensor with ultra-broad-range high sensitivity. Nat Commun, 2020, 11: 209

    Article  Google Scholar 

  4. Hempel M, Nezich D, Kong J, et al. A novel class of strain gauges based on layered percolative films of 2D materials. Nano Lett, 2012, 12: 5714–5718

    Article  Google Scholar 

  5. Chen Z, Ming T, Goulamaly M M, et al. Enhancing the sensitivity of percolative graphene films for flexible and transparent pressure sensor arrays. Adv Funct Mater, 2016, 26: 5061–5067

    Article  Google Scholar 

  6. Long Y, He P, Xu R, et al. Molybdenum-carbide-graphene composites for paper-based strain and acoustic pressure sensors. Carbon, 2020, 157: 594–601

    Article  Google Scholar 

  7. Yang T T, Wang W, Zhang H Z, et al. Tactile sensing system based on arrays of graphene woven microfabrics: Electromechanical behavior and electronic skin application. ACS Nano, 2015, 9: 10867–10875

    Article  Google Scholar 

  8. Yang T, Xie D, Li Z, et al. Recent advances in wearable tactile sensors: Materials, sensing mechanisms, and device performance. Mater Sci Eng-R-Rep, 2017, 115: 1–37

    Article  Google Scholar 

  9. Li B, Luo J, Huang X, et al. A highly stretchable, super-hydrophobic strain sensor based on polydopamine and graphene reinforced nanofiber composite for human motion monitoring. Compos Part B-Eng, 2020, 181: 107580

    Article  Google Scholar 

  10. Sengupta D, Pei Y, Kottapalli A G P. Ultralightweight and 3D squeezable graphene-polydimethylsiloxane composite foams as piezoresistive sensors. ACS Appl Mater Interfaces, 2019, 11: 35201–35211

    Article  Google Scholar 

  11. Jia Y, Chen W, Ye C, et al. Controllable formation of periodic wrinkles in marangoni-driven self-assembled graphene film for sensitive strain detection. Sci China Mater, 2020, 63: 1983–1992

    Article  Google Scholar 

  12. Leem J, Lee Y, Wang M C, et al. Crack-assisted, localized deformation of van der waals materials for enhanced strain confinement. 2D Mater, 2019, 6: 044001

    Article  Google Scholar 

  13. Xue P, Chen C, Diao D. Ultra-sensitive flexible strain sensor based on graphene nanocrystallite carbon film with wrinkle structures. Carbon, 2019, 147: 227–235

    Article  Google Scholar 

  14. Kang D, Pikhitsa P V, Choi Y W, et al. Ultrasensitive mechanical crack-based sensor inspired by the spider sensory system. Nature, 2014, 516: 222–226

    Article  Google Scholar 

  15. Yang T, Li X, Jiang X, et al. Structural engineering of gold thin films with channel cracks for ultrasensitive strain sensing. Mater Horiz, 2016, 3: 248–255

    Article  Google Scholar 

  16. Han Z, Liu L, Zhang J, et al. High-performance flexible strain sensor with bio-inspired crack arrays. Nanoscale, 2018, 10: 15178–15186

    Article  Google Scholar 

  17. Liu G S, Yang F, Xu J, et al. Ultrasonically patterning silver nanowire-acrylate composite for highly sensitive and transparent strain sensors based on parallel cracks. ACS Appl Mater Interfaces, 2020, 12: 47729–47738

    Article  Google Scholar 

  18. Chen S, Wei Y, Wei S, et al. Ultrasensitive cracking-assisted strain sensors based on silver nanowires/graphene hybrid particles. ACS Appl Mater Interfaces, 2016, 8: 25563–25570

    Article  Google Scholar 

  19. Liao X, Zhang Z, Liao Q, et al. Flexible and printable paper-based strain sensors for wearable and large-area green electronics. Nanoscale, 2016, 8: 13025–13032

    Article  Google Scholar 

  20. Song H, Zhang J, Chen D, et al. Superfast and high-sensitivity printable strain sensors with bioinspired micron-scale cracks. Nanoscale, 2017, 9: 1166–1173

