Abstract
BaTi4O9-doped Ba0.6Sr0.4TiO3 (BST) composite ceramics were prepared by the conventional solid-state reaction and their structure, dielectric nonlinear characteristics and microwave dielectric properties were investigated. The secondary phase of the orthorhombic structure Ba4Ti13O30 is formed among BST composite ceramics with the increase of BaTi4O9. At the same time, a duplex or bimodal grains size distribution shows fine grains in a coarse grain matrix. The degree of frequency dispersion of dielectric permittivity below T m is increased initially and then decreased with respect to BaTi4O9. As the BaTi4O9 content increases, the tunability of composite ceramics decreases, while the Q value increases. Interestingly, 70 wt% BaTi4O9-doped BST has a tunability ∼4.0% (under 30 kV/cm biasing) versus a permittivity ∼68 and quality factor ∼134.1 (at ∼3.2 GHz).
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Nenasheva E A, Kanareykin A V, Kartenko N F, et al. Ceramics materials based on (Ba, Sr)TiO3 solid solutions for tunable microwave devices. J Electroceram, 2004, 13: 235–238
Tagantsev A K, Sherman V O, Astafiev K F, et al. Ferroelectric materials for microwave tunable applications. J Electroceram, 2003, 11: 5–66
Dedyk A I, Nanasheva E A, Kanareykin A D, et al. Tunability and leakage currents of (Ba, Sr)TiO3 ferroelectric ceramics with various additives. J Electroceram, 2006, 17: 433–437
Irvin P, Levy J, Guo R, et al. Three-dimensional polarization imaging of (Ba, Sr)TiO3: MgO composites. Appl Phys Lett, 2005, 86: 042903
Chung U C, Elissalde C, Maglione M, et al. Low-losses, highly tunable Ba0.6Sr0.4TiO3/MgO composite. Appl Phys Lett, 2008, 92: 042902
Chiu L H, Sengupta L C, Stowell S, et al. Ceramic ferroelectric composite materials with enhanced electronic properties BSTO-Mg based compound-rare earth oxide. U S Patent, 6 074 971, 2000
Chen Y, Dong X L, Liang R H, et al. Dielectric properties of Ba0.6Sr0.4TiO3/Mg2SiO4/MgO composite ceramics. J Appl Phys, 2005, 98: 064107
Chou X J, Zhai J W, Yao X. Dielectric tunable properties of low dielectric constant Ba0.5Sr0.5TiO3-Mg2TiO4 microwave composite ceramics. Appl Phys Lett, 2007, 91: 122908
Hakki B W, Coleman P D. A dielectric resonator method of measuring inductive capacities in the millimeter range. IRE Trans Microwave Theory Tech, 1960, 8: 402–410
Yan L, Chen L F, Tan C Y, et al. Ba0.1Sr0.9TiO3-BaTi4O9 composite thin films with improved microwave dielectric properties. Eur Phys J B, 2004, 41: 201–205
Kumar S, Raju V S, Kutty T R N. Preparation of BaTi4O9 and Ba2Ti9O20 ceramics by the wet chemical gel-carbonate method and their dielectric properties. Mater Sci Eng B, 2007, 142: 78–85
Wu S, Wang G, Zhao Y, et al. BaO-TiO2 microwave ceramics. J Eur Ceram Soc, 2003, 23: 2565–2568
Bokov A A, Bing Y H, Chen W, et al. Empirical scaling of the dielectric permittivity peak in relaxor ferroelectrics. Phys Rev B, 2003, 68: 052102
Zimmermann F, Voigts M, Menesklou W, et al. Ba0.6Sr0.4TiO3 and BaZr0.3Ti0.7O3 thick films as tunable microwave dielectrics. J Eur Ceram Soc, 2004, 24: 1729–1733
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Supported by the Ministry of Science and Technology of China through 973-project (Grant No. 2009CB623302), the Cultivation Fund of the Key Scientific and Technical Innovation Project, Ministry of Education of China (Grant No.707024), Shanghai Committee of Science and Technology (Grant No. 07DZ22302), and Shanghai Foundation Project under 06JC14070
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Zhang, J., Zhai, J., Jiang, H. et al. Dielectric tunable properties of BaTi4O9-doped Ba0.6Sr0.4TiO3 microwave composite ceramics. Sci. China Ser. E-Technol. Sci. 52, 116–122 (2009). https://doi.org/10.1007/s11431-008-0333-0
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DOI: https://doi.org/10.1007/s11431-008-0333-0