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Effect of grain size on α-variant selection in a ZrTiAlV alloy

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Abstract

Local crystallographic orientation characteristics of grains with different sizes in a ZrTiAlV alloy after interrupted cooling from β phase region are investigated by electron backscatter diffraction (EBSD) technique. A statistical analysis of EBSD data shows that bigger parent β grains present weaker variant selection than smaller grains. The relevant influences are studied by comparing the nucleation behavior of grain boundary α (GBα) and succedent growth stage in varisized grains. In-depth analysis indicates that the deviation between pole of GBα and common pole of adjacent parent β grains is responsible for the smaller degree of variant selection inside the bigger parent β grains. The formation of more than one GBα type at the β/β grain boundary with common pole in bigger grains results in obstructing each other for these variants during the following growth stage, while only one type of GBα nucleate at the β/β grain boundary with common pole in smaller grains and it can freely grow into the interior of the grains, leading to stronger variant selection in smaller β grains.

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References

  1. Chai L J, Wu H, Wang S Y, et al. Microstructural characteristics of cold-rolled Zr-2.5Nb alloy annealed near the monotectoid temperature. Sci China Tech Sci, 2018, 61: 558–566

    Article  Google Scholar 

  2. Liu W, Li Q, Zhou B, et al. Effect of heat treatment on the microstructure and corrosion resistance of a Zr-Sn-Nb-Fe-Cr alloy. J Nucl Mater, 2005, 341: 97–102

    Article  Google Scholar 

  3. Qu L, Yang Z N, Zhang F C, et al. Effect of deformation and heat treatment on the microstructure and mechanical properties of β-Zr40Ti5Al4V alloy. J Alloys Compd, 2014, 612: 80–89

    Article  Google Scholar 

  4. Shi Y, Li M, Guo D, et al. A hierarchical and multiphase nanolaminated alloy with an excellent combination of tensile properties. Mater Sci Eng-A, 2014, 615: 464–468

    Article  Google Scholar 

  5. Shi Y D, Wang L N, Liang S X, et al. A high Zr-containing Ti-based alloy with ultralow Young’s modulus and ultrahigh strength and elastic admissible strain. Mater Sci Eng-A, 2016, 674: 696–700

    Article  Google Scholar 

  6. Chai L J, Xia J Y, Zhi Y, et al. Deformation mode-determined misorientation and microstructural characteristics in rolled pure Zr sheet. Sci China Tech Sci, 2018, 61: 1346–1352

    Article  Google Scholar 

  7. Wenk H R, Lonardelli I, Williams D. Texture changes in the hcp→bcc→hcp transformation of zirconium studied in situ by neutron diffraction. Acta Mater, 2004, 52: 1899–1907

    Article  Google Scholar 

  8. Gey N, Humbert M, Gautier E, et al. Study of the β→a variant selection for a zircaloy-4 rod heated to the β transus in presence or not of an axial tensile stress. J Nucl Mater, 2004, 328: 137–145

    Article  Google Scholar 

  9. Romero J, Preuss M, Quinta da Fonseca J. Capturing the texture changes in a zirconium alloy during the allotropic phase transformation. Scripta Mater, 2009, 61: 399–402

    Article  Google Scholar 

  10. Daymond M R, Holt R A, Cai S, et al. Texture inheritance and variant selection through an hcp-bcc-hcp phase transformation. Acta Mater, 2010, 58: 4053–4066

    Article  Google Scholar 

  11. Sattari M, Holt R A, Daymond M R. Variant selection and transformation texture in zirconium alloy Excel. J Nucl Mater, 2014, 453: 120–123

    Article  Google Scholar 

  12. Karthikeyan T, Dasgupta A, Khatirkar R, et al. Effect of cooling rate on transformation texture and variant selection during β→a transformation in Ti-5Ta-1.8Nb alloy. Mater Sci Eng-A, 2010, 528: 549–558

    Article  Google Scholar 

  13. Shi R, Dixit V, Fraser H L, et al. Variant selection of grain boundary α by special prior β grain boundaries in titanium alloys. Acta Mater, 2014, 75: 156–166

