Abstract
Using the industrial technologies of rubber latex irradiation, preparation of nanoscale silica (SiO2) slurry, mixing irradiated rubber latex with SiO2 slurry, and the spray drying, we have prepared the ultrafine fully-vulcanized powder carboxyl styrene-butadiene rubber (UFPCSBR)/SiO2 nanocompound powder, in which the SiO2 particles and UFPCSBR particles are isolated and stuck each other. When the UFPCSBR/SiO2 nanocompound powder is mixed with crude rubber, the UFPCSBR particles are dispersed well in rubber matrix because of their good compatibility, then the SiO2 particles are also dispersed well in rubber matrix because of the carrier nature of the UFPCSBR particles during the mixing procedure, and the novel rubber/UFPCSBR/SiO2 nanocomposites are fabricated. Compared with the rubber composites prepared by mixing the crude rubber with the UFPCSBR powder and SiO2 powder one after the other, the novel UFPCSBR/SiO2 nanocompound modified rubber/ UFPCSBR/SiO2 nanocomposites have better abrasion resistance, higher tensile strength and tear strength, and lower heat build-up data. Noteworthily, the tanδ-temperature curve of the novel rubber/UFPCSBR/SiO2 nanocomposites has the second tanδ peak due to the newly generated boundary layer surrounding the SiO2 particles, increasing the tanδ values in the temperature range of 0–20°C, which is very important to the research of green tyre tread.
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Bulgin D. Reinforcement of rubbers and plastics by particulate fillers. Composites, 1971, 2(3): 165–169
Sahakaro K, Beraheng S. Reinforcement of maleated natural rubber by precipitated silica. J Appl Polym Sci, 2008, 109: 3839–3848
Tabsan N, Wirasate S, Suchiva K. Abrasion behavior of layered silicate reinforced natural rubber. Wear, 2010, 269(5–6): 394–404
Ansarifar A, Azhar A, Ibrahim N, et al. The use of a silanised silica filler to reinforce and crosslink natural rubber. Int J Adhes Adhes, 2005, 25(1): 77–86
Stöckelhuber K W, Das A, Jurk R, et al. Contribution of physicochemical properties of interfaces on dispersibility, adhesion and flocculation of filler particles in rubber. Polymer, 2010, 51(9): 1954–1963
Wang M J, Zhang P, Mahmud K. Carbon-silica dual phase filler, A new generation reinforcing agent for rubber Part IX. Application to truck tire tread compound. Presented at a meeting of the Rubber Division, American Chemical Society. Dallas, Texas, April 4–6, 2000
Fray M E, Goettler L A. Rubber Nanocomposites: Preparation, Properties, and Applications. Chapter 24. Application of Rubber Nanocomposites. Singapore: John Wiley & Sons (Asia) Pte Ltd, 2010. 675–696
Annemieke ten B. Silica Reinforced Tyre Rubbers. Doctoral Dissertation. Enschede: University of Twente, August 30, 2002
Liu Y Q, Qiao J L, Zhang X H, et al. Preparation and application of a kind of compound powder (in Chinese). CN Patent, ZL03109108.3, 2003-04-03
Liu Y Q, Qiao J L, Zhang X H, et al. Fabrication and application of compound powder (in Chinese). CN Patent, ZL 200480009116.6, 2004-04-05
Dong W, Liu Y, Zhang X, et al. Preparation of high barrier and exfoliated-type nylon-6/ultrafine full-vulcanized powdered rubber/clay nanocomposites. Macromolecules, 2005, 38(11): 4551–4553
Wang Q, Zhang X, Dong W, et al. Rigid poly(vinyl chloride) ternary nanocomposite containing ultrafine full-vulcanized powdered rubber and nano-sized calcium carbonate. Mater Lett, 2007, 61(4–5): 1174–1177
Wang Q, Zhang X, Jin Y, et al. Preparation and properties of PVC ternary nanocomposites containing elastomeric nanoscale particles and exfoliated sodium-montmorillonite. Macromol Mater Eng, 2006, 291: 655–660
Dong W, Zhang X, Liu Y, et al. Process for preparing a nylon-6/clay/acrylate rubber nanocomposite with high toughness and stiffness. Polym Int, 2007, 56(7): 870–874
Gui H, Zhang X, Liu Y, et al. Effect of dispersion of nano-magnesium hydroxide on the flammability of flame retardant ternary composites. Compos Sci Technol, 2007, 67(6): 974–980
Dong W, Zhang X, Liu Y, et al. Effect of rubber on properties of nylon-6/unmodified clay/rubber nanocomposites. Eur Polymr J, 2006, 42(10): 2515–2522
Dong W, Zhang X, Liu Y, et al. Flame retardant nanocomposites of polyamide 6/clay/silicone rubber with high toughness and good flowability. Polymer, 2006, 47(19): 6874–6879
Bond R, Morton G F, Krol L H. A tailor—made polymer for tire applications. Polymer, 1984, 25(1):132–140
Nordsiek K H. The “integral rubber” concept—an approach to an ideal tire tread rubber. Kauts Gummi Kunstst, 1985, 38(3):178–185
Lipatov Y S, Rosovitsky V F, Babich B V, et al. On shift and resolution of relaxation maxima in two-phase polymeric systems. J Appl Polym Sci, 1980, 25: 1029–1039
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Wang, Q., Xie, J., Qiao, J. et al. Good dispersion of hydrophilic nanoscale silica in rubber matrix and the effects on rubber nanocomposites. Sci. China Technol. Sci. 55, 652–658 (2012). https://doi.org/10.1007/s11431-011-4709-1
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DOI: https://doi.org/10.1007/s11431-011-4709-1