    Article  Google Scholar 

  21. Mao L, Gong T, Ai Q, et al. Morphologically modulated laser-patterned reduced graphene oxide strain sensors for human fatigue recognition. Smart Mater Struct, 2020, 29: 015009

    Article  Google Scholar 

  22. Xiao Y, Jiang S, Li Y, et al. Highly sensitive printed crack-enhanced strain sensor as dual-directional bending detector. Smart Mater Struct, 2020, 29: 045023

    Article  Google Scholar 

  23. Chun S, Choi Y, Park W. All-graphene strain sensor on soft substrate. Carbon, 2017, 116: 753–759

    Article  Google Scholar 

  24. Gong S, Yap L W, Zhu Y, et al. A soft resistive acoustic sensor based on suspended standing nanowire membranes with point crack design. Adv Funct Mater, 2020, 30: 1910717

    Article  Google Scholar 

  25. Dinh Le T S, An J, Huang Y, et al. Ultrasensitive anti-interference voice recognition by bio-inspired skin-attachable self-cleaning acoustic sensors. ACS Nano, 2019, 13: 13293–13303

    Article  Google Scholar 

  26. Yang T, Wang W, Huang Y, et al. Accurate monitoring of small strain for timbre recognition via ductile fragmentation of functionalized graphene multilayers. ACS Appl Mater Interfaces, 2020, 12: 57352–57361

    Article  Google Scholar 

  27. Hummers Jr. W S, Offeman R E. Preparation of graphitic oxide. J Am Chem Soc, 1958, 80: 1339

    Article  Google Scholar 

  28. Marcano D C, Kosynkin D V, Berlin J M, et al. Improved synthesis of graphene oxide. ACS Nano, 2010, 4: 4806–4814

    Article  Google Scholar 

  29. Huang Y, Li J, Xiang Y, et al. Asymmetrical layered assemblies of graphene oxide for programmable actuation devices. Smart Mater Struct, 2020, 29: 115048

    Article  Google Scholar 

  30. Huang Y, Yao Q, Qi Y, et al. Wear evolution of monolayer graphene at the macroscale. Carbon, 2017, 115: 600–607

    Article  Google Scholar 

  31. Park B, Kim J, Kang D, et al. Dramatically enhanced mechanosensitivity and signal-to-noise ratio of nanoscale crack-based sensors: Effect of crack depth. Adv Mater, 2016, 28: 8130–8137

    Article  Google Scholar 

  32. Park B, Lee S, Choi H, et al. A semi-permanent and durable nanoscale-crack-based sensor by on-demand healing. Nanoscale, 2018, 10: 4354–4360

    Article  Google Scholar 

  33. Kwon Y, Park C, Kim J, et al. Effects of bending strain and crack direction on crack-based strain sensors. Smart Mater Struct, 2020, 29: 115007

    Article  Google Scholar 

  34. Won S, Hwangbo Y, Lee S K, et al. Double-layer cvd graphene as stretchable transparent electrodes. Nanoscale, 2014, 6: 6057–6064

    Article  Google Scholar 

  35. Xiang Y, Li T, Suo Z, et al. High ductility of a metal film adherent on a polymer substrate. Appl Phys Lett, 2005, 87: 161910

    Article  Google Scholar 

  36. Graz I M, Cotton D P J, Lacour S P. Extended cyclic uniaxial loading of stretchable gold thin-films on elastomeric substrates. Appl Phys Lett, 2009, 94: 071902

    Article  Google Scholar 

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Correspondence to YueHua Huang or TingTing Yang.

Additional information

This work was supported by the National Natural Science Foundation of China (Grant No. 51802293), the Tribology Science Fund of State Key Laboratory of Tribology of China (Grant No. SKLTKF20B02), and the Innovation Funds for Chongqing’s Overseas Returnees (Grant No. cx2019081).

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Huang, Y., Xiang, Y., Ren, W. et al. Enhancing the sensitivity of crack-based strain sensor assembled by functionalized graphene for human motion detection. Sci. China Technol. Sci. 64, 1805–1813 (2021). https://doi.org/10.1007/s11431-021-1856-6

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  • DOI: https://doi.org/10.1007/s11431-021-1856-6

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