    Article  Google Scholar 

  14. Obasi G C, Birosca S, Quinta da Fonseca J, et al. Effect of β grain growth on variant selection and texture memory effect during a→β→a phase transformation in Ti-6Al-4V. Acta Mater, 2012, 60: 1048–1058

    Article  Google Scholar 

  15. Jafarian H, Borhani E, Shibata A, et al. Variant selection of martensite transformation from ultrafine-grained austenite in Fe-Ni-C alloy. J Alloys Compd, 2013, 577: S668–S672

    Article  Google Scholar 

  16. Chai L, Xia J, Zhi Y, et al. Strengthening or weakening texture intensity of Zr alloy by modifying cooling rates from α+β region. Mater Chem Phys, 2018, 213: 414–421

    Article  Google Scholar 

  17. Zhao Z B, Wang Q J, Hu Q M, et al. Effect of β(110) texture intensity on a-variant selection and microstructure morphology during β→a phase transformation in near a titanium alloy. Acta Mater, 2017, 126: 372–382

    Article  Google Scholar 

  18. Jiang X, Wynne B P, Martin J. Variant selection in stationary shoulder friction stir welded Ti-6Al-4V alloy. J Mater Sci Tech, 2018, 34: 198–208

    Article  Google Scholar 

  19. Obasi G C, da Fonseca J Q, Rugg D, et al. The effect of β grain coarsening on variant selection and texture evolution in a near-β Ti alloy. Mater Sci Eng-A, 2013, 576: 272–279

    Article  Google Scholar 

  20. Qiu R S, Luan B F, Chai L J, et al. Precise determination of the a→a+β phase transformation temperature of Zr-1.0Sn-0.3Nb-0.3Fe alloy. Sci China Tech Sci, 2013, 56: 60–65

    Article  Google Scholar 

  21. Duan J, Tan Y, Ji L, et al. Hot deformation behavior of 51.1Zr-40.2Ti-4.5Al-4.2V alloy in the single β phase field. Prog Nat Sci-Mater Int, 2015, 25: 34–41

    Article  Google Scholar 

  22. Guo D, Li M, Shi Y, et al. Optimization of tensile properties of a hierarchical structured TiZrAlV alloy by proton irradiation. Mater Lett, 2015, 161: 743–746

    Article  Google Scholar 

  23. Guo D, Li J, Zhang G, et al. Microstructure evolution and mechanical properties of deformed TiZrAlV upon annealing. J Alloys Compd, 2015, 651: 779–784

    Article  Google Scholar 

  24. Shi Y, Wang L, Li M, et al. Enhancing mechanical properties of TiZrAlV by engineering a multi-modal-laminated structure. Adv Eng Mater, 2016, 18: 60–64

    Article  Google Scholar 

  25. Ran J. Microstructure and phase evolution of the metastable β-type 51Zr-40Ti-4.5Al-4.5V alloy. Vacuum, 2017, 137: 60–65

    Article  Google Scholar 

  26. Chai L, Luan B, Zhang M, et al. Experimental observation of 12 α variants inherited from one β grain in a Zr alloy. J Nucl Mater, 2013, 440: 377–381

    Article  Google Scholar 

  27. Qiu D, Shi R, Zhang D, et al. Variant selection by dislocations during a precipitation in α/β titanium alloys. Acta Mater, 2015, 88: 218–231

    Article  Google Scholar 

  28. Sankaran A, Bouzy E, Humbert M, et al. Variant selection during nucleation and growth of γ-massive phase in TiAl-based intermetallic alloys. Acta Mater, 2009, 57: 1230–1242

    Article  Google Scholar 

  29. Wittig J E. The massive transformation in titanium aluminides: Initial stages of nucleation and growth. Metall Mat Trans A, 2002, 33: 2373–2379

    Article  Google Scholar 

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Li, F., Qiu, X., Liao, Z. et al. Effect of grain size on α-variant selection in a ZrTiAlV alloy. Sci. China Technol. Sci. 62, 982–988 (2019). https://doi.org/10.1007/s11431-018-9479-y

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  • DOI: https://doi.org/10.1007/s11431-018-9479-y

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