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Dielectric tunable properties of BaTi4O9-doped Ba0.6Sr0.4TiO3 microwave composite ceramics

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Abstract

BaTi4O9-doped Ba0.6Sr0.4TiO3 (BST) composite ceramics were prepared by the conventional solid-state reaction and their structure, dielectric nonlinear characteristics and microwave dielectric properties were investigated. The secondary phase of the orthorhombic structure Ba4Ti13O30 is formed among BST composite ceramics with the increase of BaTi4O9. At the same time, a duplex or bimodal grains size distribution shows fine grains in a coarse grain matrix. The degree of frequency dispersion of dielectric permittivity below T m is increased initially and then decreased with respect to BaTi4O9. As the BaTi4O9 content increases, the tunability of composite ceramics decreases, while the Q value increases. Interestingly, 70 wt% BaTi4O9-doped BST has a tunability ∼4.0% (under 30 kV/cm biasing) versus a permittivity ∼68 and quality factor ∼134.1 (at ∼3.2 GHz).

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Correspondence to JiWei Zhai.

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Supported by the Ministry of Science and Technology of China through 973-project (Grant No. 2009CB623302), the Cultivation Fund of the Key Scientific and Technical Innovation Project, Ministry of Education of China (Grant No.707024), Shanghai Committee of Science and Technology (Grant No. 07DZ22302), and Shanghai Foundation Project under 06JC14070

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Zhang, J., Zhai, J., Jiang, H. et al. Dielectric tunable properties of BaTi4O9-doped Ba0.6Sr0.4TiO3 microwave composite ceramics. Sci. China Ser. E-Technol. Sci. 52, 116–122 (2009). https://doi.org/10.1007/s11431-008-0333-0

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  • DOI: https://doi.org/10.1007/s11431-008-0333-0

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