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Standardization of tritiated water by the CIEMAT/NIST and TDCR methods

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Abstract

The activity of tritiated water has been standardized by two liquid scintillation counting methods: The CIEMAT/NIST method with the 54Mn-standard efficiency tracing and the triple-to-double coincidence ratio (TDCR) method. The samples were prepared with Ultima Gold™ AB liquid scintillation cocktail in low-potassium glass vials. In the application of the CIEMAT/NIST method, the computer program EMILIA was used to calculate the efficiency of 3H and 54Mn according to the KL1L2L3M atomic rearrangement model. And the detection efficiency of the TDCR counter was calculated using TDCR07 code, which makes it possible to allow for the potential asymmetry between the three photomultiplier tubes. The influence of stopping power and kB factor is discussed in the paper. When a power approach is adopted for the stopping power for electrons below 1 keV and kB is chosen to be 0.0075 cm/MeV, the relative deviation will be only 0.3% between the two methods.

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References

  1. Malonda G. Counting efficiency for electron capture radionuclides. Int J Appl Radiat Isot, 1982, 33: 249–253

    Article  Google Scholar 

  2. Malonda G, Torano G. Evaluation of counting efficiency in liquid scintillation counting of pure β-ray emitters. Int J Appl Radiat Isot, 1982, 33: 249–53

    Article  Google Scholar 

  3. Broda R, Pochwalski K, Radoszewski T. Calculation of liquid-scintillation detector efficiency. Appl Radiat Isot, 1988, 39: 159–164

    Article  Google Scholar 

  4. Pochwalski K, Broda R, Radozewski T. Standardization of pure betaemitters by liquid scintillation counting. Int J Appl Radiat Isot, 1988, 39: 165–172

    Article  Google Scholar 

  5. Broda R, Pochwalski K. The enhanced triple to double coincidence ratio (ETDCR) method for standardization of radionuclides by liquid scintillation counting. Nucl Instrum Methods A, 1992, 312: 85–89

    Article  Google Scholar 

  6. Carles G, Malonda G. Free parameter, figure of merit and ionization quench in liquid scintillation counting. Appl Radiat Isot, 2001, 54: 447–454

    Article  Google Scholar 

  7. Broda R, Cassette P, Kossert K. Radionuclide metrology using liquid scintillation counting. Metrologia, 2007, 44: 36–52

    Article  Google Scholar 

  8. Carles G. EMILIA, the LS counting efficiency for electron-capture and capture-gamma emitters. Comput Phys Comm, 2006, 174: 35–46

    Article  Google Scholar 

  9. Annunziata M F. Handbook of Radioactivity Analysis. 2nd ed. San Diego: Academic Press, 2002. 445–469

    Google Scholar 

  10. Kossert K, Carles G. The LSC efficiency for low-Z electron-capture nuclides. Appl Radiat Isot, 2006, 64: 1446–1453

    Article  Google Scholar 

  11. Nähle O, Kossert K, Cassette P. Activity standardization of 3H with the new TDCR system at PTB. Appl Radiat Isot, 2010, 68: 1043–1048

    Article  Google Scholar 

  12. The International Bureau of Weights and Measures (BIPM). Measurement of activity concentration of the same solution of tritiated water. http://kcdb.bipm.org/appendixB/KCDB_ApB_info.asp?cmp_idy=887&cmp_cod=CCRI(II)-K2.H-3&prov=exalead

  13. Ratel G. Analysis of the results of the international comparison of activity measurements of a solution of 55Fe. Appl Radiat Isot, 2008, 66: 729–732

    Article  Google Scholar 

  14. Barquero R, Arcos L. Compensation by the CIEMAT/NIST method of long-term effects in LSC measurements of beta emitters. Appl Radiat Isot, 2004, 61: 1403–1411

    Article  Google Scholar 

  15. Günther E. What can we expect from the CIEMAT/NIST method? Appl Radiat Isot, 2002, 56: 357–360

    Article  Google Scholar 

  16. Broda R. A review of the triple-to-double coincidence ratio (TDCR) method for standardizing radionuclides. Appl Radiat Isot, 2003, 58: 585–594

    Article  Google Scholar 

  17. Malonda G, Carles G. Standardization of electron-capture radionuclides by liquid scintillation counting. Appl Radiat Isot, 2002, 52: 657–662

    Article  Google Scholar 

  18. Birks J B. The Theory and Practice of Scintillation Counting. Oxford: Pergamon Press, 1964

    Google Scholar 

  19. Wu Y L, Liang J C, Liu H R, et al. Construction and implementation of a liquid scintillation TDCR system (in Chinese). Acta Metrol Sin, 2014, 35: 83–86

    Google Scholar 

  20. Cassette P, Broda R, Hainosa D, et al. Analysis of detection-efficiency variation techniques for the implementation of the TDCR method in liquid scintillation counting. Appl Radiat Isot, 2000, 52, 643–648

    Article  Google Scholar 

  21. Günther E. Standardization of the EC nuclides55Fe and 65Zn with the CIEMAT/NIST LSC tracer method. Appl Radiat Isot, 1998, 49: 1055–1060

    Article  Google Scholar 

  22. José M, Arcos L, Ortiz F. KB: A code to determine the ionization quenching function Q(E) as a function of the kB parameter. Comput Phys Commun, 1997, 103: 83–94

    Article  Google Scholar 

  23. International Commission on Radiation Units and Measurements (ICRU). Stopping power for electrons and positrons. ICRU Report 37, 1984. 4–5

    Google Scholar 

  24. Tan Z, Xia Y. Stopping power and mean free path for low-energy electrons in ten scintillators over energy range of 20–20000 eV. Appl Radiat Isot, 2012, 70: 296–300

    Article  Google Scholar 

  25. Kossert K, Cassette P, Carles G, et al. Extension of the TDCR model to computer counting efficiencies for radionuclides with complex decay schemes. Appl Radiat Isot, 2014, 87: 242–248

    Article  Google Scholar 

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Authors and Affiliations

  1. China Institute of Atomic Energy, Beijing, 102413, China

    YongLe Wu, HaoRan Liu, JunCheng Liang, WenJun Xiong, SenLin Liu & DaQing Yuan

  2. Nuclear and Radiation Safety Center, Beijing, 100082, China

    YongLe Wu, JiaCheng Liu & HuiGuo Yue

  3. National Institute of Metrology, Beijing, 100013, China

    HaoRan Liu, JunCheng Liang, JiaCheng Liu & YuanDi Yang

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  1. YongLe Wu
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  2. HaoRan Liu
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  3. JunCheng Liang
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  4. JiaCheng Liu
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  5. WenJun Xiong
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  6. HuiGuo Yue
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  7. SenLin Liu
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  8. YuanDi Yang
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  9. DaQing Yuan
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Correspondence to DaQing Yuan.

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Wu, Y., Liu, H., Liang, J. et al. Standardization of tritiated water by the CIEMAT/NIST and TDCR methods. Sci. China Technol. Sci. 58, 559–564 (2015). https://doi.org/10.1007/s11431-014-5739-2

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  • DOI: https://doi.org/10.1007/s11431-014-5739-2

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