Abstract
A high performance heterojunction organic ultraviolet photodetector based on NPB and Bphen has been fabricated. A transparent conducting polymer PEDOT:PSS coated quartz substrate instead of ITO coated glass substrate as anode is propitious to detect shorter wavelength ultraviolet light. As a result, the device shows a low dark current density, a high responsivity of 502 mA/W and a detectivity of 2.67×1012 cm Hz1/2/W which is illuminated by a 220 nm ultraviolet light with an intensity of 1.6 mW/cm2. Moreover, the performance of the PEDOT:PSS transparent electrode device is better than the semi-transparent Al electrode device electrode because of the higher transmittance and electrode properties.
Similar content being viewed by others
References
Razeghi M, Rogalski A. Semiconductor ultraviolet detectors. J Appl Phys, 1996, 79: 7433–7473
Liao M, Koide Y, Alvarez J. Photovoltaic Schottky ultraviolet detectors fabricated on boron-doped homoepitaxial diamond layer. Appl Phys Lett, 2006, 88: 033504
Dahal R, Tahtamouni T M, Fan Z, et al. Hybrid AlN-SiC deep ultraviolet Schottky barrier photodetectors. Appl Phys Lett, 2007, 90: 263505
Mazzeo G, Conte G, Reverchon J L, et al. Deep ultraviolet detection dynamics of AlGaN based devices. Appl Phys Lett, 2006, 89: 223513
Li J, Fan Z, Dahal R, et al. 200 nm deep ultraviolet photodetectors based on AlN. Appl Phys Lett, 2006, 89: 213510
Chen L, Li W, Wei H, et al. Organic ultraviolet photovoltaic diodes based on copper phthalocyanine as an electron acceptor. Sol Energy Mater Sol Cells, 2006, 90: 1788–1796
Kong Z, Li W, Che G, et al. Highly sensitive organic ultraviolet optical sensor based on phosphorescent Cu (I) complex. Appl Phys Lett, 2006, 89: 161112
Ray D, Narasimhan K L. High response organic visible-blind ultraviolet detector. Appl Phys Lett, 2007, 91: 093516
Han Y, Wu G, Wang M, et al. High efficient UV-A photodetectors based on monodispersed ligand-capped TiO2 nanocrystals and polyfluorene hybrids. Polymer, 2010, 51: 3736–3743
Han Y, Wu G, Li H, et al. Highly efficient ultraviolet photodetectors based on TiO2 nanocrystal-polymer composites via wet processing. Nanotechnology, 2010, 21: 185708
Li H, Wu G, Shi M, et al. Synthesis of solution processable ultraviolet sensitive organic molecules and their application in hybrid UV photodetector. Synthetic Metals, 2010, 160: 1648–1653
Li H, Wu G, Chen H, et al. Spectral response tuning and realization of quasi-solar-blind detection in organic ultraviolet photodetectors. Org Electron, 2011, 12: 70–77
Yan F, Liu H, Li W, et al. Double wavelength ultraviolet light sensitive organic photodetector. Appl Phys Lett 2009, 95: 253308
Wu S, Li W, Chu B, et al. High response deep ultraviolet organic photodetector with spectrum peak focused on 280 nm. Appl Phys Lett 2010, 96: 093302
Hau S K, Yip H L, Zou J, et al. Indium tin oxide-free semi-transparent inverted polymer solar cells using conducting polymer as both bottom and top electrodes. Org Electron, 2009, 10: 1401–1407
Kim Y S, Oh S B, Park J H, et al. Highly conductive PEDOT/silicate hybrid anode for ITO-free polymer solar cells. Sol Energy Mater Sol Cells, 2010, 94: 471–477
Girtan M, Rusu M. Role of ITO and PEDOT:PSS in stability/degradation of polymer: Fullerene bulk heterojunctions solar cells. Sol Energy Mater Sol Cells, 2010, 94: 446–450
Kirchmeyer S, Reuter K. Scientific importance, properties and growing applications of poly(3,4-ethylenedioxythiophene). J Mater Chem, 2005, 15: 2077–2088
Kanaan H, Jolinat P, Ablart G, et al. Influence of poly (3,4-ethylenedioxythiophene)-poly(styrenesulfonate) in polyfluorene based light-emitting diodes: Evidence of charge trapping at the organic interface. Org Electron, 2010, 11: 1047–1052
Schlaf R, Parkinson B A, Lee P A, et al. Photoemission spectroscopy of LiF coated Al and Pt electrodes. J Appl Phys 1998, 84: 6729–6736
Wang S, Fung M, Lai S, et al. Experimental study of a chemical reaction between LiF and Al. J Appl Phys 2003, 94: 169–173
Kim J, Jung J, Lee D, et al. Enhancement of electrical conductivity of poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) by a change of solvents. Synthetic Metals, 2002, 126: 311–316
Ouyang J, Xu Q, Chu C, et al. On the mechanism of conductivity enhancement in poly(3,4-ethylenedioxy thiophene):poly(styrene sulfonate) film through solvent treatment. Polymer, 2004, 45: 8443–8450
Dong Q, Zhou Y, Pei J, et al. All-spin-coating vacuum-free processed semi-transparent inverted polymer solar cells with PEDOT:PSS anode and PAH-D interfacial layer. Org Electron, 2010, 11: 1327–1331
Sze S M. Physics of Semiconductor Devices. 3rd ed. New York: John Wiley & Sons, Inc, 2007
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Dai, Q., Zhu, L., Sun, J. et al. Organic photodetectors based on transparent electrodes for application in ultraviolet light detection. Sci. China Technol. Sci. 55, 1551–1555 (2012). https://doi.org/10.1007/s11431-012-4806-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11431-012-4806-9