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Reversible magnetocaloric effect and refrigeration capacity enhanced by two successive magnetic transitions in DyB2

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Abstract

A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive magnetic transitions: a spin-reorientation-like transition followed by a ferromagnetic-paramagnetic transition. These two transitions appreciably enlarge the magnetic-refrigeration temperature window and yield a huge refrigeration capacity of 610 J kg−1, with a maximum magnetic entropy change −ΔSmax of 17 J kg−1K−1, at a magnetic-field change of 5 T. The corresponding values for low magnetic-field change of 2 T are 193 J kg−1 and 7.4 J kg−1K−1, respectively.

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References

  1. Tishin A M, Spinchkin Y I. The Magnetocaloric Effect and Its Applications. Bristol: IOP, 2003

    Book  Google Scholar 

  2. Warburg E. Magnetische untersuchungen. Ann Phys (Leipzig), 1881, 13: 141–164

    MATH  Google Scholar 

  3. Gschneidner Jr K A, Pecharsky V K, Tsokol A O. Recent developments in magnetocaloric materials. Rep Prog Phys, 2005, 68: 1479–1539

    Article  Google Scholar 

  4. Dan’kov S Y, Spichkin Y I, Tishin A M. Magnetic entropy and phase transitions in Gd, Tb, Dy and Ho. J Mag Mag Mater, 1996, 152: 208–212

    Article  Google Scholar 

  5. Li B, Du J, Ren W J, et al. Large reversible magnetocaloric effect in Tb3Co compound. Appl Phys Lett, 2008, 92: 242504

    Article  Google Scholar 

  6. Li B, Hu W J, Liu X G, et al. Large reversible magnetocaloric effect in TbCoC2 in low magnetic field. Appl Phys Lett, 2008, 92: 242508

    Article  Google Scholar 

  7. Han Z, Li D, Meng H, et al. Magnetocaloric effect in terbium diboride. J Alloys Compd, 2010, 498: 118–120

    Article  Google Scholar 

  8. Pecharsky V K, Gschneidner Jr K A. Giant Magnetocaloric Effect in Gd5(Si2Ge2). Phys Rev Lett, 1997, 78: 4494

    Article  Google Scholar 

  9. Hu F X, Shen B G, Sun J R, et al. Influence of negative lattice expansion and metamagnetic transition on magnetic entropy change in the compound LaFe11.4Si1.6. Appl Phys Lett, 2001, 78: 3675

    Article  Google Scholar 

  10. Tegus O, Brück E, Buschow K H J, et al. Transition-metal-based magnetic refrigerants for room-temperature applications. Nature, 2002, 415: 150–152

    Article  Google Scholar 

  11. de Campos A, Rocco D L, Carvalho A M G, et al. Ambient pressure colossal magnetocaloric effect tuned by composition in Mn1-xFexAs. Nat Mater, 2006, 5: 802–804

    Article  Google Scholar 

  12. Wada H, Tanabe Y. Giant magnetocaloric effect of MnAs1-xSbx. Appl Phys Lett, 2001, 79: 3302

    Article  Google Scholar 

  13. Zhang Q, Cho J H, Li B, et al. Magnetocaloric effect in Ho2In over a wide temperature range. Appl Phys Lett, 2009, 94: 182501

    Article  Google Scholar 

  14. Matkovich V I. Boron and Refractory Borides. Berlin: Springer, 1977. 494–515

    Book  Google Scholar 

  15. Yamamoto T A, Nakagawa T, Sako K, et al. Magnetocaloric effect of rare earth mono-nitrides, TbN and HoN. J Alloys Compd, 2004, 376: 17–22

    Article  Google Scholar 

  16. Singh N K, Suresh K G, Nirmala R, et al. Magnetic and magnetocaloric properties of the intermetallic compound TbNiAl. J Mag Mag Mater, 2006, 302: 302–305

    Article  Google Scholar 

  17. Zhang Z, Shen B G, Xu Z Y, et al. Large reversible magnetocaloric effect in Er2In compound. J Alloys Compd, 2011, 509: 2602–2605

    Article  Google Scholar 

  18. Devonshire A F. Theory of ferroelectrics. Adv Phys, 1951, 3: 85–130

    Article  Google Scholar 

  19. Arrott A. Criterion for ferromagnetism from observations of magnetic isotherms. Phys Rev, 1957, 108: 1394

    Article  Google Scholar 

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Correspondence to Hui Meng.

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Meng, H., Li, B., Han, Z. et al. Reversible magnetocaloric effect and refrigeration capacity enhanced by two successive magnetic transitions in DyB2. Sci. China Technol. Sci. 55, 501–504 (2012). https://doi.org/10.1007/s11431-011-4684-6

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  • DOI: https://doi.org/10.1007/s11431-011-4684-6

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