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Hybrid UV photodetector with high photo-to-dark current ratio based on ordered TiO2 nanorod arrays and polystyrene sulfate

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Abstract

Vertically aligned TiO2 nanorods arrays were successfully synthesized on FTO glass by wet-chemical method. Based on polystyrene sulfate (PSS) functionalized TiO2 nanorods arrays, a sandwich-structured hybrid UV photodetector was fabricated. The photo-to-dark current ratio of the device increases by more than 3 orders of magnitude with typical case, while the dark current is about 10 nA at 1 V bias. The high photoresponse together with the low dark current could probably contribute a large photocurrent and low-power application. The high performance of the hybrid material and facile low-cost fabrication of the UV detector make the devices promising for large-area UV photodetection applications.

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References

  1. Lin C, Song Y, Cao L X, et al. Effective photocatalysis of functional nanocomposites based on carbon and TiO2 nanoparticles. Nanoscale, 2013, 5: 4986–4992

    Article  Google Scholar 

  2. O’Regan B, Gratzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353: 737–740

    Article  Google Scholar 

  3. Docampo P, Guldin S, Stefik M, et al. Control of solid-state dye-sensitized solar cell performance by block-copolymer-directed TiO2 synthesis. Adv Funct Mater, 2010, 20: 1787–1796

    Article  Google Scholar 

  4. Li Y H, Gong J, He G H, et al. Fabrication of polyaniline/titanium dioxide composite nanofibers for gas sensing application. Mater Chem Phys, 2011, 129: 477–482

    Article  Google Scholar 

  5. Zhang H F, Ruan S P, Li H L, et al. Schottky diode ultraviolet detector based on TiO2 nanowire array. IEEE Electron Dev Lett, 2012, 33: 83–85

    Article  Google Scholar 

  6. Han Y G, Wu G, Wang M, et al. Hybrid ultraviolet photodetectors with high photosensitivity based on TiO2 nanorods array and polyfluorene. Appl Surf Sci, 2009, 256: 1530–1533

    Article  Google Scholar 

  7. Han Y G, Wu G, Wang M, et al. High efficient UV-A photodetectors based on monodispersed ligand-capped TiO2 nanocrystals and polyfluorene hybrids. Polymer, 2010, 51: 3736–3743

    Article  Google Scholar 

  8. Han Y G, Fan C C, Wu G, et al. Low-temperature solution processed utraviolet photodetector based on an ordered TiO2 nanorod array-polymer hybrid. J Phys Chem C, 2011, 115: 13438–13445

    Article  Google Scholar 

  9. Xue H L, Kong X Z, Liu Z R. TiO2 based metal-semiconductor-metal ultraviolet photodetectors. Appl Phys Lett, 2007, 90: 201118

    Article  Google Scholar 

  10. Kong X Z, Liu C X, Dong W, et al. Metal-semiconductor-metal TiO2 ultraviolet detectors with Ni electrodes. Appl Phys Lett, 2009, 94: 123502

    Article  Google Scholar 

  11. Sakai N, Prasad G K, Ebina Y, et al. Layer-by-layer assembled TiO2 nanoparticle /PEDOT-PSS composite films for switching of electric conductivity in response to ultraviolet and visible Light. Chem Mater, 2006, 18: 3596–3598

    Article  Google Scholar 

  12. La C S, Park M C, Kuang Q, et al. Giant enhancement in UV response of ZnO nanobelts by polymer surface-functionalization. J Am Chem Soc, 2007, 129: 12096–12097

    Article  Google Scholar 

  13. Yu C, Park J. Thermal annealing synthesis of titanium-dioxide nanowirenanoparticle heterostructures. J Solid State Chem, 2010, 83: 2268–2273

    Article  Google Scholar 

  14. Cheng G, Li Z H, Wang S J, et al. The unsaturated photocurrent controlled by two-dimensional barrier geometry of a single ZnO nanowire Schottky photodiode. Appl Phys Lett, 2008, 93: 123103

    Article  Google Scholar 

  15. Kuo C Y, Tang W C, Gau C, et al. Ordered bulk heterojunction solar cells with vertically aligned TiO2 nanorods embedded in a conjugated polymer. Appl Phys Lett, 2008, 93: 033307

    Article  Google Scholar 

  16. Liu B, Aydil E S. Growth of oriented single-crystalline rutile TiO2 nanorods on transparent conducting substrates for dye-sensitized solar cells. J Am Chem Soc, 2009, 131: 3985–3990

    Article  Google Scholar 

  17. He X S, Hu C G, Feng B, et al. Vertically aligned TiO2 nanorod arrays as a steady light sensor. J Electrochem Soc, 2010, 157: J381–J385

    Article  Google Scholar 

  18. Tsai T Y, Chang S J, Weng W Y, et al. A visible-blind TiO2 nanowire photodetector. J Electrochem Soc, 2012, 159: J132–J135

    Article  Google Scholar 

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Correspondence to GaoHong He.

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Zheng, W., He, G., Li, X. et al. Hybrid UV photodetector with high photo-to-dark current ratio based on ordered TiO2 nanorod arrays and polystyrene sulfate. Sci. China Technol. Sci. 56, 2642–2645 (2013). https://doi.org/10.1007/s11431-013-5354-7

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  • DOI: https://doi.org/10.1007/s11431-013-5354-7

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